Optical pressure-sensitive adhesive sheet

Inactive Publication Date: 2012-12-27
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0019]The optical pressure-sensitive adhesive sheet according to the present invention, as having the configuration, exhibits excellent tackiness and blistering/separation resistance under high-temperature conditions and thus excels in high-temperature bonding reliability. The optical pressure-sensitive adhesive sheet according to the present invention also excels in whitening resistance and thereby does not impair the appearances of optical members and optical products obtained by the use of the sheet. Particularly when the optical products (optical members) are display devices (display members), the sheet does not lower the visibility of displays of them. In addition, the sh

Problems solved by technology

However, a pressure-sensitive adhesive sheet formed from the pressure-sensitive adhesive, when exposed to high temperatures, has an insufficient adhesive strength and suffers from blistering and separation, thus being inferior in h

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0159]In a separable flask were placed 69.7 parts by weight of 2-ethylhexyl acrylate (2EHA), 10 parts by weight of 2-methoxyethyl acrylate (MEA), 13 parts by weight of 2-hydroxyethyl acrylate (2HEA), 6 parts by weight of N-vinyl-2-pyrrolidone (NVP), and 1.3 parts by weight of N-hydroxyethylacrylamide (HEAA) as monomer components, 0.1 part by weight of 2,2′-azobisisobutyronitrile as a polymerization initiator, and 200 parts by weight of ethyl acetate as a polymerization solvent, followed by stirring for one hour with the introduction of nitrogen gas. After removing oxygen from the polymerization system in this manner, the mixture was raised in temperature to 63° C., reacted for 10 hours, diluted with ethyl acetate, and thereby yielded an acrylic polymer solution having a solids concentration of 30 percent by weight.

[0160]With reference to Table 1, a pressure-sensitive adhesive composition (solution) was prepared by adding, to 100 parts by weight of the acrylic polymer, 0.2 part by weigh

example 2

[0161]A double-coated pressure-sensitive adhesive sheet (substrate-less double-coated pressure-sensitive adhesive sheet) including a pressure-sensitive adhesive layer having a thickness of 50 μm was obtained by the procedure of Example 1, except for using, as monomer components, 69.7 parts by weight of n-butyl acrylate (BA), 10 parts by weight of 2-methoxyethyl acrylate (MEA), 13 parts by weight of 2-hydroxyethyl acrylate (2HEA), 6 parts by weight of N-vinyl-2-pyrrolidone (NVP), and 1.3 parts by weight of N-hydroxyethylacrylamide (HEAA), and except for not using the silane coupling agent “KBM-403,” as indicated in Table 1.

example 3

[0162]A double-coated pressure-sensitive adhesive sheet (substrate-less double-coated pressure-sensitive adhesive sheet) including a pressure-sensitive adhesive layer having a thickness of 50 μm was obtained by the procedure of Example 1, except for using, as monomer components, 75 parts by weight of 2-ethylhexyl acrylate (2EHA), 11.5 parts by weight of 2-methoxyethyl acrylate (MEA), 5 parts by weight of 2-hydroxyethyl acrylate (2HEA), 7 parts by weight of N-vinyl-2-pyrrolidone (NVP), and 1.5 parts by weight of N-hydroxyethylacrylamide (HEAA), as indicated in Table 1.

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Abstract

Provided is an optical pressure-sensitive adhesive sheet which excels in whitening resistance and high-temperature bonding reliability and exhibits superior bump absorptivity. The optical pressure-sensitive adhesive sheet according to the present invention includes an acrylic pressure-sensitive adhesive layer and has a moisture content of 0.65 percent by weight or more after storage in an environment of 60° C. and 95 percent relative humidity for 120 hours, in which the acrylic pressure-sensitive adhesive layer contains an acrylic polymer and has a storage shear modulus at 23° C. of from 0.8×105 to 5.0×105 Pa, and the acrylic polymer is formed from, as an essential monomer component, a monomer that will form a homopolymer having a glass transition temperature of −10° C. or higher.

Description

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Claims

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Application Information

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Owner NITTO DENKO CORP
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