Method for preparing Sb contaminated site efficient ecological remediation flora from biogas residues

A technology of ecological restoration and biogas residue, which is applied in the direction of using microorganisms and the recovery of contaminated soil, etc., can solve the problems of long reaction cycle, secondary pollution, high energy consumption, etc., and achieve the reduction of cultivation and domestication cycle and natural tolerance The effect of strong power and improved economy

Inactive Publication Date: 2016-10-12
QINGDAO TECHNOLOGICAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high temperature melting method is costly and consumes a lot of energy
The biological method has a long reaction cycle and is likely to cause secondary pollution by foreign biological agents
The effect of the curing method is unstable, and the curing agent is likely to cause secondary pollution to the soil
Patent No. 201510056406.6 introduces a solidification method for soil containing heavy metals, but this method uses a large amount of materials, and the cost is high. On the other hand, the solidification effect is unstable. For example, the added calcium oxide is prone to carbonation under natural conditions. Reduces the effect of alkaline curing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0014] Example 1:

[0015] (1) Mix the biogas residue with a solution containing a certain amount of carbon source, add a certain amount of sulfate, and put it into the reactor for biochemical reaction, and control the dry biogas residue content of the mixed solution to 0.5% and the solid content rate of 10%. The organic carbon content is 12%, and the mass ratio of organic carbon / sulfate is 5:1, and then react for 1 day;

[0016] (2) Add a certain amount of antimonate to the solution after step (1) to control the molar ratio of sulfate / antimonate (2-3):1, and the mass ratio of organic carbon / antimony (10- 30): 1, then react for 5 days;

[0017] (3) Repeat adding antimonate to the solution twice, each time controlling the molar ratio of sulfate / antimonate (2-3):1, the mass ratio of organic carbon / antimony (10-30):1, The reaction time is 5 days, and then an efficient ecological restoration flora is obtained.

Example Embodiment

[0018] Example 2:

[0019] (1) Mix the biogas residue with a solution containing a certain amount of carbon source, add a certain amount of sulfate, and put it into the reactor for biochemical reaction, control the dry biogas residue content of the mixed solution to 8-10%, and the solid content rate of 10- 15%, the organic carbon content is 10-15%, the mass ratio of organic carbon / sulfate is 20:1, and then react for 0.1-1 days;

[0020] (2) Add a certain amount of antimonate to the solution after step (1) to control the molar ratio of sulfate / antimonate (1-5):1, and the mass ratio of organic carbon / antimony (30- 80):1, followed by reaction for 0-1 days;

[0021] (3) Repeat adding antimonate to the solution once, controlling the molar ratio of sulfate / antimonate (1-5):1, the mass ratio of organic carbon / antimony (30-80):1, and the reaction time is 1 Days, and then obtain efficient ecological restoration flora.

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Abstract

The invention provides a method for preparing an Sb (V) contaminated site efficient ecological remediation flora from biogas residues. By adding a carbon source and sulfate to the biogas residues, a sulfate-reducing flora in the biogas residues achieves rapid growth, and meanwhile sulfide is generated; and then, antimonate is added to the biogas residues to consume and inhibit the sulfide which grows from the sulfate-reducing flora, due to the existence of the sulfide, the toxicity of the antimonate on the sulfate-reducing flora is also greatly reduced, and meanwhile, the Sb-resistant performance of the cultured sulfate-reducing flora is also improved.

Description

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Claims

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Application Information

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Owner QINGDAO TECHNOLOGICAL UNIVERSITY
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