Process for the preparation of polymers containing amino groups employing a heterogeneous iron catalyst

Inactive Publication Date: 2017-03-23
ARLANXEO DEUT GMBH
View PDF5 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0013]The present invention allows a good control of the degree of hydrogenation of CEN bonds in particular for copolymers having a saturated main chain such as hydrogenated nitrile rubber or for copolymers or having residual double bonds in the range from 0.5 to 20 mol-% based on repeating units derived from diene monomers. The present invention further provides a process for the hydrogenation of nitrile groups in polymers such that the molecular weight of the rubbe

Problems solved by technology

Although homogeneous hydrogenation provides high conversions, it sometimes causes chain scission and often leads to polymer contamination with the metal due to catalyst extraction difficulties.
But no information was given about the molecular weight before and after the hydrogenation and no quantitative analysis of the conversion of nitrile groups to amino groups was done.
However, the drastic conditions of 250° C. and 930-950 atm do not allow commercial use of this method.
Furthermore, U.S. Pat. No. 2,585,583 described that polymers with a higher molecular weight than 1000

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Example

[0014]The present invention provides a process for the preparation of polymers containing amino groups by hydrogenation of nitrile groups containing polymers. The term polymers as used in this invention, refers to compounds comprising one or more kinds of repeating units wherein the total number of repeating units is 10 or more, preferably 100 or more and most preferably 1000 or more.

[0015]Generally, the nitrile groups containing polymers have a Mooney viscosity of from 10 to 180 MU, more preferably of from 20 to 150 MU and most preferably of from 30 to 120 Mooney units. The Mooney viscosity (ML (1+4@100° C.)) is determined at 100° C. by means of a shear disc viscometer in accordance with ASTM D 1646.

[0016]The nitrile groups containing polymers typically have a weight average molar mass Mw of from 20,000 to 1.2 Mio g / mol, preferably of from 100,000 to 1 Mio. g / mol, more preferably of from 200,000 to 800,000 g / mol. The weight average molar weight Mw is determined by gel-permeation

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Temperatureaaaaaaaaaa
Temperatureaaaaaaaaaa
Temperatureaaaaaaaaaa
Login to view more

Abstract

The present invention is related to a process for the preparation of polymers containing amino groups by hydrogenation of nitrile groups containing polymers by heterogeneous catalysis.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Owner ARLANXEO DEUT GMBH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products