System for preparing potassium sulfate from high-salt-content industrial wastewater and technology of system

A technology with high salt content in industrial wastewater, applied in the field of water treatment, can solve the problems of difficulty in salt separation by evaporation and crystallization, low economic value of Glauber's salt, and low quality of crystallized salt

Active Publication Date: 2016-06-08
INNER MONGOLIA JIUKE KANGRUI ENVIRONMENTAL TECH
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Problems solved by technology

[0008] Aiming at the problems of high cost, large nanofiltration system, difficulty in salt separation by evaporation and crystallization, low quality of crystallized salt, and low ec

Method used

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  • System for preparing potassium sulfate from high-salt-content industrial wastewater and technology of system
  • System for preparing potassium sulfate from high-salt-content industrial wastewater and technology of system

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Embodiment

[0044] Highly salty wastewater discharged from a chemical industry park, the wastewater COD≤90mg / L, TDS≤12000mg / L, NaCI≤3000mg / L, Na 2 SO 4 ≤6000mg / L, total hardness ≤1000mg / L.

[0045] (1) chemical softening

[0046] Chemical softening uses sodium carbonate and sodium hydroxide to remove calcium and magnesium ions in wastewater. After the influent is precipitated by 25% NaOH and 20% sodium carbonate, add 8% to 12% polyferric sulfate (coagulant) and 0.8% PAM (coagulant aid) to coagulate in the sedimentation tank 3 Most of the hardness and calcium and magnesium ions in the concentrated water of precipitation, solid-liquid separation, and a stage of reverse osmosis are removed.

[0047] Table 1

[0048] water quality Chemical softening of incoming water chemical softening water Removal rate (%) Total hardness mg / L 980 39 96

[0049] (2) Resin softening

[0050] The water produced by the sand filter is further softened by ion exchange res

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Abstract

The invention relates to a system for preparing potassium sulfate from high-salt-content industrial wastewater and belongs to the field of water treatment. The high-salt-content industrial wastewater is pretreated through a regulating pool, a pipeline mixer, a high-density precipitate pool, a V-type filter pool, ion exchange resin and an ultrafiltration membrane system and then concentrated through a first section reverse osmosis membrane system and a second section reverse osmosis membrane system and then enters a nanofiltration membrane system for salt separation, nanofiltration produced water and thick water enter a plate-pipe type high-pressure flat sheet membrane system II and a plate-pipe type high-pressure flat sheet membrane system I respectively to be concentrated again, the concentrated thick water enters a freezing crystallization system for crystallization, crystals enter a potassium sulfate preparing system to be converted, freezing mother liquor and the concentrated nanofiltration produced water enter an advanced oxidizing system for oxidation and then enter an evaporative crystallization system for crystallization, and produced sodium sulfate crystal salt enters a potassium sulfate preparing system for conversion. The system has the advantages that the scale of the nanofiltration system is reduced, and investment cost is reduced; salt separation is thorough, and operation cost is low; the purity of the crystallization salt is high; mirabilite and sodium sulfateare converted into potassium sulfate, and the economic value is improved.

Description

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Claims

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Application Information

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Owner INNER MONGOLIA JIUKE KANGRUI ENVIRONMENTAL TECH
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