Method for treating diesel through hydrogenation

A hydrotreating and diesel technology, applied in hydrotreating process, treating hydrocarbon oil, chemical instruments and methods, etc., can solve problems such as poor selectivity of monocyclic aromatic hydrocarbons, improve activity and stability, prevent aggregation, and solve technical problems The effect of defects

Active Publication Date: 2018-11-02
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is the poor selectivity of s

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0079] Example 1

[0080] use figure 1 The shown process processes the diesel feedstock oil D. Diesel feedstock oil D enters the hydrogenation reactor from the feed oil inlet, and hydrogen enters the hydrogenation reactor from the hydrogen inlet. The first reaction zone and the second reaction zone are set up in the hydrogenation reactor from top to bottom, in the first reaction zone The hydrorefining catalyst A is filled, and the second reaction zone is filled with hydrorefining catalyst B. The reaction effluent I is discharged from the top of the hydrogenation reactor, and the reaction effluent II is discharged from the bottom of the hydrogenation reactor. The reaction effluent I and the reaction After the effluent II is mixed, it is separated to obtain hydrogenated oil. The hydrogenation reaction conditions and product properties are shown in Table 2. It can be seen from Table 2 that the saturation rate of polycyclic aromatic hydrocarbons in the hydrogenated oil is 85.1%, and

Example Embodiment

[0081] Example 2

[0082] use figure 1 The process shown treats the diesel feedstock oil E. Diesel feed oil E enters the hydrogenation reactor from the feed oil inlet, and hydrogen enters the hydrogenation reactor from the hydrogen inlet. The first reaction zone and the second reaction zone are set up in the hydrogenation reactor from top to bottom, in the first reaction zone The hydrorefining catalyst A is loaded, the hydrorefining catalyst C is loaded in the second reaction zone, the reaction effluent I is discharged from the top of the hydrogenation reactor, the reaction effluent II is discharged from the bottom of the hydrogenation reactor, and the reaction effluent I and the reaction After the effluent II is mixed, it is separated to obtain hydrogenated oil. The hydrogenation reaction conditions and product properties are shown in Table 2. It can be seen from Table 2 that the saturation rate of polycyclic aromatic hydrocarbons in the hydrogenated oil is 85.4%, and the select

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PUM

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Abstract

The invention provides a method for treating diesel through hydrogenation. The method comprises the following steps: diesel raw oil enters a hydrogenation reactor from a raw oil inlet, a first reaction area and a second reaction area are arranged in the hydrogenation reactor from top to bottom, the raw oil inlet is formed between the first reaction area and the second reaction area, a hydrogen inlet is formed in the bottom of the hydrogenation reactor, a reaction effluent I is discharged from the top of the hydrogenation reactor, a reaction effluent II is discharged from the bottom of the hydrogenation reactor, after the reaction effluent I is mixed with the reaction effluent II, the mixture is separated to obtain hydrogenation generation oil, and based on the diesel raw oil, the saturation factor of polycyclic aromatic hydrocarbons in the hydrogenation generation oil is 85%-90%, and the selectivity of monocyclic aromatic hydrocarbons is 80%-85%. In the method provided by the invention, the high-quality raw materials are provided for preparing a high-octane gasoline or BTX component through catalytic cracking or hydrogen cracking, and moreover, the hydrogen consumption in the hydrogenation process is reduced, and the process economy is beneficially improved.

Description

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Claims

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Application Information

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Owner CHINA PETROLEUM & CHEM CORP
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