111results about "Metal/metal-oxides/metal-hydroxide catalysts" patented technology

A method for inspecting a honeycomb structured body of the present invention is a method for inspecting a honeycomb structured body comprising a pillar-shaped honeycomb fired body having a multitude of cells placed in parallel with one another in the longitudinal direction with a cell wall therebetween, the method comprising: measuring the shape of the honeycomb structured body in the longitudinal direction through preparing a contact measurement apparatus including a reference surface, a rail disposed perpendicularly to the reference surface, and a measurement probe including a contacting probe configured to move along the rail; contacting one end face of the honeycomb structured body with the reference surface; and moving the measurement probe in a direction nearing the reference surface to contact the contacting probe with the other end face of the honeycomb structured body.

The invention provides a hydrogenation catalyst and a preparation method thereof. The preparation method uses metal active components of group VIB and VIII for step load, wherein metal of group VIB is molybdenum, metal of group VIII is cobalt or nickel, and a carrier is porous oxide. Load of group VIB metal uses a corresponding soluble salt as a raw material, inorganic acid is used as an acidifying agent, and a long-chain alkyl quaternary ammonium cation is used as a precipitating agent; and Mo-based single-component loaded catalyst is prepared by firstly synthesizing an organic-inorganic hybrid material suspension, performing aqueous phase diffusion and tunnel deposition, filtering, washing, drying, and roasting. Load of group VIII metal uses a corresponding soluble salt as a raw material, and the metal is loaded onto the carried through a normal-temperature isopyknic dipping technology. The method can effectively improve load capacity of the active components and dispersiveness of the active components in the tunnels; and the prepared hydrotreating catalysts is excellent in hydrodesulfurization activity.

The invention relates to a method for preparing a catalyst with active metal component nonuniform distribution, which comprises the step of introducing effective quantity of at least one metal component selected from a VIII group and effective quantity of at least one metal component selected from a VIB group on a carrier by a soaking method. The method is characterized in that the soaking process comprises the following steps: firstly, mixing one or more acid selected from nitric acid, phosphoric acid, oxalic acid, citric acid, tartaric acid, pimelic acid and adipic acid, a compound of at least one metal component containing the VIB group, a compound of at least one metal component containing the VIII group, and water in sequence into a solution; secondly, using the mixed solution prepared in the first step to soak the carrier at room temperature, wherein the soaking time is between 1 and 5 hours; and thirdly, drying the carrier soaked in the second step for 2 to 10 hours at a temperature of between 60 and 160 DEG C, and roasting the soaked carrier for 2 to 5 hours at a temperature of between 400 and 600 DEG C. The method adopts the one-step soaking method to greatly simplify the preparation method of the catalyst.

The invention discloses a phenol ortho-methylation catalyst and a preparation method thereof. The catalyst is an alkaline Fe/Mg compound oxide, wherein, the mol ratio of Fe to Mg is 1: (0.1-2). The preparation method comprises the following steps: mixing and dissolving soluble malysite and soluble magnesium salts into alcohols solvent according to a required proportion to prepare a solution A; adding polyethyleneglycol (PEG) into strong aqua ammonia to prepare a solution B; slowly mixing the solution A and the solution B in a cocurrent flow mode under the condition of normal temperature and ultrasound, and then going on with the ultrasound for 30 minutes; filtering, washing, drying and baking the obtained precipitation; porphyrizing the baked solid and repulverizing the solid into 10-20 mesh finely ground particles after tabletting; the finely ground particles are the catalyst. The catalyst has the advantages of high activity at low temperature, simple preparation, innocuity, good stability, high selectivity of ortho position, particularly high selectivity of orthocresol and few by-products.

The invention provides a catalyst for selective hydrogenation and olefin removal of reformed generated oil. The catalyst comprises an active component oxide, an auxiliary agent oxide and a carrier, wherein according to the content of metal, the content of the components is as follows in percentage by mass: 0.05-0.5wt% of the active component oxide, 0.5-10wt% of the auxiliary agent oxide and the residual amount of the carrier; the active component oxide is at least one of oxides of noble metal Pt, Pd and Ru; the auxiliary agent oxide is one or two of oxides of Na, K, Mg, Ca, Co, Fe, Ni, Mo and Cu; the carrier is Al2O3. The catalyst has the advantages of high activity, good selectivity, long service life and low cost.

The invention discloses a method for preparing a ZnWO4 nanorod photocatalysis material. The method includes preparing a tungstic acid solution A, a zinc chloride solution B and a sodium citrate solution C; dropwise adding the solution A and the solution C into the solution B to form a solution D; regulating potential of hydrogen (pH) of the solution D to 6-8, and uniformly stirring to obtain a solution E; adding the solution E into a microwave hydrothermal reaction kettle, performing a heating reaction, naturally cooling the solution E to the room temperature after the reaction is finished, and taking out the reaction kettle; and opening the reaction kettle, washing a product for 4-6 times by deionized water and absolute ethyl alcohol, and drying to obtain the ZnWO4 nanorod photocatalysis material. According to the method, the microwave hydrothermal method is utilized to rapidly synthesize the ZnWO4 nanorod with the photocatalysis property, the later crystallization heat treatment is not required, the obtained product is high in purity, and the shape is controllable. The ZnWO4 nanorod with the photocatalysis effect can be synthesized in 10 minutes, and the degradation rate of the prepared ZnWO4 nanorod to rhodamine B in 50-60 minutes can reach to 97%-99%.

A biomass pyrolysis gasification multifunctional iron-based catalyst and a preparation method thereof are disclosed. The preparation method is characterized by comprising the following steps: (1) carrier pretreatment: placing CaO in a muffle furnace for calcining, then grinding and screening to prepare CaO carrier particles; (2) introduction of a main active component: mixing the CaO carrier particles with a Fe(NO3)3.9H2O solution, stirring and immersing, drying, calcining and grinding; (3) introduction of an auxiliary active component: mixing the sample prepared by the step (2) with a Ce(NO3)3.6H2O solution, stirring, immersing, drying, placing the obtained sample in a muffle furnace for calcining, placing the calcined sample in a dryer to cool to room temperature, grinding, then mixing the obtained powder with a Zr(NO3)4.5H2O solution, stirring, immersing, drying, then placing the sample in a muffle furnace for calcining, then placing the calcined sample in a dryer to cool to room temperature, and then grinding; and (4) shaping of the catalyst: performing shaping on the obtained catalyst, and screening to obtain the catalyst finished product.

A novel carbon nanotube powder containing carbon nanotubes which have a roll-like structure, also novel carbon nanotubes having a roll-like structure, novel processes for the production of the carbon nanotube powders and of the carbon nanotubes, and their use as an additive or substrate for various applications are described.

The invention provides a CDs-Pt nanomaterial with catalase catalytic properties. The CDs-Pt nanomaterial shows good enzyme-like catalytic activity in an acetate buffer solution using TMB as a substrate. The CDs-Pt nanomaterial provided by the invention belongs to the field of catalytic material and mimic enzyme research, and the obtained CDs-Pt nanomaterial has the characteristics that carbon quantum dots are modified by precious metal platinum, the synthetic steps are simple, the material scale is small, and the CDs-Pt nanomaterial has good dispersion in a reaction system, and has broad prospect in actual application such as hydrogen peroxide detection and glucose detection.

The invention relates to the technical field of photocatalysis, and specifically relates to a graphene-based gamma-FeO2O3 composite material photocatalyst, and a preparation method and use thereof. According to the graphene-based gamma-FeO2O3 composite material photocatalyst, gamma-Fe2O3 particles are attached to the surface of graphene, size distribution of the graphene is 1-50 mu m and the size distribution of the gamma-Fe2O3 particles is 20-500nm. The preparation method mainly comprises the following steps: preparation of graphite oxide; preparation of a graphite oxide iron sulfate hydrate intercalating matter; and preparation of the graphene-based gamma-FeO2O3 composite material photocatalyst. The graphene-based gamma-FeO2O3 composite material photocatalyst prepared by the preparation method disclosed by the invention has high carrier transmission rate, large specific surface area and low energy gap, so that the photocatalyst has extremely high activity of photocatalytic degradation of organic matters. The photocatalytic activity of the photocatalyst disclosed by the invention is over 86% higher than that of pure gamma-FeO2O3 particles. The photocatalyst has good circular stability, can be repeatedly used for many times, and does not cause secondary pollution in the photocatalytic degradation process.

The invention discloses a catalyst for catalyzing the hydrogenation of C5 and C9 petroleum resins as well as a preparation method and application thereof. The catalyst adopts nickel nanoparticles as active ingredients and magnesium oxide as a carrier. The preparation method comprises: (1) preparing a nickel-salt solution, under a stirring condition, adding the magnesium oxide carrier into the nickel-salt solution, and stirring for 0.5 to 24 h at 25 to 100 DEG C; (2) preparing a precipitator solution, under a stirring condition, adding the precipitator solution into a mixture obtained in the step (1), and stirring for 0.5 to 50 h at 25 to 100 DEG C; and (3) filtering a mixture obtained in the step (2), drying a filter cake, then placing the filter cake into a tubular furnace, and reducing the filter cake to obtain the magnesium oxide-loaded nickel catalyst. The prepared nickel/magnesium oxide catalyst has the characteristics of high catalytic activity, good stability, easiness in separation and the like; and the petroleum resin is hydrogenated under a moderate reaction condition, the degree of unsaturation of the resin is remarkably decreased, the hue is obviously improved, and the industrialized production is realized.

A method of operating a furnace having process tubes and multiple burners where it is desired to conform the temperatures of the process tubes to selected target temperature criterion. The present method provides a systematic and quantitative approach to determine how to adjust burner flow rates to result in desired tube wall temperatures, for example to minimize the temperature deviation between tube wall temperatures at a predetermined elevation in the furnace.

The invention relates to a method for preparing solid base catalyst with high specific surface by hybrid composite precursors, belonging to the technical field of preparation of composite metal oxide. The method comprises the following steps of: according to the characteristics of designability in structure and adjustability in laminate composition of laminated composite metal hydroxide, introducing a certain amount of Mg and Al, or Ca, Cu, Co, In and Ga on the laminate, preparing laminated compound, obtaining hybrid composite precursors by hybridization with carbon, then conducting high-temperature roasting on the precursors and obtaining the solid base catalyst of composite metal oxide with high specific surface and mesoporous structure. Due to introduction of the carbon into the precursors, the composite metal oxide obtained by the method has the characteristics of narrow pore size distribution and large specific surface area and the like, and the application of the catalyst in Knoevenagel condensation reaction of benzaldehyde and ethyl cyanoacetate shows good base catalytic activity.

According to the invention, the porous carbon-coated nano zero-valent iron composite catalyst is prepared by taking a metal skeleton as a precursor, and has excellent catalytic performance in an electro-Fenton process. The synthesis method has the advantages of simplicity and convenience in operation, low equipment requirement, good product performance reproducibility and the like. Due to the synergistic effect of iron and carbon, electron transfer is accelerated, and the catalytic efficiency is remarkably improved. The iron-carbon material has strong magnetism, can be quickly separated in a magnetic field, and is convenient to recover.

The composition of nano-grade lanthanum titanium compound oxide is La2-4Ti2-9O7-24, in which La:Ti:O (atom ratio)=2-4:2-9:7-24, LawTi2O7 and La4Ti9O24 are existed in micro-crystal state, its average grain size is 28nm-35nm, and its specific surface area is greater than 60 sq.m/g. Said compound oxide can be used as catalyst for preparing lactide by utilizing lactic acid dehydration and polycondensation, can improve viscosity of reaction system and can effectively reduce lactic acid oligomer cracking temp., and the yield of lactide is 80%-90%.

The present invention relates to a novel nickel catalyst. The present invention also relates to a process for the preparation of an improved nickel catalyst. The present invention also relates to a process for hydrogenation of m-dinitro benzene to m-phenylene diamine using the said improved catalyst. More particularly the present invention relates to a process involving hydrogenation of m-dinitrobenzene to m phenylene diamine in the presence of a supported bimetallic platinum catalyst, using methanol as a solvent. The catalyst system consisting of one metal selected from platinum group and other nickel supported on either carbon or alumina or silica or zeolite. The catalyst of the present invention is a bimetallic catalyst prepared by precipitation and impregnation technique at very specific preparation conditions.

The invention discloses a preparation method for a supported Mo-based oxidation desulfurization catalyst, and belongs to the technical fields of coal processing, petroleum processing and petrochemical processing, and relates to a preparation method for a solid catalyst for oxidative removal of distillate oil and sulphide-containing thiophene aromatic heterocyclic compounds in the chemical materials. The method is characterized by: loading an organic acid on a porous carrier-supported Mo-based oxide catalyst, then drying at a temperature of 70-120 DEG C; heating to the temperature of 100-180 DEG C in the protection of inert gas, and holding for 1-5 hours, wherein the heating rate is 1-10 DEG C per minute; then heating to the temperature of 200-260 DEG C and holding for 1-5 hours, wherein the heating rate is 1-10 DEG C per minute; then heating to the temperature of 300-340 DEG C and holding for 1-5 hours, wherein the heating rate is 1-10 DEG C per minute to prepare the catalyst. The mixture comprising Mo<6+> and low valence state Mo<5+> is loaded on the surface of the catalyst. With the present invention, the oxidation activity and the desulfurization activity of the supported Mo-based catalyst provided by the present invention can be significantly improved, and a wide application prospect in the field of deep desulfurization is provided.

The invention discloses an activated carbon-supported ruthenium-based ammonia synthetic catalyst and a preparation method thereof. The preparation method comprises the steps of with potassium ruthenate K2RuO4 H2O as a metallic ruthenium precursor, liquid ammonia and acetic acid as a stabilizer of ruthenium impregnation liquid, alkaline metal and alkaline-earth salts or bases as aids, and activatedcarbon as a supporter, performing impregnating to obtain the activated carbon-supported ruthenium-based ammonia synthetic catalyst. The activated carbon-supported ruthenium-based ammonia synthetic catalyst prepared herein is free of chlorine ions; active ingredients and the aids are distributed evenly on the catalyst; the prepared catalyst has stable performance, high activity, and good safety ofuse and is suitable for industrial production and application.

The invention discloses two types of catalysts for synthesizing methyl chlorosilane and a preparation method thereof. The two types of catalysts are prepared by taking metal copper powder as a raw material through the steps of oxidizing to remove surface impurities, deeply oxidizing to change substance structures, partially reducing and regulating product constituents, the catalyst I comprises the following constituents in percentage by weight: 15-30% of metal copper, 20-30% of cuprous oxide and 40-65% of copper oxide, and is used during normal reaction after a synthesis reaction is started, and the catalyst II comprises the following constituents in percentage by weight: 50-65% of metal copper, 25-35% of cuprous oxide and 5-20% of copper oxide, and is used during driving starting reaction in the early stage of synthesis reaction. The method disclosed by the invention has the advantages of low energy consumption, high efficiency, environmental friendliness, effectively reduced production cost, and more stable and complete reduction reaction; meanwhile, the prepared copper catalysts have the characteristics of high catalytic activity and selectivity, strong raw material adaptability and good overall indicators.

The invention discloses an application of a composite oxide with a perovskite structure in chemical looping hydrogen production and a preparation thereof. the composite metal oxide with the perovskite structure is AB'xB1-xO3, wherein A is rare earth meal lanthanum, B and B' are respectively transition metals cobalt and copper, and x is less than 1 and greater than 0. The application of an oxygen carrier in chemical looping hydrogen production is as follows: the combustion temperature in a steam reactor is 500-800 DEG C and the reduction temperature in a fuel reactor is 500-800 DEG C. The preparation method of the oxygen carrier comprises the following steps of: preparing a solution from a precursor composed of cobalt nitrate, copper nitrate and lanthanum nitrate and citric acid or ethylene glycol which is used as a complexing agent, mixing and uniformly stirring, vaporizing moisture until the solution becomes a viscous gel from a transparent sol, and finally drying and roasting. The roasted sample is the composite metal oxide with the perovskite structure. The oxygen carrier provided by the invention has high oxygen carrying rate, high activity, good stability and the like.

A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel, of cobalt and of tin, and in the range from 0.2 to 5.0% by weight of oxygen compounds of yttrium, of lanthanum, of cerium and/or of hafnium, each calculated as Y₂O₃, La₂O₃, Ce₂O₃ and Hf₂O₃ respectively, and catalysts as defined above.