The embodiment of the invention discloses an establishing method and system of a trust chain. The method comprises the steps of starting a BMC module and a TCM module before a server is powered on; adopting the TCM module to scale BMC firmware in the BMC module to obtain a first scaling result, and judging whether or not the BMC firmware is tampered according to the first scaling result; if the BMC firmware is not tampered, adopting the BMC firmware to scale BIOS-Boot-Block to obtain a second scaling result, and judging whether or not the BIOS-Boot-Block is tampered according to the second scaling result; if the BIOS-Boot-Block is not tampered, controlling a power control module to power on the server, and adopting a BIOS to establish the subsequent trust chain. According to the establishing method and system of the trust chain, the safety of the trust chain is improved when the trust chain is established, and accordingly the safety of the system is improved.