The invention relates to the fire extinguishing agent concentration measuring technology, in particular to a calibrating device for a fire extinguishing agent concentration measuring system. The problem that an existing fire extinguishing agent concentration measuring system is low in calibration accuracy is solved. The calibration device comprises a standard gas pressure control tank and a standard gas equally-dividing device, wherein the inlet of the standard gas pressure control tank is communicated with a standard gas generating device through a flow control valve, the standard gas equally-dividing device is provided with a containing cavity, an inlet and measuring outlets, the inlet and the measuring outlets are communicated with the containing cavity, the outlet of the standard gas pressure control tank is communicated with the inlet of the containing cavity through the outlet valve, the measuring outlets of the containing cavity are evenly distributed, and each measuring outlet is communicated with the fire extinguishing agent concentration measuring system through a measuring channel. By means of the device, the consistency and synchronism of all channel calibration sources during calibration of the special fire extinguishing agent concentration measuring system can be ensured, and therefore the final calibration accuracy of each channel is ensured, calibration efficiency is improved, and calibration expenses are saved.