Graphene adsorbent for crude oil desulfurization

A graphene and adsorbent technology, applied in the field of graphene adsorbents, can solve problems such as unachievable desulfurization effect, product performance impact, etc., and achieve the effect of satisfying use requirements, improving adsorption effect, and improving surface activity.

Inactive Publication Date: 2018-06-29
SHANDONG XINGHUO SCI TECH INSTITYTE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new compound can be used for improving the efficiency of removing hydrogen Sulphur (H2S) from petroleum products like gasoline or diesel fuel without causing damage to equipment. It does this through modifying certain types of carbon black called Graphite Black Oil (GOB). By adding these chemical agents onto GIBO we have improved its ability to absorb H2/SO, which helps remove impurity gases such as oxygen and water vapor that may harm downstream devices during processing.

Problems solved by technology

This patented technical solution described by this patents relates to separating crude or residual oil into its many diverse compounds before processing them further. However, current methods often result in some unwanted substances being introduced during separation processes due to impurity content within these complex mixtures.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A graphene adsorbent for crude oil desulfurization, comprising the following raw materials in parts by weight: 2.4 parts of diethanolamine, 10 parts of graphene, 1.5 parts of bismuth oxide, 2 parts of iron oxide, 2.2 parts of aluminum oxide, 0.6 part of sodium nitrite, 4 parts of acetaldehyde, 46 parts of ethylene glycol, 1.8 parts of polyacrylamide, 5 parts of strong alkali solution, 1.6 parts of surfactant, 2 parts of phenol and 6.5 parts of Radix Radix. Surfactant adopts cationic surfactant, strong alkali solution adopts sodium hydroxide solution.

[0021] The preparation method of the described graphene adsorbent for crude oil desulfurization, concrete steps are as follows:

[0022] Step 1: Crush Radix Radix at minus 5 degrees Celsius and pass through a 20-mesh sieve, then add water 7 times the weight of Radix Radix Radix and soak at room temperature for 4 hours, stir evenly, add enzymes for enzymolysis, and obtain Radix Radix Radix Enzymolysis Solution;

[0023] Step

Embodiment 2

[0028] A graphene adsorbent for crude oil desulfurization, comprising the following raw materials in parts by weight: 2.7 parts of diethanolamine, 13 parts of graphene, 1.8 parts of bismuth oxide, 2.6 parts of iron oxide, 2.8 parts of aluminum oxide, 1 part of sodium nitrite, 5.5 parts of acetaldehyde, 52 parts of ethylene glycol, 3.5 parts of polyacrylamide, 7 parts of strong alkali solution, 2.4 parts of surfactant, 2.4 parts of phenol and 7.3 parts of Radix Radix. Graphene adopts multi-layer graphene, and the particle size of bismuth oxide, iron oxide and aluminum oxide is 0.07mm.

[0029] The preparation method of the described graphene adsorbent for crude oil desulfurization, concrete steps are as follows:

[0030] Step 1: Crush Radix Radix at minus 6 degrees Celsius and pass through a 40-mesh sieve, then add water 9 times the weight of Radix Radix and soak it at room temperature for 4 hours, stir well and then add enzymes for enzymolysis. During the enzymolysis process, low

Embodiment 3

[0036] A graphene adsorbent for crude oil desulfurization, comprising the following raw materials in parts by weight: 3 parts of diethanolamine, 16 parts of graphene, 2.3 parts of bismuth oxide, 3.4 parts of iron oxide, 3.3 parts of aluminum oxide, 1.2 parts of sodium nitrite, 7.5 parts of acetaldehyde, 59 parts of ethylene glycol, 3.6 parts of polyacrylamide, 8 parts of strong alkali solution, 2.7 parts of surfactant, 2.8 parts of phenol and 8 parts of Radix Radix. The surfactant is a compound surfactant, and the strong alkali solution is a mixture of potassium hydroxide solution and lithium hydroxide solution.

[0037] The preparation method of the described graphene adsorbent for crude oil desulfurization, concrete steps are as follows:

[0038] Step 1: Pulverize Radix Radix at minus 8 degrees Celsius and pass through a 20-mesh sieve, then add water 9 times the weight of Radix Radix and soak at room temperature for 4 hours, stir evenly, add enzymes for enzymolysis, and obtain

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Abstract

The invention discloses a graphene adsorbent for crude oil desulfurization. The graphene adsorbent for the crude oil desulfurization is prepared from the following raw materials in parts by weight: 2.4 to 3.2 parts of diethanolamine, 10 to 18 parts of graphene, 1.5 to 2.5 of bismuth oxide, 2 to 4 parts of iron oxide, 2.2 to 3.6 parts of alumina, 0.6 to 1.5 parts of sodium nitrite, 4 to 8 parts ofacetaldehyde, 46 to 63 parts of ethylene glycol, 1.8 to 5 parts of polyacrylamide, 5 to 10 parts of strong alkali solution, 1.6 to 3 parts of surfactant, 2 to 3 parts of phenol and 6.5 to 9 parts of radix isatidis. The graphene adsorbent for the crude oil desulfurization has wide raw material sources, the specific surface area of the graphene is improved by supporting inorganic oxide on the graphene, the graphene is modified by using a strong alkali, sodium nitrite and a surfactant to improve the surface activity of the graphene, and the adsorption to sulfides in crude oil is improved by combining the graphene adsorbent with other components.

Description

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Claims

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Application Information

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Owner SHANDONG XINGHUO SCI TECH INSTITYTE
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