108results about "Luminescent compositions" patented technology

A luminescent solar collector is provided comprising a substrate and a light energy converter, such as a photocell, operatively connected thereto. The substrate is molded from a thermoplastic composition comprising a polymer and a fluorescent dye or quantum dot dispersed therein. The polymer comprises a polycarbonate unit and a polyester unit derived from the reaction of isophthalic acid, terephthalic acid, and resorcinol (ITR). In further embodiments, the substrate comprises two or more layers including a fluorescent layer and an overcoat layer. The fluorescent layer comprises the fluorescent dye or quantum dot and a polycarbonate polymer. The overcoat layer comprises the ITR unit. The substrate, in single layer or multiple layer form, has reduced haze levels over a prolonged period of time.

It is an object to provide a light-emitting element with high luminous efficiency by using a hole transporting substance with a sufficiently high T₁ level. Further, it is another object to provide a light-emitting device and an electronic appliance with low power consumption by using a hole transporting substance with a sufficiently high T₁ level. The present invention provides a light-emitting element which has a first layer containing a spiro-9,9′-bifluorene derivative in which one amino group is combined and a second layer containing a phosphorescent compound between an anode and a cathode.

Highly luminescent nanostructures, particularly highly luminescent quantum dots, comprising a nanocrystal core and thick shells of ZnSe and ZnS, are provided. The nanostructures may have one or more gradient ZnSe_xS_1-x monolayers between the ZnSe and ZnS shells, wherein the value of x decreases gradually from the interior to the exterior of the nanostructure. Also provided are methods of preparing the nanostructures comprising a high temperature synthesis method. The thick shell nanostructures of the present invention display increased stability and are able to maintain high levels of photoluminescent intensity over long periods of time. Also provided are nanostructures with increased blue light absorption.

The invention discloses magnetically fluorescent bifunctional microsphere and a preparation method thereof. The nanometer microspheres with the magnetically fluorescent function are obtained mainly by wrapping the surfaces of magnetic nanoparticles with polyaniline macromolecules and successfully connecting fluorescent nanometer material quantum dots through functional amino groups at the terminals of the polyaniline macromolecules. The magnetically fluorescent nanometer microspheres have the excellent fluorescence characteristics of the quantum dots and the superparamagnetism of the magnetic particles and can be collected and separated through a simple applied magnetic field. The magnetically fluorescent bifunctional microspheres can be applied to the fields of immunodetection, targeted therapy, cellular seperation and the like.

The invention discloses a preparation method for a co-doped type and separately-coded type ZnInS/ZnS dual-emitter quantum dot. The preparation method comprises preparation of white-light emitting ZnInS:Ag/ZnS/ZnS:Mn/ZnS and ZnInS:Ag & Mn/ZnS/ZnS/ZnS nano materials, wherein by adopting a core-shell structure, the ZnInS:Ag/ZnS/ZnS:Mn/Zn nano material is synthesized by the following steps of: (1) preparing a color-adjustable ZnInS: Ag core; (2) carrying out core-covering on a first molar layer ZnS; and (3) adsorbing Mn ions and carrying out cover-covering on second and third molar layers; and for the preparation of the ZnInS:Ag & Mn/ZnS/ZnS/ZnS nano material, injecting time of a Mn precursor in the step (3) is advanced to injecting time of an S precursor in the step (1). The preparation method adopts a single-pot thermal injection process, is simple in process, easy to operate, capable of being completed in common chemical laboratories, and easy to popularize; and raw materials are convenient to supply, and are low in price.

The present invention relates to a ceramics composite including: a matrix phase including Al₂O₃ or a substance in which one selected from Sc₂O₃ and Ga₂O₃ is incorporated into Al₂O₃; a main phosphor phase formed in the matrix phase and including a substance represented by a general formula A₃B₅O₁₂:Ce in which A is at least one selected from Y, Gd, Tb, Yb and Lu and B is at least one selected from Al, Ga and Sc; and a CeAl₁₁O₁₈ phase mixed in the matrix phase and the main phosphor phase.

The present invention provides a temperature sensitive paint for low-temperature use which shows durability at low temperatures, has a high light emission intensity, and makes it possible to perform precise temperature measurements of surface temperature fields by applying the paint to the surface of an object and measuring the light emission even in cases where the measurement distance is long in, for example, a large cryogenic wind tunnel or the like. The temperature sensitive paint for low-temperature use contains a ruthenium complex having a high light emission intensity as a temperature sensitive luminophore, a urethane type polymer as a binder, and an alcohol organic solvent as a solvent. Use of an alcohol organic solvent makes it possible to dissolve a temperature sensitive luminophore at a high solubility and to increase the light emission intensity by raising the temperature sensitive luminophore concentration in the coating film, so that more precise temperature measurements can be performed. By using the urethane type polymer having the durability at low-temperature, it is possible to obtain durability where no cracks occur at low temperatures even when the film thickness is increased. Therefore, adjustment of the light emission intensity and surface treatment such as surface polishing and the like can be performed by using this temperature sensitive paint for low-temperature use.

An aminostyryl compound represented by Formula 1:

The organic light emitting device using the aminostyryl compound exhibits low driving voltage and improved brightness, efficiency, and color purity.

Process for treating spent nuclear fuel (SNF) to make mixed metal oxides of UO₃ and PuO₂ to prevent nuclear proliferation. The process comprises the steps of (1) dissolving spent nuclear fuel in an acidic solution in the presence of an agent that reduces Pu⁺⁶ to Pu⁺⁴ and an agent that oxidizes Pu⁺³ to Pu⁺⁴; (2) extracting U⁺⁶ and Pu⁺⁴ from acidic solution with an organic solvent comprising a ligand that binds U⁺⁶ and Pu⁺⁴ and which is soluble in the organic solvent; (3) jointly extracting U⁺⁶ and Pu⁺⁴ from the organic solvent with an acidic aqueous solution; and (4) precipitating a mixture of U⁺⁶ and Pu⁺⁴ by adding a carboxylic acid to the acidic aqueous solution. The U⁺⁶ and Pu⁺⁴ precipitate is then be calcined to form a mixed metal oxide of UO₃ and PuO₂. Additional steps can result in the formation of a mixed metal oxide of UO₃, PuO₂ and NpO₂ as well as the removal and isolation of technecium from the SNF.

The invention discloses preparation of fluorogold nano-clusters and application of the fluorogold nano-clusters to tetracycline and copper fluorescent probes. The fluorogold nano-clusters (Au NCs) aresynthesized with a one-step method from casein separated from milk and carbon quantum dots as a stabilizer and a reducer for synthesis of the Au NCs. The Au NCs perform emission three times at 433 nm, 702 nm and 1052 nm under the excitation wavelength of 350 nm, tetracycline has a linear quenching effect at 702 nm, Cu<2+> is added to an Au NCs system after quenching, fluorescence recovers, and fluorescence intensity at 1052 nm is almost not affected in the overall process; tetracycline is added to the Au NCs, observation is carried out under a UV (ultraviolet) lamp with wavelength of 365 nm,red fluorescence of the Au NCs changes into yellow fluorescence, and after addition of Cu<2+>, the yellow fluorescence disappears gradually and the red fluorescence recovers gradually. Therefore, a near-infrared ratio fluorescence switch for tetracycline and Cu<2+> and UV visual dual-signal detection are established. The method has the advantages of adopting a fluorescence spectrum in a near infrared region and being small in interference, high in specificity and detection sensitivity, convenient to operate and capable of detecting tetracycline and Cu<2+> simultaneously.

The invention relates to a preparation method of solid carbon dot fluorescent powder with high quantum yield. The preparation method comprises the following steps: weighing raw materials according tothe following constituents in parts by weight: 0.25 to 1 part of potassium hydrogen phthalate, 0.5 part of sodium azide and 0.25 to 1 part of boric acid; mixing the raw materials, then dissolving themixture in a formaldehyde solution ultrasonically, putting the mixed solution in a microwave oven for heating at the power of 225 to 750 W for 4 to 10 min, and completely evaporating the liquid at theend of reaction to obtain white powder which is nitrogen and boron-doped carbon dots (NBCDs). The preparation method is low in cost, high in preparation speed and easy to operate; the quantum yield (QY) of the prepared solid luminous NBCSs is extremely high, and the absolute solid luminous QY of the NBCSs is 67.7 percent.

The invention discloses a high water-solubility ruthenium metal complex singlet oxygen fluorescent probe, a preparation method thereof, and an application thereof. According to the invention, a transition metal ruthenium is adopted as a central ion of the ruthenium complex; and anthracene nucleus derivatives with sodium (or potassium) sulfonate groups are adopted as ligands. The ruthenium complex has properties of a singlet oxygen fluorescent probe and a better water-solubility than existing anthracene nucleus derivative ligand ruthenium complexes. The ruthenium complex is suitable for quantitative or qualitative determinations of <1>O2 in neutral or basic system solutions.

The invention discloses Mn<4+> doped fluoroaluminate red fluorescent powder as well as a preparation method and an application thereof. The method comprises steps as follows: hydrofluoric acid and water are added to a polytetrafluoroethylene container, K2MnF6 is added and stirred to be dissolved, and then KF is added; after KF is dissolved, K3AlF6 is added and continuously stirred to be completely dissolved, and then the mixture is continuously stirred for 30 min; the mixture is left to stand after stirring is stopped, suction filtration is performed, a filter cake is dried under the vacuum condition at the temperature of 70 DEG C, and the Mn<4+> doped fluoroaluminate red fluorescent powder is obtained. Compared with the prior art, the K3AlF6:Mn<4+> red fluorescent powder is synthesized in a hydrofluoric acid aqueous solution, and the diluted aqueous solution has a function of purifying the K3AlF6 phase; excessive KF.2H2O is added, so that the K3AlF6 phase is crystallized and separated to be purified in the aqueous solution; the obtained fluorescent powder has a narrow emission spectrum range, and the reabsorption phenomenon is effectively avoided; the phase of the synthesized fluorescent powder is pure, and the light emitting efficiency and collection rate are high; the color gamut range of a white light LED device packaged by the fluorescent powder is wide.

The present invention provides semiconductor nanoparticles which emit light at room temperature and include a sulfide or oxide containing zinc, a Group 11 element in the periodic table, and a Group 13 element in the periodic table as a main component or a sulfide or oxide containing a Group 11 element in the periodic table and a Group 13 element in the periodic table as a main component. For example, the semiconductor nanoparticles are represented by Zn_(1-2x)In_xAg_xS (O<x≦0.5).

A high-molecular photoluminescent material is prepared through melt grafting the rare-earth compound of organic alkenyl acid, with synthetic high-molecular basic material, dissolving in arene solvent, precipitation in acetone and drying. Its advantages are high stability, fluorescent intensity and color purity, and low cost.

The invention relates to a method for recovering of fluorescent material from faulty glass bodies (1) of discharge lamps by crushing (11) the lamps, separating and recovering the fluorescent components thereof. The method comprises the steps of breaking the faulty glass bodies (1) in a crusher, removing all metallic component parts if present in the glass bodies (1) by means of electromagnetic separation (13), separating a remaining fraction forming a reusable waste from the broken scrap including glass particles and fluorescent material particles by sieving (15), separating the fluorescent material from the surface of the glass particles in a liquid by washing (19), and obtaining a reusable fluorescent material from the liquid suspension by means of at least one sedimentary deposition (21). The method comprises the step of treating of the remaining fraction by heat for removing the binding material from the fluorescent material if it is necessary.

The inorganic scintillator of the invention is an inorganic scintillator capable of producing scintillation by radiation, which is a crystal comprising a metal oxide containing Lu, Gd, Ce and Si and belonging to space group C2/c monoclinic crystals, and which satisfies the condition specified by the following inequality (1A), wherein A_Lu represents the number of Lu atoms in the crystal and A_Gd represents the number of Gd atoms in the crystal.

{A_Lu/(A_Lu+A_Gd)}<0.50  (1A)

The invention belongs to the technical field of photoelectric materials, and relates to a Eu<2+> doped silicon nitride orange red luminescent material for a blue light-excitated white light-emitting diode (LED) and a preparation thereof. Chemical components of the Eu<2+> doped silicon nitride orange red luminescent material meet a chemical general formula, namely Si3N4:xEu<2+>,yAl, wherein x is more than or equal to 0.0005 and is less than or equal to 0.1; and y is more than or equal to 0 and is less than or equal to 0.2. The Eu<2+> doped silicon nitride orange red luminescent material is simple in preparation technology and low in cost; and the material emits orange red light with the wavelength of between 500 and 700nm under the excitation of blue light with the wavelength of between 400 and 450nm, and the emission peak value is 565nm. Because the emission bandwidth of the material covers partial red light area, the material contains more red light components compared with YAG:Ce<3+> yellow phosphor powder; in the meanwhile, a silicon nitride matrix has excellent thermal stability and chemical stability, so that the Eu<2+> doped silicon nitride orange red luminescent material has potential application prospect on low-color-temperature high-power white LEDs.

The invention relates to rare earth ion liquid as well as a preparation method and application thereof in o detection of ferric ions. According to the invention, the rare earth ion liquid [C4mim] [Dy(NO3)4] is used as a fluorescence probe, a rare earth ion liquid aqueous solution with fixed concentration is prepared to be used as standard detection liquid, and whether water contains ferric ions or not can be judged by observing whether the ionic liquid fluorescence light cancels or not under 325nm excitation wavelength. By adopting the rare earth ion liquid, the ferric ions can be exclusively recognized, interference of other heavy metal ions is avoided, the detection method is simple and fast, a detection reagent is short in synthesis period and high in yield, and when being applied to actual production, the ion liquid is an environment-friendly solvent and has a wide application prospect.

The invention discloses a method for synthesizing red fluorogold nano-clusters through photoinduction and application thereof and belongs to the technical field of fluorogold nano-clusters. The methodcomprises the following steps: under a room temprature condition, adding mono(6-mercapto-6-deoxy)-beta-cyclodextrin into chloroauric acid and reacting at a stirring speed of 550 to 600 rmp until a solution becomes colorless, so as to obtain a solution A; slowly adding silver nitrate into the solution A and reacting at the stirring speed of 550 to 600 rmp for 9 to 10 min; then adding lipoic acid to obtain a mixed system B; reacting at the stirring speed of 550 to 600 rmp for 9 to 10 min; then regulating the pH (Potential of Hydrogen) of the solution to 3.5 to 4.5 by adopting hydrochloric acid,so as to obtain a solution B; putting the solution B under LED (Light Emitting Diode) lamplight and reacting for 85 to 90 min, so as to obtain a light yellow solution, i.e., the red fluorogold nano-clusters Au(0)@Au(I)-6-SH-beta-CD. According to the method disclosed by the invention, a photo-reduction method takes mercapto-beta cyclodextrin as a coating agent to synthesize gold nano-clusters; anda synthesis method is simple and can be used for selectively detecting silver ions.

The invention provides a preparation method of ZnCdSe/ZnS quantum dots. The method comprises the following steps that 1, a zinc source, a cadmium source, organic acid and/or organic amine and an organic solvent are stirred and heated to be dissolved after shielding gas is introduced to obtain a zinc and cadmium mixed pro-solution; 2, the solution is heated to 200-350 DEG C, and then a selenium source is injected into the solution within 30 s; 3, a sulfur source or sulfur and zinc source mixed solution is added drop by drop; 4, the temperature of 200-350 DEG C is kept constant, then cooling is performed to reach the room temperature, and separation and purification are performed to obtain ZnCdSe/ZnS quantum dots. The preparation method of the ZnCdSe/ZnS quantum dots is safety to implement, simple, controllable, low in cost, and capable of achieving repetition and amplification; the obtained quantum dots are uniform and controllable in size and appearance, the monodipserity is good, the fluorescence quantum yield is high, and the good stability on the high-temperature, washing and water dissolution modification and other conditions is good.

The invention discloses a green and simple method for preparing a Cu-doped selenide multi-element alloy quantum dot. The method comprises the following steps: preparing a Se precursor solution and a Zn precursor solution; and adding a Zn salt, a In salt, a Cu salt and an organic cladding agent into octadecene (ODE), heating to obtain a transparent solution, heating the transparent solution in the presence of a protection gas, mixing the heated transparent solution with the Se precursor solution, and reacting to obtain the Cu:Zn-In-Se bare nucleus quantum dot. The method has the advantages of safe and simple synthesis conditions, and no heavy metal element Cd, organophosphorus or other toxic inflammable reagents; and the luminescence efficiency of the quantum dot is high, the fluorescence peak of the quantum dot is tunable from 560nm to 720nm, and the PL QY can reach 38%.

The invention discloses a near-infrared long-afterglow luminescent material having photo-stimulated luminescence. The near-infrared long-afterglow luminescent material has a molecular formula of ABO3: Mnx, Rn and in the molecular formula, A represents La, Y or Gd, B represents Al or Ga, R represents one of rare earth elements, germanium, titanium, silicon, zirconium, cobalt, nickel, tin, chromium and iron, x is greater than or equal to 0.0001mol% and less than or equal to 50mol%, and n is greater than or equal to 0mol% and less than or equal to 50mol%. The invention also discloses a preparation method and a use of the near-infrared long-afterglow luminescent material having photo-stimulated luminescence. The near-infrared long-afterglow luminescent material having photo-stimulated luminescence has photo-stimulated luminescence and photo-stimulated long-afterglow luminescence, realizes recycle of the long-afterglow materials and can be used for biological fluorescence labeling imaging well.

The invention relates to a preparation method of a ternary terbium complex monomer and a copolymer luminescent material of the ternary terbium complex monomer and MMA. The method comprises the steps that firstly, the ternary terbium complex monomer is prepared, and recrystallization is conducted on an initiating agent AIBN (azodiisobutyronitrile) through methyl alcohol; then the ternary terbium complex monomer is dissolved by utilizing DMF (N,N-dimethylformamide) and DMSO (dimethyl sulfoxide) or a toluene solvent respectively, wherein the molar ratio of the ternary terbium complex monomer to the MMA is 1-10 to 100, and the initiating agent AIBN accounts for 0.5%-1% of the total mass of an initiating system; after reaction is conducted for 20-60 h under the conditions that inert gas argon exists, water and oxygen do not exist, and the temperature ranges from 50 DEG C to 85 DEG C, copolymer powder is obtained through methyl alcohol reprecipitation. The copolymer can be used for electronic terminals such as computers, televisions and mobile phones and mainly serves as the luminescent material of the panel display field. In addition, due to the fact that a pendant group -N-H- of the copolymer contains a reactive hydrogen atom, the copolymer can be used for ion recognition and fluorescent probes.

The present invention relates to one kind of composite light emitting materials comprising compound formed with porphyrin ligand and metal platinum and inorganic mesoporous molecular sieve, and the application of these materials in oxygen sensing. Through dispersing and dissolving the mesoporous molecular sieve with the organic template agent eliminated in solvent; adding the compound formed with porphyrin ligand and metal platinum into the solution with the weight ratio between the compound and the mesoporous molecular sieve being 1-8 to 100; stirring to react for 1 hr; filtering; washing the solid product with the solvent the same as that in the mother liquid for 3-6 times and naturally drying in the air, the composite light emitting materials may be prepared. The materials are light purple and can emit light with peak wavelength of 630-680 nm under the irradiation of ultraviolet lamp.