Light-emitting element using spirofluorene derivative and electronic appliance

a technology of spirofluorene and light-emitting element, which is applied in the direction of discharge tube luminescnet screen, organic chemistry, natural mineral layered products, etc., can solve the problems of difficult generation of triplet excited molecules and oxygen addition reactions, and achieve high t1 level, high luminous efficiency, and high hole-transporting property

Active Publication Date: 2008-08-28
SEMICON ENERGY LAB CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The inventors have developed a new type of material called Spiron 9, which has very good transport properties for holes and electrons. This makes it possible to create efficient LEDs at lower voltages while also reducing their energy usage compared to traditional materials like fluorescent powders.

Problems solved by technology

The technical problem addressed in this patent text relates to improving the performance of organic compounds used as light-emitting materials in light-emission elements. Specifically, there is a challenge in achieving efficient conversion of triplets excitations to single states while also avoiding unwanted energy transfer processes during the process.

Method used

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  • Light-emitting element using spirofluorene derivative and electronic appliance
  • Light-emitting element using spirofluorene derivative and electronic appliance
  • Light-emitting element using spirofluorene derivative and electronic appliance

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embodiment mode 1

[0080]In Embodiment Mode 1, a concept of a light-emitting element of the present invention will be explained.

[0081]In recent years, the present inventors have focused on phosphorescent compounds to achieve high performance of light-emitting elements and examined light-emitting elements using a wide variety of phosphorescent compounds. As one result thereof, the present inventors have found that by using a spiro-9,9′-bifluorene derivative to which one amino group is bonded is used, a light-emitting element containing a phosphorescent compound can provide light emission with very high efficiency compared to light-emitting elements using a phosphorescent compound which have been reported so far.

[0082]Through the property evaluation made by the present inventors, it was found that the T1 level of the spiro-9,9′-bifluorene derivative is high. That is, it was found that triplet excitation energy is difficult to transfer from other layers to a layer including the spiro-9,9′-bifluorene derivat

embodiment mode 2

[0088]In Embodiment Mode 2, a structure of a light-emitting element of the present invention will be explained with reference to FIG. 1.

[0089]FIG. 1 is a view illustrating a light-emitting element having a layer 120 containing an organic compound between a first electrode 101 and a second electrode 104. The layer 120 containing an organic compound includes a first layer 102 containing a spiro-9,9′-bifluorene derivative and a second layer 103 containing a phosphorescent compound.

[0090]Here, the second layer 103 containing a phosphorescent compound is preferably a layer in which a substance with triplet excitation energy larger than that of the phosphorescent compound is used as a host material and the phosphorescent compound is dispersed as a guest material. Dispersing the phosphorescent compound which is a substance serving as an emission center can prevent light emitted from the phosphorescent compound from being quenched due to the concentration.

[0091]A phosphorescent compound is not

embodiment mode 3

[0162]In Embodiment Mode 3, a light-emitting element with different element structure from that of Embodiment Mode 2 is exemplified in which a plurality of first layers containing a spiro-9,9′-bifluorene derivative and second layers containing a phosphorescent compound are provided and each of second layers containing phosphorescent compounds emits light. Accordingly, light that is a combination of light emitted from the plurality of light-emitting layers can be obtained. In Embodiment Mode 3, a mode of the light-emitting element including a plurality of first layers containing spiro-9,9′-bifluorene derivatives and second layers containing phosphorescent compounds will be explained with reference to FIG. 2.

[0163]A light-emitting element in FIG. 2 includes a layer A 203 containing an organic compound and a layer B 206 containing an organic compound between a first electrode 201 and a second electrode 202. The layer A 203 containing an organic compound includes a first layer 212 containi

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Abstract

It is an object to provide a light-emitting element with high luminous efficiency by using a hole transporting substance with a sufficiently high T1 level. Further, it is another object to provide a light-emitting device and an electronic appliance with low power consumption by using a hole transporting substance with a sufficiently high T1 level. The present invention provides a light-emitting element which has a first layer containing a spiro-9,9′-bifluorene derivative in which one amino group is combined and a second layer containing a phosphorescent compound between an anode and a cathode.

Description

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Claims

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Application Information

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Owner SEMICON ENERGY LAB CO LTD
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