Method for detecting low-concentration ammonia nitrogen in drinking water

A low-concentration ammonia nitrogen and detection method technology is applied in the detection field of low-concentration ammonia nitrogen in drinking water, which can solve the problems of inaccurate determination of low-concentration ammonia nitrogen, and achieve the effect of meeting the requirements of ammonia nitrogen detection, accurate measurement, and good linear relationship.

Active Publication Date: 2020-11-10
深圳市泛邦建设工程咨询有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows for quicker and more reliable analysis of small amounts (<100 ppb), even at very dilute concentrations like 1-5% or 10-20%. By adjusting the amount added during this process, it becomes possible to detect different levels of impurities such as urea nitrosamines that may be harmful if ingested into human bodies.

Problems solved by technology

Technological Problem: Current National Standard Method for Detecting Nitramic Acid Using LC-MS or Hydrolysis Quantitative Analysis can only be used at very high concentrations due to its poor response times associated with rapid absorption by certain compounds such as urea molecules from surfaces being tested. To address this issue, there have been attempts made to develop more accurate analyte measurement techniques based upon specific chemical properties like selective binding ability between different types of ionizable substances called ligands.

Method used

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  • Method for detecting low-concentration ammonia nitrogen in drinking water
  • Method for detecting low-concentration ammonia nitrogen in drinking water
  • Method for detecting low-concentration ammonia nitrogen in drinking water

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Example 1: The detection of low-concentration ammonia nitrogen in drinking water is completed according to the following steps

[0028] 1 Take an appropriate amount of environmental water sample, add zinc sulfate (100g / L) for flocculation and sedimentation for 10 minutes, and transfer 50 mL of supernatant to the colorimetric tube

[0029] 2 Add 4 mL of sodium hydroxide solution (6M) in water and mix well

[0030] 3 Add 1mL potassium sodium tartrate solution to the water, mix well, the concentration of potassium sodium tartrate solution is 500g / L

[0031] 4 Add 1.5mL Nessler's reagent (HgCl 2 -KI-KOH)

[0032] 5 Let stand for 30 minutes

[0033] 6 Take the blank test as a reference, and measure the absorbance of the sample at a wavelength of 420nm

[0034] 7 Take ammonium chloride (concentration 0~2.0mg / L) as the standard solution, measure the absorbance value according to the steps 1-6, and draw the standard curve

[0035] 8 According to the formula Calculate the ammonia nitroge

Embodiment 2

[0036] Example 2: The detection of low-concentration ammonia nitrogen in drinking water is completed according to the following steps

[0037] 1 Take 25mL sample to colorimetric tube

[0038] 2 Add 1 mL of sodium hydroxide solution (8M) in water and mix well

[0039] 3 Add 0.5mL potassium sodium tartrate solution to the water, mix well, the concentration of potassium sodium tartrate solution is 500g / L

[0040] 4 Add 0.5mL Nessler's reagent (HgI 2 -KI-KOH)

[0041] 5 Let stand for 10 minutes

[0042] 6 Take the blank test as a reference, and measure the absorbance of the sample at a wavelength of 420nm

[0043] 7 Take ammonium chloride (concentration 0~2.0mg / L) as the standard solution, measure the absorbance value according to the steps 1-6, and draw the standard curve

[0044] 8 According to the formula Calculate the ammonia nitrogen concentration in the water sample, where C is the ammonia nitrogen concentration in the water sample, A is the absorbance value of the sample, a is the int

Embodiment 3

[0050] Example 3: The detection of low-concentration ammonia nitrogen in drinking water is done according to the following steps: 1 Take 25mL tap water sample to colorimetric tube

[0051] 2 Add 1 mL of sodium hydroxide solution (8M) in water and mix well

[0052] 3 Add 0.5mL potassium sodium tartrate solution to the water, mix well, the concentration of potassium sodium tartrate solution is 500g / L

[0053] 4 Add 0.5mL Nessler's reagent (HgI 2 -KI-KOH)

[0054] 5 Let stand for 20 minutes

[0055] 6 Take the blank test as a reference, and measure the absorbance of the sample at a wavelength of 420nm

[0056] 7 Take ammonium chloride (concentration 0~2.0mg / L) as the standard solution, measure the absorbance value according to the steps 1-6, and draw the standard curve

[0057] 8 According to the formula Calculate the ammonia nitrogen concentration in the water sample, where C is the ammonia nitrogen concentration in the water sample, A is the absorbance value of the sample, a is the inter

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Abstract

The invention belongs to the field of water analysis, and particularly discloses an improved national standard analysis method suitable for detecting low-concentration ammonia nitrogen in drinking water. On the basis of a national standard method (HJ 535-2009), a proper amount of strong alkali solution is additionally added into a water sample, so that the pH value of the final sample is greater than 13, and then the absorbance value of a complex generated by reaction of ammonia nitrogen and a Nessler's reagent is measured at the wavelength of 420nm, so that the quantitative analysis work is completed. Compared with a national standard method (HJ 535-2009), the method has the advantages that the low-concentration ammonia nitrogen can be accurately measured, and the problems that the national standard method (HJ 535-2009) is insufficient in sensitivity to the low-concentration ammonia nitrogen and inaccurate in measurement are solved.

Description

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Claims

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Application Information

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Owner 深圳市泛邦建设工程咨询有限公司
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