Process for the reduction of the relative permeability to water in oil-bearing formations
a technology of relative permeability and oil-bearing formations, which is applied in the direction of fluid removal, chemistry apparatus and processes, borehole/well accessories, etc., can solve the problems of strong decline in oil production, inability to achieve the effect of applied treatments, and increased operation costs for pumping, treatment and discarding of huge volumes of water
Inactive Publication Date: 2002-11-05
PETROLEO BRASILEIRO SA PETROBRAS
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Benefits of technology
In order to avoid the mixture of solutions of different polarity within the well, the slugs of aqueous cationic and anionic polymeric solutions as well as the slug of aqueous solution of the multivalent cationic crosslinking agent are separated by slugs of aqueous solutions of alkaline salts such as KCl. This serves to prevent the mixture of the said cationic and anionic polymer aqueous solutions (as well as the mixture of said solutions with the crosslinking agent) which would cause flocculation, precipitation or gel formation in the string, this bringing harm to the injection of the aqueous solutions themselves into the reservoir.
The dimensioning of the spacing slug is effected so as to prevent the occurrence of flocculation, precipitation or gel formation near the face of the well, this bringing harm to the injection, besides reducing the possible extension of the treatment.
For producing formations having low permeability and low salinity the process may be much simpler: one single layer of cationic polymer may be injected in the production well, or one layer of cationic polymer followed by a layer of anionic polymer, followed or not by other layers of cationic and anionic polymer.
For more favorable situations, that is, low permeability and / or low salinity, one single layer of anionic polymer is sufficient.
by injecting into said production well a slug of water or of cleansing organic solvent the volume of which should be close to that of the annulus or of the production string, withdrawing any damage caused to the formation by precipitation of waxes or asphaltenes;
The present invention provides still an extremely flexible process for reducing the relative permeability to water by using solely commercial products, this rendering such process cheap and versatile, since the need of each formation is supplied by the variation of the successive layers of a certain type of polymer. Still, the flexibility of the applications according to the present invention is caused by the varied molecular weights and hydrolysis degree of the commercial products used in the process, which will be dimensioned as a function of the reservoir conditions (kind of rock, temperature, salinity and permeability).
Problems solved by technology
The production of water associated to the production of oil has been one of the major drawbacks for oil companies worldwide.
The breakthrough of the formation or injection water results in a strong decline of oil production, increasing the operation costs for pumping, treatment and discarding of huge volumes of water.
High formation temperatures may inhibit the effect of applied treatments.
On its turn, salinity may inhibit the swelling of the hydrophilic film and thus hinder the effect of permeability reduction to water.
Rigs are then required and the operation cost is considerably increased.
In spite of the alleged advantage, that the polymers may be used in various kinds of rocks, the synthesis of polymers having complex structures, which should be tested for each particular situation, is certainly time-consuming and expensive.
Besides, said US patent uses high molecular weight polymers in one single layer, this being only effective for high salinity, and low to medium permeability reservoirs.
In case of high permeability, the efficacy of the process using a high molecular weight polymer as a monolayer may be critically impaired.
Thus, the patent literature teaches various procedures where i) the polymers used are weakly adsorbed by the rock and present low molecular weight, with the ensuing low values of Residual Resistance Factor (RRF), that is, the plugging of the water production zone is below the desired value, or ii) complex syntheses and expensive products are involved, with the use of the monolayer configuration.
However, many times said products reveal themselves useless in formations of high salinity and high permeability.
Thus, the literature does not describe nor suggest a process for the selective and controlled reduction of the permeability to water of water producing areas in sandstones, such as described and claimed in the present application.
This serves to prevent the mixture of the said cationic and anionic polymer aqueous solutions (as well as the mixture of said solutions with the crosslinking agent) which would cause flocculation, precipitation or gel formation in the string, this bringing harm to the injection of the aqueous solutions themselves into the reservoir.
The dimensioning of the spacing slug is effected so as to prevent the occurrence of flocculation, precipitation or gel formation near the face of the well, this bringing harm to the injection, besides reducing the possible extension of the treatment.
Method used
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Embodiment Construction
Broadly, the concept of the present invention comprises the injection of aqueous polymer slugs alternated with the injection of spacing slugs of aqueous solutions, said slugs allowing the displacement and separation between the polymer slugs, so that the layer is only formed on the polymer film. This way it is possible to prevent the mixture between the polymer solutions and crosslinking agent, said mixture being a source of undesired tridimensional crosslinking with loss of selectivity and blocking of the formation pores.
In the present specification and claims, the term "partial crosslinking without gel formation" or simply "punctual crosslinking" means that the crosslinking agent that bears at least three positive charges when interacting with the already adsorbed anionic polymer may react with two charges of the same polymer chain (intramolecular reaction) or alternatively with one charge of one chain and another charge of another chain (intermolecular reaction), leaving one posi...
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Abstract
A process for the selective and controlled reduction of permeability to water in oil-bearing formations made up of sandstone or limestone, the process comprising the injection of a slug of polymer aqueous solutions having a polarity opposite to the polarity of the rock, followed by the injection of a spacing slug of alkaline halide and then a fresh slug of polymer aqueous solution, the polarity of which is opposite to the polarity of the first polymer slug, and then a slug of aqueous solution of trivalent metal crosslinking agent to effect the partial crosslinking of the polymer charges, the polymer layers being successively added until the injection pressure of the polymer aqueous solutions show that the desired Residual Resistance Factor RRF was attained, and well production may be resumed.
Description
The present invention relates to a process for the selective and controlled reduction of the relative permeability to water in oil-bearing formations, and more specifically to such a process whereby said reduction is achieved with the aid of successive polymer slugs, which are adsorbed to the rock surface and among themselves, creating a hydrophilic film which swells in the presence of water and strongly reduces the permeability to water. On the contrary, in the presence of oil the film keeps its original thickness, so that the permeability to oil is only slightly reduced.BACKGROUND INFORMATIONThe production of water associated to the production of oil has been one of the major drawbacks for oil companies worldwide. The breakthrough of the formation or injection water results in a strong decline of oil production, increasing the operation costs for pumping, treatment and discarding of huge volumes of water.Different techniques may be used to reduce the production of water or to prev...
Claims
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IPC IPC(8): C09K8/512C09K8/50E21B33/138
CPCC09K8/501C09K8/512E21B33/138
Inventor BARBOSA, LUIZ CESAR FERREIRACOELHO, SERGIO LUIZ PEREIRA DE FREITASDE HOLLEBEN, CARLOS ROBERTO CARVALHODE GODOY, GERALDO MARIA RAMOS
Owner PETROLEO BRASILEIRO SA PETROBRAS
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