The invention discloses environment-friendly impermeable composite bentonite, and belongs to the field of green chemistry and environmental protection. The composite bentonite is prepared from the following components in parts by mass: 1000-1200 parts of bentonite, 90-120 parts of sodium carbonate, 300-500 parts of a biodegradable polyester material, 50-100 parts of a cross-linking agent, 30-50 parts of a drying agent and 30-50 parts of a preservative; wherein the bentonite is granular bentonite; the biodegradable polyester material is one of poly (trimethylene carbonate), polycaprolactone andpolyvalerolactone; the cross-linking agent is N-hydroxymethyl acrylamide; the drying agent is at least one of bamboo charcoal and quartz sand; and the preservative is copper sulfate. By adding the biodegradable material and the cross-linking agent, the composite bentonite has good anti-seepage performance, can be biologically degraded, and has a wind indicator effect on the development of green chemistry.