The invention discloses an extraction composition, an extraction
system and application of the extraction composition. The extraction composition includes an extraction agent and a neutral phosphorusoxygen compound shown in the formula A. The extraction agent includes N,N-dihexyl
propanamide but does not include N,N-di(2-ethylhexyl)
acetamide. A mixture of an
amide compound of a specific structureand the neutral
phosphorus oxygen compound is selected as the extraction composition, and the extraction rate of Li of
lithium containing brine can reach up to 91.03%; the
lithium-
magnesium distribution coefficient can reach up to 757.29; and when HCl is used for
lithium reextraction, the reextraction rate is 84% or above, the extraction and reextraction performance of extracting lithium salt from the lithium containing brine is greatly improved, cost is reduced, and the extraction composite is more suitable for industrial production (Please see the formula in the specification).