70 results about "Phosphorus" patented technology

There is provided a thin film transistor having improved reliability. A gate electrode includes a first gate electrode having a taper portion and a second gate electrode with a width narrower than the first gate electrode. A semiconductor layer is doped with phosphorus of a low concentration through the first gate electrode. In the semiconductor layer, two kinds of n⁻-type impurity regions are formed between a channel formation region and n⁺-type impurity regions. Some of the n⁻-type impurity regions overlap with a gate electrode, and the other n⁻-type impurity regions do not overlap with the gate electrode. Since the two kinds of n⁻-type impurity regions are formed, an off current can be reduced, and deterioration of characteristics can be suppressed.

A method for producing a surface-treated silver-containing powder comprises vacuum freeze drying a dispersion liquid, which is obtained by dispersing silver or silver compound particles (a) in a solvent together with a surfactant (b) of an alkylamine type or an alkylamine salt type, or a phosphate type having a phosphorus content of 0.5 to 10% by mass so that the surfactant (b) is adsorbed in the surface of the silver or silver compound particles (a), thereby producing a silver-containing powder (c) whose surface is treated with the surfactant (b). Moreover, a silver paste is produced by dispersing the surface-treated silver-containing powder (c) in a solvent, or in a solvent with a resin.

The invention discloses a scale advanced treatment method for livestock and poultry farming waste water. The method of the invention comprises the following steps: (1) adding acid to the livestock and poultry farming waste water after biological treatment, and regulating the pH value of the waste water to be less than or equal to 5.0; (2) adding H2O2 and soluble ferrite to the waste water to carry out oxidation reaction, wherein the mol ratio of the H2O2 to the Fe<2+> in the soluble ferrite is between 1:1 to 2:1; and (3) after carrying out reaction for not less than 10 minutes, adding alkali to reaction liquid, regulating the pH of the reaction liquid to be greater than or equal to 6.0, carrying out flocculating and depositing, and then discharging deposit and waste water according with the discharge standard. By controlling the pH value of the reaction system, the adding proportion of the H2O2 to the FeSO4, and the running time, the invention achieves the treatment effect and optimization of energy consumption. The process effectively oxidizes and decomposes the trace organic pollutants (incretion interferents, antibiotics and the like), simultaneously removes various heavy metals and phosphorus by coagulating sedimentation, inactivates pathogenic bacteria in the waste water, and realizes integrated high-efficiency reinforcement treatment of the livestock and poultry farming waste water.

The invention discloses a mushroom cultivating material which is characterized in that bamboo sawdust, bamboo shells and biogas residues are used as raw materials, and the water content of the cultivating material is 62-65%. The invention also provides a manufacturing method of the cultivating material. Compared with the prior art, the mushroom cultivating material has the advantages that firstly, the cultivating material is reasonable in proportion, and a fungous material keeps certain air permeability, so that the growth speed of mycelia is increased, and the sackful time is shortened; secondly, bamboo sawdust particles are hard in texture and resistant to decomposition, and the biogas residues contains comprehensive nutrients including nitrogen, phosphorus and potassium, so that the growth of mushroom is promoted, the yield of a product is increased, and the quality of the product is improved; and thirdly, wood is replaced with bamboos and bran is replaced with the biogas residues, so that the source of a cultivating raw material is widened, and the production cost is reduced. The mushroom cultivating material has the social benefits that wood dust is replaced with the bamboo sawdust and the bamboo shells, so that part of contradiction between a fungus and forestry can be alleviated, waste materials can be changed into things of value, and energy conservation and emission reduction can be favorably realized.

The invention discloses a modified phosphogypsum highway subgrade filler and a preparation method thereof. The method comprises the following steps: aging phosphogypsum for more than 5 days to obtain a material A; calcining the material A at 160-200 DEG C for 1.5-2.5 hours to obtain a material B, and naturally cooling the material B; uniformly mixing 91-93 wt% of the material A and 7-9 wt% of the material B to obtain a material C; and adding water, which accounts for 12-16 wt% of the material C, into the material C, and stirring uniformly to obtain the modified phosphogypsum highway subgrade filler. The phosphogypsum is calcined at controlled temperature for controlled time according to the chemical characteristics of the calcined phosphogypsum to obtain the modifier, thereby enhancing the gelation property in the phosphogypsum, improving the stability and water resistance of the internal structure and obtaining the subgrade filler satisfying the highway engineering requirements. The modified phosphogypsum highway subgrade filler effectively solves the problem that the existing phosphogypsum is restricted to the local doping materials and is low in consumption.

The invention discloses a halogen-free flame retardant and a preparation method thereof and a flame-retardant polyolefin composition composed of the same. The structural formula of the halogen-free flame retardant is shown in the description, wherein the ratio of x to y to z is 1:(5-10):(1-5). The preparation method comprises the steps that melamine, phosphoric acid and piperazine are weighed and put into a high-speed mixer of which the top is provided with a liquid spray device to be stirred and mixed to be uniform, and a halogen-free flame retardant premixed material is obtained; the halogen-free flame retardant premixed material is subjected to a high-temperature dehydration condensation reaction, and the polyphosphoric acid-melamine-piperazine composite salt halogen-free flame retardant is obtained. The halogen-free flame retardant with the composite salt structure has the advantages that the halogen-free flame retardant is good in heat stability, high in phosphorus content and free of impurities such as halogens and inorganic salts, and the index of whiteness is larger than 90; few synthesizing process steps are needed, operation is simple and easy to carry out, the requirement on equipment is low, and the product yield reaches up to 80% or above; the flame-retardant polyolefin composition containing the halogen-free flame retardant has the good flame-retardant property, high water-resistant and heat-resistant properties and the excellent pigmenting property.

The invention discloses a phosphor-doped CHA molecular sieve, and a preparation method and application thereof, and belongs to the field of zeolite molecular sieve preparation technology and application. The preparation method is characterized by comprising the following steps: mixing a silicon source, an aluminum source, sodium hydroxide, potassium hydroxide, SAPO-18, AlPO-18 or SAPO-34 seed crystal and distilled water to form uniform gel; performing hydrothermal crystallization, performing washing and drying after performing solid-liquid separation on a crystallized product, thereby obtaining the phosphor-doped CHA molecular sieve which can perform ammonia gas selective catalytic reduction denitration catalysis after being loaded with Cu<2+>. Addition of seed crystal such as SAPO-18 is akey factor for generating the phosphor-doped CHA molecular sieve. The method can be used for preparing the phosphor-doped CHA molecular sieve with high degree of crystallinity under a conventional hydro-thermal synthesis condition, so that ammonia gas selective catalytic reduction denitration (NH3-SCR) low-temperature activity is good.

The invention discloses a coproduction method of 1, 2-propanediamine and dimethyl piperazine, which comprises the following steps of: mixing ammonia and isopropanol amine, pre-heating for vaporization, filling steam into a fixed-bed reactor, performing reaction in the presence of a catalyst for condensation and amination and under conditions with the pressure of 1.0MPa to 4.0MPa, the temperature of 300 DEG C to 350 DEG C and the contact time of 1.0-3.0s to obtain product stream of 1, 2-propanediamine, 2, 5-dimethyl piperazine, 2, 6-dimethyl piperazine, unreacted ammonia and unreacted isopropanol amine, and distilling the product stream for separation to obtain the 1, 2-propanediamine, 2, 5-dimethyl piperazine and 2, 6-dimethyl piperazine; wherein the weight ratio of the ammonia and the isopropanol amin is (10-16):1, and the catalyst for condensation and amination comprises the following ingredients by weight percentage: 97-99 percent of HZSM-5 (H-type zeolite sieve of molecular porosity 5) zeolite and 1-3 percent of phosphorus. The coproduction method is mainly applied in preparation of the 1, 2-propanediamine and the dimethyl piperazine.

The invention provides a combined treatment method of leachate and excrement wastewater due to high contents of organic matters and phosphor but insufficient nitrogen in the excrement wastewater and high contents of organic matters and nitrogen but insufficient phosphor in the leachate. Therefore, nitrogen and phosphor in the excrement wastewater and leachate are complemented with each other, nutrient elements required by microbes are balanced, and a biological treatment method is suitable for treatment. According to the method, biological treatment, membrane separation treatment and reverse osmosis deep treatment are adopted, so that the treated discharge water is in accordance with the first-grade requirement of the GB8978-1996 Comprehensive Sewage Discharge Standard of People's Republic of China.

The invention discloses a composite phosphate type anode material for a lithium ion battery, and a preparation method thereof. The composite phosphate type anode material can cause the raw material containing metals, lithium and phosphorus source and/or superfine LiMPO4 and/or superfine Li5-yM'2(PO4)3 to react under inert or reducing atmosphere and high temperature to synthesize LiMPO4 and Li5-yM'2(PO4)3 composite phosphate with combined chemical bonds, and by adding a conductive agent ball grinder, the composite anode material with excellent electrochemical performance can be obtained. The composite anode material prepared by the method has the advantages of low cost, unique process method and good electrochemical performance; the industrialization is easy to achieve.

The invention provides a slow-release compound fertilizer, which is a spherical or near-spherical granular compound fertilizer having a layered structure, wherein the innermost layer is a nitrogenous fertilizer layer; the intermediate layer is a potassic fertilizer layer; the outer layer is a mineral layer containing phosphorus; proportions of nitrogen, phosphorus and potassium are determined according to thicknesses of the fertilizer layers. The invention further provides a production method of the slow-release compound fertilizer. Tailing pulp is generated after heavy metals, manganese and iron are recycled from leached residues of production enterprises for electrolyzing manganese metal and manganese dioxide. The production method comprises the following steps of: adding flocculating agent, the weight of which is 0.01-0.02% of that of tailing mud, into the obtained tailing pulp, carrying out filter pressing by using a belt filter press, wherein the moisture content of filtered mud is 40-50%; and then, adding phosphatic fertilizer into the filtered mud, uniformly mixing, and carrying out calendering forming three times and roller-crushing calendaring granulating once by adopting a fertilizer granulator and drying to obtain the slow-release compound fertilizer.

The invention relates to a method for preparing the cathode material used in a ferrous phosphate lithium battery by adopting low-valent oxyacid of phosphorus; the technical proposal is as follows: lithium salt, ferrous salt, phosphate, and hypophosphorous acid or hypophosphite are blended according to the mol ratio that Li: Fe: PO4<3->: H3PO2 or AH2PO2 or E(H2PO2)2 is equal to x: y (1-z): k. Carbon-containing compound or carbon powder and wet milling liquid are added, ball milling is carried out for 3-12 hours, and the mixture is dried in atmospheric pressure or vacuum at 48-100 DEG C. The dried powder is prepared into the lithium iron phosphate containing controllable Fe2P by two-stage sintering process or temperature programmed two-stage sintering process. When the molecular formula of hypophosphite, one ingredient of the reaction composite, is AH2PO2 or E(H2PO2)2, A is Li<+>, Na <+>, K<+>, Ag<+> or NH<+>, E is Ca<2+>, Sr<2+>, Ba <2+>, Ga <2+>, Ge<2+>, Sn<2+>, Sc<2+>, Mn<2+>, Fe<2+>, Co<2+>, Ni<2+>, Cu<2+>, Zn<2+> or Mo<2+>. The method of the invention has low cost of raw materials, broad source of raw materials, simple preparation and short time consumed; the prepared materials have even composition, excellent discharge performance and good discharge cycling performance in heavy current.

The invention provides soil ecological system restoring organic fertilizer which is high in content of nutrients available for crops and reasonable in nutrition collocation, is thoroughly decomposed, has a small number of foreign microbes and is high in organic matter content. The soil ecological system restoring organic fertilizer comprises organic raw materials, microbial agents and NPK, wherein the organic raw materials comprise cake fertilizer, green manure, plant protein and biochemical humic acid; the microbial agents comprise nine microbial bacteria such as nitrogen-fixing bacteria, phosphorus-solubilizing bacteria, potassium-releasing bacteria, actinomycetes, saccharomycetes, lactic acid bacteria, photosynthetic bacteria, paenibacillus polymyxa and bacillus subtilis; the NPK accounts for 5-25% of the total fertilizer; the NPK comprises ammonium sulfate, ammonium chloride, ammonium nitrate phosphate, ammonium phosphate, potassium sulfate, potassium chloride, potassium nitrate, magnesium sulfate, zinc sulfate and borax; the organic raw materials are taken as the balance of the fertilizer.

The invention discloses a flame-retardant polybutylene terephthalate (PBT) composite material, which is prepared by taking a mixture of montmorillonite and polytetrafluoroethylene as an organic synergistic flame retardant and cooperating with a nitrogen containing flame retardant, and a preparation method thereof. The composite material comprises the following components in percentage by weight: 45-70 percent of polybutylene terephthalate, 1-10 percent of nano-sized organic montmorillonite and 10-30 percent of glass fiber which is subjected to surface treatment, and 10-30 percent of nitrogen containing flame retardant, wherein the nano-sized organic montmorillonite is montmorillonite mineral powder processed by an alkyl intercalating agent; and the glass fiber is alkali-free glass fiber processed by a coupling agent. The preparation method comprises the following steps of mixing the components, antioxidant and lubricating agent; melting, blending and extruding the mixture by a double-screw extruder to obtain the polybutylene terephthalate composite material which has high performance and is synergistically filled by montmorillonite and glass fiber. The composite material is high in modulus, good in toughness, high in temperature resistance and high in CTI value; the processing environment is friendly; the composite material are free of halogen and phosphorus, meets an ROSH (The Restriction of the use of Certain Hazardous Substances in Electrical and Electronic Equipment) principle, and is widely applied to the field of engineering plastics.

A NiCuSiFe alloy prepared from Ni and Cu contained waste through resmelting contains Ni (25-60 wt%), Cu (25-60), Si (8-15), impurity (less than or equal to 0.2) and Fe (the rest), and can also be used as additive for smelting refractory steel, high-weatherability steel and other alloy steel. Its advantages are low smelting point, high dispersity and deoxidizing effect in molten steel and low cost.

The invention discloses a magnetic bioreaction separation device for treating organic wastewater, which comprises a magnetic bioreactor and a rare-earth magnetic disc separation device, wherein the magnetic bioreactor consists of a reaction vessel, and microbe carrier magnetic species or magnetic zooglea formed by the microbe carrier magnetic species, which is placed in the reaction vessel; the magnetic bioreactor is connected with the rare-earth magnetic disc separation device by a flowing discharge pipeline; and the upper part of the rare-earth magnetic disc separation device is provided with a water outlet pipe, and the lower part thereof is provided with a sludge discharge valve. Since the invention utilizes the microbes attached to the microbe carrier magnetic species or magnetic zooglea to decompose the organic matter, while the magnetic zooglea and the treated water can be treated by the rare-earth magnetic disc separation device for solid-liquid separation, not only the cost on the investment and operation is lower than that of the membrane bioreactor, but also the separation efficiency is high, the energy consumption is low, and the effect on denitrification, phosphorous, SS, COD and BOD removal; and the invention is particularly suitable for treating the organic wastewater with large flow and high concentration.

Compositions comprising a thermoplastic elastomer, e.g., a polyurethane, a nitrogen and/or phosphorus-based, intumescent flame retardant, e.g., a polyphosphate, a non-phosphorus-based burn synergist, e.g., carbon black or a metal oxide, and an optional olefin polymer, EVA are provided. Color-stable, halogen-free, flame retardant compositions comprising a thermoplastic elastomer polymer, a phosphorus-based flame retardant, at least 3 weight percent TiO2 and a UV stabilizer are also provided.

The invention provides a phosphatidyl nanometer prodrug released by enzymatic response and a preparation method and application thereof. The phosphatidyl nanometer prodrug is formed by a hydrophilia antitumor drug containing primary alcohol and a phospholipid compound through bonding of a phosphorus oxygen bond under the catalytic action of phospholipase D. The invention further provides application of the phosphatidyl nanometer prodrug released by enzymatic response for releasing the antitumor drug to tumor tissue in a targeting mode. The hydrolysis/transesterification two-way reaction characteristic of the phospholipase D highly-expressed in tumor tissue is utilized creatively, and the amphipathicity phosphatidyl nanometer prodrug is obtained through biological catalytic synthesis of the phospholipase D in vitro; when the prodrug is accumulated to tumors in a targeting mode for responding to the phospholipase D to trigger hydrolysis, the antitumor drug is specifically released, and meanwhile the purposes of safety, stability and effective release of the targeting medicine are achieved.

The invention discloses an ox-bone dried bean curd and a production method thereof. The ox-bone dried bean curd is prepared from the following raw materials by weight ratio: mixing ox-bone juice and spice by weight ration of 97-99:1-3, adding bean curd blocks, boiling and sterilizing at high temperature. The ox-bone juice is prepared by rinsing ox bones, adding water, and boiling for 15-25 minutes at high temperature of 118-121 DEG C. The nutritional ingredient of the ox bones is fully utilized, and a unique process is used for production, so that the ox-bone dried bean has nutrient substances needed by the human body containing calcium, phosphorus, ferrum, amino acid, protein and the like. The spice is added in the production process, so that the ox-bone dried bean curd has garnet-red color, delicate taste and soft aroma and is incomparable to an ordinary sauce halide bean curd.

The invention relates to a carbon/carbon composite material modified by a silicon carbide and hydroxyapatite gradient coating and a preparation method thereof. A SiC coating and a SiC-HA coating are prepared on the surface of a carbon/carbon composite material by embedding and supersonic plasma spraying methods. The SiC coating prepared by the embedding method belongs to in-situ growth combinationof C and Si, and the SiC-HA coating and the SiC coating are gradient coatings, so that the SiC-HA coating and the SiC coating can be better fused, surface defects due to mismatch of thermal expansioncoefficients can be reduced, and bonding strength and corrosion resistance between the coating and a substrate can be improved. The thermal stress between the coating and the carbon/carbon compositesubstrate can be effectively reduced, generation of cracks can be reduced, and the compactness of the coating can be improved. The supersonic plasma spraying method is precise in control of parameters, can produce a uniform thickness coating, is low in requirements on components, and has a very broad application prospect in the biological field.