118 results about "Nitrogen" patented technology

A system and method for separating air into components uses an air dehydration membrane for removing water vapor from compressed air. Dried compressed air is then directed, from the dehydration membrane, into a gas separation module which may be a membrane system, different from the air dehydration membrane, or a pressure swing adsorption (PSA) system. The air dehydration membrane is made of a hydrophilic polymer having a permeability for water vapor which is greater than its permeability for air, and having low selectivity between oxygen and nitrogen. The air dehydration membrane has a hydrophilic coating, which itself may be a polymer. The coating does not affect the selectivity of the coated dehydration membrane with respect to oxygen and nitrogen, but does increase selectivity of the membrane with respect to water vapor.

The invention discloses a mushroom cultivating material which is characterized in that bamboo sawdust, bamboo shells and biogas residues are used as raw materials, and the water content of the cultivating material is 62-65%. The invention also provides a manufacturing method of the cultivating material. Compared with the prior art, the mushroom cultivating material has the advantages that firstly, the cultivating material is reasonable in proportion, and a fungous material keeps certain air permeability, so that the growth speed of mycelia is increased, and the sackful time is shortened; secondly, bamboo sawdust particles are hard in texture and resistant to decomposition, and the biogas residues contains comprehensive nutrients including nitrogen, phosphorus and potassium, so that the growth of mushroom is promoted, the yield of a product is increased, and the quality of the product is improved; and thirdly, wood is replaced with bamboos and bran is replaced with the biogas residues, so that the source of a cultivating raw material is widened, and the production cost is reduced. The mushroom cultivating material has the social benefits that wood dust is replaced with the bamboo sawdust and the bamboo shells, so that part of contradiction between a fungus and forestry can be alleviated, waste materials can be changed into things of value, and energy conservation and emission reduction can be favorably realized.

The invention provides an aluminum and aluminum alloy matrix aluminum nitride reinforced gradient composite surface layer. In the surface layer, aluminum and an aluminum alloy matrix are melted by nitrogen arc with a simple process to ensure that Al and N elements in a melting bath to perform nitridation reaction, namely Al reacts with N to generate AlN, so as to obtain the 'AlN reinforced gradient composite surface layer'. Compared with a thin surface nitridated (AlN) layer prepared by reactive sputtering, chemical vapor deposition, ion injection, plasma nitridation and other methods, the surface layer has large thickness (0.13-0.3mm), has the microstructural characteristic of surface gradient composites, and has remarkably improved microhardness and abrasion resistance compared with the aluminum and the aluminum alloy matrix.

The invention relates to a catalyst for ternary copolymerization of norbornenes, tetrafluoroethylene and pentenes and a ternary copolymerization method. The catalyst is characterized in that the catalyst is prepared through the following method comprising the steps of: dissolving iron dichloride, a ligand and an alkyl metal compound in a solvent in a dry single-neck glass bottle in an inert gas atmosphere, sealing a bottle mouth through an emulsion pipe, keeping the constant temperature in a water bath at the temperature of 40-50 DEG C for 10-30min, and cooling to obtain an iron complex catalyst. Compared with the prior art, the catalyst provided by the invention is a novel iron complex catalyst which can produce catalytic activity in an nitrogen-protected system at a certain pressure and the temperature of 20-120 DEG C so as to catalyze the ternary copolymerization of the norbornenes with the tetrafluoroethylene and the pentenes, and a product after soaking in methanol is very easy to wash and separate. The catalyst has the characteristics of high copolymer yield, low reaction temperature, low price, easiness in obtainment, high catalytic efficiency and the like.

The invention discloses a high-pressure sealing nitrogen spring lever clamping device. An oil cylinder end cover is installed at the bottom of an oil cylinder body in a sealing mode, an oil cylinder piston is movably installed in the inner cavity of the oil cylinder body, the position between the inner cavity of the oil cylinder body and the large-end portion of the oil cylinder piston is sealed, the extended end of the oil cylinder piston penetrates through the top of the oil cylinder body to be movably connected with a press arm, the position between the extended end of the oil cylinder piston and the top of the oil cylinder body is sealed, the top of the oil cylinder body is movably connected with one end of a connecting rod, the other end of the connecting rod is movably connected with the press arm, and an oil inlet channel is arranged at the top of the oil cylinder body. A nitrogen spring full of nitrogen in the inside is arranged between the large-end portion of the oil cylinder piston and the oil cylinder end cover. The high-pressure sealing nitrogen spring lever clamping device utilizes the high-pressure sealed nitrogen spring to perform propulsion, clamps a workpiece through a hinge mechanism, does not need a power source, achieves pressure maintaining and clamping through the nitrogen spring, is high in stability, free of pollution and large in clamping stroke, saves energy, can adjust the clamping height and is driven to lift the press arm through oil pressure when the workpiece is loosened.

The invention discloses a phosphor-silicon-containing aggregated flame retardant and a preparation method thereof. The preparation method comprises the following steps: adding 10-(2,5-dihydroxy phenyl)-9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and an acid-binding agent into a reactor loaded with a burette, a condensing tube and a nitrogen protection device, heating to 40 to 100 DEG C; weighing R1, R2-dichlorosilane, adding a solvent, and adding the mixture into the burette; adding the mixture at the temperature of 40 to 100 DEG C dropwise, and performing a thermal reaction for 2 to 10 hours after finishing of dropping; adding a precipitant, performing suction filtration, washing filter cakes with the precipitant, and drying to obtain the phosphor-silicon-containing aggregated flame retardant. The phosphor-silicon-containing aggregated flame retardant has high phosphor content and silicon content, abundant carbon sources, high char forming characteristic, superior flame retardance and thermal stability, and can be applied to high-molecular materials such as flame-retardant polypropylene, polystyrene and epoxy resin.

A method and system for the purification and recycle of impure argon is disclosed. The system and process of the present invention can produce very high purity argon, i.e., about 1 ppb or less of impurities. In one embodiment of the invention, a cryogenic separation apparatus is used to remove the nitrogen, hydrocarbon, and hydrogen impurities from the argon stream. A catalyst bed is then operated at ambient temperature to remove hydrogen, oxygen, and carbon monoxide impurities to provide the purified argon product. Also disclosed is a method to minimize to loss of the purified argon product during regeneration of the catalyst bed.

The invention provides a combined treatment method of leachate and excrement wastewater due to high contents of organic matters and phosphor but insufficient nitrogen in the excrement wastewater and high contents of organic matters and nitrogen but insufficient phosphor in the leachate. Therefore, nitrogen and phosphor in the excrement wastewater and leachate are complemented with each other, nutrient elements required by microbes are balanced, and a biological treatment method is suitable for treatment. According to the method, biological treatment, membrane separation treatment and reverse osmosis deep treatment are adopted, so that the treated discharge water is in accordance with the first-grade requirement of the GB8978-1996 Comprehensive Sewage Discharge Standard of People's Republic of China.

The invention relates to a preparation method of solid carbon dot fluorescent powder with high quantum yield. The preparation method comprises the following steps: weighing raw materials according tothe following constituents in parts by weight: 0.25 to 1 part of potassium hydrogen phthalate, 0.5 part of sodium azide and 0.25 to 1 part of boric acid; mixing the raw materials, then dissolving themixture in a formaldehyde solution ultrasonically, putting the mixed solution in a microwave oven for heating at the power of 225 to 750 W for 4 to 10 min, and completely evaporating the liquid at theend of reaction to obtain white powder which is nitrogen and boron-doped carbon dots (NBCDs). The preparation method is low in cost, high in preparation speed and easy to operate; the quantum yield (QY) of the prepared solid luminous NBCSs is extremely high, and the absolute solid luminous QY of the NBCSs is 67.7 percent.

The invention provides a slow-release compound fertilizer, which is a spherical or near-spherical granular compound fertilizer having a layered structure, wherein the innermost layer is a nitrogenous fertilizer layer; the intermediate layer is a potassic fertilizer layer; the outer layer is a mineral layer containing phosphorus; proportions of nitrogen, phosphorus and potassium are determined according to thicknesses of the fertilizer layers. The invention further provides a production method of the slow-release compound fertilizer. Tailing pulp is generated after heavy metals, manganese and iron are recycled from leached residues of production enterprises for electrolyzing manganese metal and manganese dioxide. The production method comprises the following steps of: adding flocculating agent, the weight of which is 0.01-0.02% of that of tailing mud, into the obtained tailing pulp, carrying out filter pressing by using a belt filter press, wherein the moisture content of filtered mud is 40-50%; and then, adding phosphatic fertilizer into the filtered mud, uniformly mixing, and carrying out calendering forming three times and roller-crushing calendaring granulating once by adopting a fertilizer granulator and drying to obtain the slow-release compound fertilizer.

The invention discloses a romaine lettuce soilless culture nutrient liquid. The romaine lettuce soilless culture nutrient liquid consists of the following components in parts by mass: 250-350 parts of rice washing water, 2-5 parts of urea, 1-5 parts of calcium nitrate, 1-5 parts of potassium nitrate, 1-3 parts of monopotassium phosphate, 1-6 parts of potassium sulfate, 0.5-2 parts of magnesium sulfate, 0.1-0.5 part of chelated iron, 0.2-2 parts of borax, 1-5 parts of sodium molybdate, 2-8 parts of elecampane, 1-5 parts of poria cocos and 1-3 parts of alum. The rice washing water used by the romaine lettuce soilless culture nutrient liquid is rich in nitrogen, phosphor, potassium and various trace elements needed for the growth of romaine lettuce; the elecampane and the poria cocos can be added to promote the romaine lettuce to evenly and comprehensively absorb trace elements, and to promote the growth and the root system development of the romaine lettuce, so that the plant resistance is strengthened, the occurrence of physiological diseases is prevented; the nutrition of the romaine lettuce soilless culture nutrient liquid well exceeds nutrients which can be provided by the soil, and thus, the romaine lettuce soilless culture nutrient liquid is relatively beneficial to the growth of the romaine lettuce; and the grown romaine lettuce is completely filled, crisp and tasty in fruit, bright-colored in lettuce leaf and good in quality.

The invention relates to a method for preparing material pellets in the production of a vanadium-nitrogen alloy. The method comprises the following steps of: mixing a solid vanadium raw material with a solid reducer in a proportion of 8: (1-3): 1 in a dry powder mixing machine for 40-70min, and then adding a liquid binder to a wet mixing machine and mixing for 90-150min, wherein the addition amount of the liquid binder is 3-8 percent of the total amount of the solid vanadium raw material and the solid reducer; and then pressing and pelletizing by two speed-adjustable forming machines which are connected in series. By carrying out dry mixing on the raw material before wet mixing, the uniformity of the raw material is greatly increased, and the pelletizing quality and the product grade of the finished product are improved; and qualified pellets can be obtained in a such way that the two forming machines work in series at an once working process, thus a continuous working mechanism is formed and the pelletizing efficiency is increased.

The invention provides soil ecological system restoring organic fertilizer which is high in content of nutrients available for crops and reasonable in nutrition collocation, is thoroughly decomposed, has a small number of foreign microbes and is high in organic matter content. The soil ecological system restoring organic fertilizer comprises organic raw materials, microbial agents and NPK, wherein the organic raw materials comprise cake fertilizer, green manure, plant protein and biochemical humic acid; the microbial agents comprise nine microbial bacteria such as nitrogen-fixing bacteria, phosphorus-solubilizing bacteria, potassium-releasing bacteria, actinomycetes, saccharomycetes, lactic acid bacteria, photosynthetic bacteria, paenibacillus polymyxa and bacillus subtilis; the NPK accounts for 5-25% of the total fertilizer; the NPK comprises ammonium sulfate, ammonium chloride, ammonium nitrate phosphate, ammonium phosphate, potassium sulfate, potassium chloride, potassium nitrate, magnesium sulfate, zinc sulfate and borax; the organic raw materials are taken as the balance of the fertilizer.

The invention discloses a lithium air battery catalyst based on metal organic frameworks (MOFs), and a method for preparing the lithium air battery catalyst. The catalyst consists of a transition metal complex and MOFs carriers, wherein the transition metal complex is obtained by reacting cobalt salt or manganese salt with a nitrogen-containing ligand. After being applied to a lithium air battery, the catalyst is high in catalytic activity and high in stability. By using the low-cost nitrogen-containing ligand as a raw material, the catalyst has the advantages of simple preparation process, low preparation cost and the like.

The invention discloses a flame-retardant polybutylene terephthalate (PBT) composite material, which is prepared by taking a mixture of montmorillonite and polytetrafluoroethylene as an organic synergistic flame retardant and cooperating with a nitrogen containing flame retardant, and a preparation method thereof. The composite material comprises the following components in percentage by weight: 45-70 percent of polybutylene terephthalate, 1-10 percent of nano-sized organic montmorillonite and 10-30 percent of glass fiber which is subjected to surface treatment, and 10-30 percent of nitrogen containing flame retardant, wherein the nano-sized organic montmorillonite is montmorillonite mineral powder processed by an alkyl intercalating agent; and the glass fiber is alkali-free glass fiber processed by a coupling agent. The preparation method comprises the following steps of mixing the components, antioxidant and lubricating agent; melting, blending and extruding the mixture by a double-screw extruder to obtain the polybutylene terephthalate composite material which has high performance and is synergistically filled by montmorillonite and glass fiber. The composite material is high in modulus, good in toughness, high in temperature resistance and high in CTI value; the processing environment is friendly; the composite material are free of halogen and phosphorus, meets an ROSH (The Restriction of the use of Certain Hazardous Substances in Electrical and Electronic Equipment) principle, and is widely applied to the field of engineering plastics.

The invention discloses a method for lowering the content of nitrogen metabolism hazard materials in soy sauce through compound bacteria, and belongs to the technical field of microorganisms. By meansof combined fermentation of staphylococcus xylosus and Tetragenococcus halophilus, by lowering accumulation of biogenic amine and ethyl carbamate, the nitrogen metabolism hazard materials in soy sauce are controlled. In the soy sauce fermentation process, when soy sauce is mixed with finished koji and saline water according to the ratio of 1:1, when staphylococcus xylosus and Tetragenococcus halophilus are inoculated at the same time for fermentation, the total biogenic amine content in the finished soy sauce can be lowered by 64.2%, the content of ethyl carbamate is lowered by 77.2%, and meanwhile the amino nitrogen is increased by 61.1%.

A preparation method of polysilazane for preparation of SiCN nonoxide ceramic fibre relates to a preparation method of high molecular weight polysilazane. According to the method, a protective measure is taken by introducing nitrogen into a reaction system; a repetitive ammonolysis reaction is carried out on reaction products from the first step to ensure that the reaction in the first step is completely finished so as to raise reaction yield; and based on the products from the first step, activated thermopolymerization is carried out for intermolecular crosslinking so as to obtain high molecular weight polysilazane. By a systematic desensitization method, hydrolysis of raw materials, methyl hydrogen-dichlorosilane and methyl vinyldichloridesilane, which are sensitive to water and the air, is prevented so as to guarantee that the reactions can be carried out smoothly, and the purpose of raising quality and yield of the low polymer product is achieved. By a repetitive reaction method, the ammonolysis reaction is more thoroughly completed so as to achieve the purpose of uniform molecular weight of the low polymer. By the activated thermopolymerization method, intermolecular crosslinking of the low polymer is realized to form a high polymer so as to achieve the purpose of obtaining the high molecular weight PSZ (200,000).

An integrated apparatus for separating a mixture of carbon dioxide and at least one other gas and for separating air by air distillation is provided. The apparatus includes a CO₂ separation unit configured to separate the mixture, an air separation unit configured to separate air by cryogenic distillation, a water cooling tower that operates by direct contact, a line for sending water to the top of the tower, a line for sending at least one portion of the nitrogen-enriched gas stream to a lower level of the tower, a cooled water line for withdrawing cooled water from the tower and means for cooling the air upstream of the air separation unit, the cooled water line being connected to means for cooling the air upstream of the air separation unit and to the inlet and/or to the outlet of the unit for separating the gaseous mixture.

The invention provides graphene-based hierarchical pore capacitor carbon and a preparation method thereof. The preparation method comprises the following steps: water-soluble sugar and a graphenes substance are subjected to a hydro-thermal reaction, a cross-linking agent is added during a reaction process, an activator is added after the reaction is complete, and then the materials are subjected to a carbonization reaction to obtain the product. The cross-linking agent is a nitrogenous foaming agent, and the activator is selected from one or more of potassium hydroxide, sodium hydroxide, zinc chloride and phosphoric acid. According to the invention, stacking and agglomeration of the graphene can be inhibited with a larger degree, the specific surface area and amount of porosity are increased, and the specific surface area utilization rate and specific capacitance are increased.