Graphene-based hierarchical pore capacitor carbon and preparation method thereof as well as capacitor

A graphene and capacitive carbon technology, which is applied in graphene, hybrid capacitor electrodes, chemical instruments and methods, etc., can solve the problems of not fully exerting the effects of cellulose and graphene, and the specific capacitance value needs to be improved, so as to achieve enhanced mechanical stability. properties, improve overall strength and stability, and increase the effect of specific area

Inactive Publication Date: 2017-03-01
山东圣泉新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology involves making materials called Graphene hydrocracked from water solvable sugars like glucose or fructoses. These liquids help dissolve some atoms inside them while still allowing certain parts (such as carboxyl groups) to bond together tightly within their lattichthal plane. By doing this they form tiny holes around each atom, resulting in better conductivity than traditional methods without these gases. Additionally, there are different ways how to chemically modify the properties of the materials themselves during production. Overall, this new method allows for more efficient use of resources and improved performance compared to previous techniques.

Problems solved by technology

Technological Problem: Current Li ion battery chemistries use expensive metals like cathode active metal powder or tantum, while Lithium secondary cells require higher specific capacities compared to traditional ones such as LC and EDLC. To improve these technical problem addressed in this patents, researchers aim towards developing highly effective and durably charged composite negative elecurbs that can store and release sufficient amounts of charges during chargings without losing them over time.

Method used

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  • Graphene-based hierarchical pore capacitor carbon and preparation method thereof as well as capacitor
  • Graphene-based hierarchical pore capacitor carbon and preparation method thereof as well as capacitor

Examples

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preparation example

[0045] Graphene-like substances can be prepared by the following methods, but are not limited to the following methods:

[0046] Prepare the cellulose first:

[0047] (1) After the wheat straw is pulverized and pretreated, use the organic acid solution whose total acid concentration is 80wt% formic acid and acetic acid to cook the treated wheat straw, the quality of acetic acid and formic acid in the organic acid solution of the present embodiment Ratio is 1:12, and before adding raw material, add the hydrogen peroxide (H 2 o 2 ) as a catalyst, control the reaction temperature at 120°C, react for 30min, and have a solid-liquid mass ratio of 1:10, and carry out the first solid-liquid separation of the obtained reaction solution;

[0048] (2) the solid that solid-liquid separation obtains for the first time is added the organic acid liquid that total acid concentration is 75wt% formic acid and acetic acid to carry out acid washing, wherein the organic acid solution that above-men

Embodiment 1

[0064] A preparation method of a three-dimensional graphene-based capacitor carbon with a hierarchical pore structure, comprising the steps of:

[0065] (1) 1g of graphene A is dissolved in water, and ultrasonically obtains a uniformly dispersed graphene aqueous solution;

[0066] (2) Add 25g of soluble starch, stir, and sonicate to obtain a mixed and uniform solution;

[0067] (3) Add the above mixed solution into the high-pressure polytetrafluoroethylene hydrothermal reaction kettle, set the temperature to 160°C for reaction, and gradually add 5g of hexamethylenediamine when the temperature reaches 160°C, and start stirring, and then turn off the stirring after completion, Hydrothermal reaction for 6 hours; natural cooling to room temperature, suction filtration and washing of the solid-liquid mixture in the reactor to obtain multidimensional graphene-based capacitor carbon;

[0068] (4) Mix the multi-dimensional graphene-based capacitor carbon with 80gKOH evenly, and activate

Embodiment 2

[0071] The difference from Example 1 is that the graphene-like substance is graphene oxide A.

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Abstract

The invention provides graphene-based hierarchical pore capacitor carbon and a preparation method thereof. The preparation method comprises the following steps: water-soluble sugar and a graphenes substance are subjected to a hydro-thermal reaction, a cross-linking agent is added during a reaction process, an activator is added after the reaction is complete, and then the materials are subjected to a carbonization reaction to obtain the product. The cross-linking agent is a nitrogenous foaming agent, and the activator is selected from one or more of potassium hydroxide, sodium hydroxide, zinc chloride and phosphoric acid. According to the invention, stacking and agglomeration of the graphene can be inhibited with a larger degree, the specific surface area and amount of porosity are increased, and the specific surface area utilization rate and specific capacitance are increased.

Description

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Claims

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Application Information

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Owner 山东圣泉新能源科技有限公司
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