Method for preparing carbon adsorbing material used for efficiently removing harmful ions from waste water

An adsorption material and carbon-based technology, which is applied in the preparation field of hydrothermal carbonization, can solve the problems of poor adsorption effect of mercury and other metals, difficult recovery and reuse, poor selectivity, etc., and achieves low cost of raw materials, excellent effect and good stability. Effect

Inactive Publication Date: 2011-09-14
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This technology uses cheaply available sugars like glucose syrup for making high purity carboxylic acids called charcoal that have strong affinity towards other metals. These carriers also contain oxygen atoms attached through chemical bonds between them. By reacting these molecules together under certain temperatures and pressures, they become more stable than traditional absorbents made from synthetic resins. They provide an effective way to remove harmful substances without causing damage on their own body when used alone.

Problems solved by technology

Technological Problem addressed by this patented technical problem involves finding ways to improve the ability of certain types of absorbents (such as charcoal) used in treating polluted waters without causing negative effects like health hazards due to their low specificity towards different kinds of metallics found naturally within our bodies' cells).

Method used

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  • Method for preparing carbon adsorbing material used for efficiently removing harmful ions from waste water
  • Method for preparing carbon adsorbing material used for efficiently removing harmful ions from waste water
  • Method for preparing carbon adsorbing material used for efficiently removing harmful ions from waste water

Examples

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Effect test

Embodiment 1

[0014] Weigh 6g of glucose and 1g of thioglycolic acid, mix the two evenly, add appropriate amount of water, place in a stainless steel autoclave lined with polytetrafluoroethylene, and react in an oven at 180°C for a period of time. Take out and cool, grind the obtained solid substance, wash with deionized water and ethanol, filter with suction, and dry the obtained product overnight. The content of surface carboxyl groups measured by acid-base titration is 4.13mmol / g. The content of S was found to be 2.63mmol / g by EDS analysis. The adsorption capacity for adsorbing Hg(II) ions at pH=1.5 is 300 mg / g.

Embodiment 2

[0016] Weigh 6g of furfural and 3g of cysteine, mix the two evenly, add appropriate amount of water, place in a stainless steel autoclave lined with polytetrafluoroethylene, and react in an oven at 180°C for a period of time. Take out and cool, grind the obtained solid substance, wash with deionized water and ethanol, filter with suction, and dry the obtained product overnight. The content of surface carboxyl groups measured by acid-base titration is 4.30mmol / g. The content of S was found to be 4.0 mmol / g by EDS analysis. The adsorption capacity for adsorbing lead ions at pH=6 is 145mg / g.

Embodiment 3

[0018] Weigh 6g of sucrose and 1g of lysine, mix the two evenly, add appropriate amount of water, place in a stainless steel autoclave lined with polytetrafluoroethylene, and react in an oven at 200°C for a period of time. Take out and cool, grind the obtained solid substance, wash with deionized water and ethanol, filter with suction, and dry the obtained product overnight. The content of amino groups on the surface was determined to be 2.2 mmol / g by acid-base titration. The adsorption capacity for Cu(II) ions is 130 mg / g when pH=4, and the adsorption capacity for chromate is 200 mg / g when pH=7.

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Abstract

The invention belongs to the technical field of adsorbing agents and relates to a method for preparing a carbon adsorbing material used for efficiently removing harmful ions from waste water. The method comprises the following step: on the basis of taking the soluble saccharide or furfural as a carbon source and the amino acid or compound containing sulfydryl, carboxyl or amino group as an additive, performing the hydro-thermal reaction on the carbon source and the additive at 160-220 DEG C, thereby generating the carbon solid adsorbing material. The adsorbing material can be used for processing heavy metal ions or transition metal ions in industrial effluent and domestic sewage and the processing effect is excellent. The method has the advantages that the soluble saccharide or furfural is used as a raw material for preparing the carbon solid adsorbing material, the cost of the raw material is low, the preparation process is simple, the solid adsorbing material is synthesized through one step of hydro-thermal reaction, the reaction condition is mild and controllable, and the solid adsorbing material prepared by using the method has excellent stability and contains a large amount of surface groups. The content of the surface groups can be controlled within a large scope without changing the reaction condition. The surface groups have strong interaction with the metal ions, such as sulfydryl and mercury ions, so that the carbon adsorbing material can be used for efficiently removing the harmful ions.

Description

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Claims

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Application Information

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Owner EAST CHINA UNIV OF SCI & TECH
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