A kind of preparation method of temperature-resistant, salt-resistant nano oil displacement agent

An oil displacement agent and salt-resistant technology, which is applied in the field of nano functional materials for oil and gas fields to enhance oil recovery, can solve the problems of losing the advantages of nanoparticle oil displacement, easy shedding of surface polymers, easy aggregation of nanoparticle, etc., and achieve low cost , simple preparation method and easy preparation process

Active Publication Date: 2016-03-30
HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows for improved stability when used alone or together with other agents like water injection (waterflood) techniques without losing their effectiveness over time due to changes made during use that could affect them. It also simplifies the manufacturing processes while maintaining high efficiency compared to current methods such as adding various substances into solutions containing these particles. Overall, this new type of material provides better results than existing products on certain types of wells.

Problems solved by technology

Technological Problem addressed in this patents relates to improving the efficiency of recovering petroleum resources while reducing environmental impact caused by drilling operations or other methods like water injection techniques. Current technologies involve adding surfactants/polymers to improve fluid mobility but they also cause damage to certain types of materials found near wellbore locations where hydrocarbon production occurs. To address these issues, new ways were proposed involving modification of surfaces made of different material compositions called microscale silicate systems. These modified microspheres exhibit improved properties compared to existing ones without any modifications at all.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] In a three-necked flask, add 20 g of nano silicon dioxide and 12 mL of vinyltrimethoxysilane coupling agent, and stir for 3 hours. Weigh 18g of acrylamide and dissolve it in 125mL of water. After it is completely dissolved, add the above mixing system, add 1.2g of potassium persulfate, raise the temperature to 65°C, and react for 3 hours to obtain polyacrylamide-modified silica nanoparticle dispersion liquid;

[0023] Add 18g of sodium hydroxide and 20g of sodium lauryl sulfate to the polyacrylamide-modified silica nanoparticle dispersion prepared above in sequence, and stir for 4 hours at room temperature to obtain a temperature-resistant and salt-resistant Nano oil displacing agent.

Embodiment 2

[0025] In a three-necked flask, add 15 g of nano silicon dioxide and 8 mL of vinyltriethoxysilane coupling agent, and stir for 3 hours. Weigh 25g of acrylamide and dissolve it in 180mL of water. After it is completely dissolved, add the above-mentioned mixing system, add 1.8g of potassium persulfate, raise the temperature to 75°C, and react for 4 hours to obtain a polyacrylamide-modified silica nanoparticle dispersion liquid;

[0026] Add 28g of sodium carbonate and 15g of sodium lauryl sulfate into the above-prepared polyacrylamide-modified silica nanoparticle dispersion in sequence, and at room temperature for 5 hours, a temperature-resistant and salt-resistant nano-flooding Oil agent.

Embodiment 3

[0028] Into a three-necked flask, 18 g of nano-silica and 12 mL of γ-methacryloxypropyltrimethoxysilane coupling agent were added, and stirred for 3 hours. Weigh 29g of acrylamide and dissolve it in 175mL of water. After it is completely dissolved, add the above-mentioned mixing system, add 1.2g of potassium persulfate, raise the temperature to 75°C, and react for 5 hours to obtain a polyacrylamide-modified silica nanoparticle dispersion liquid;

[0029] Add 23g of potassium carbonate and 19g of sodium dodecylsulfonate in sequence to the above-prepared polyacrylamide-modified silica nanoparticle dispersion, and at room temperature for 5 hours, the temperature-resistant and salt-resistant nanoparticle oil repellant.

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Abstract

The invention provides a preparation method of a temperature-resistant and salt-tolerant nano oil displacement agent. The preparation method comprises the following steps: modifying polyacrylamide to surfaces of silica nanoparticles through chemical bonds to obtain nano-composite particles with stable performance, and then using the nano-composite particles together with alkali and a surfactant to prepare the nano oil displacement agent. The nano oil displacement agent can solve the problem about high possibility of falling off of a polymer on the surface of a traditional nano oil displacement agent in the formation moving process, so as to achieve an excellent oil displacement effect. Especially in the high-temperature and high-salt formation, the nano oil displacement agent can overcome harsh formation conditions and cannot reduce the oil displacement effect.

Description

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Claims

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Application Information

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Owner HENAN ZHENGJIA ENERGY ENVIRONMENTAL PROTECTION CO LTD
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