EPDM/polypropylene thermoplastic elastomer and preparation process thereof

A thermoplastic elastomer, EPDM technology, which is applied in the field of resource reuse of waste tires (waste EPDM), can solve the problem that it is difficult to meet the requirements of activation treatment, affect the effect of subsequent processes, and cannot achieve Activation requirements and other issues, to achieve the effect of expanding a wide range of hardness changes, excellent toughening, and improving plasticity and elasticity

Active Publication Date: 2014-04-30
辽宁瑞德橡塑科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the method of using waste tires (waste EPDM rubber) to prepare thermoplastic elastomers is to first crush them into vulcanized rubber powder, and then blend them with other polymers, and their properties are very different from those of unvulcanized rubber. , the vulcanized rubber powder obtained by crushing waste rubber products, its structure is still a network structure of three sulfur bond states of monosulfide, disulfide and polysulfide formed at the crosslinking point of vulcanized rubber. Linked, physical coagulated random polymer elastomers, when blended with other polymers, have poor compatibility with the blended matrix material, and the blended system with plastic materials is

Method used

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  • EPDM/polypropylene thermoplastic elastomer and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049]The material formula consists of: PP (F401), recycled PP, plasticized rubber powder, naphthenic oil, POE, 1250 mesh talc, antioxidant 1010, PE wax, butyl methacrylate, DCP; among them, plasticized rubber The powder is obtained by pretreatment of waste EPDM rubber powder (containing more than 40% of glue), and the pretreatment formula is composed of the following components in parts by weight: 80 mesh waste EPDM rubber powder, solid coal tar, rubber Activator 420, surfactant TAIC, 1250 mesh talc. See Table 1 for specific parts by weight.

[0050] Preparation process: (1) First, put the waste EPDM rubber powder into the high mixer for 1400 rpm treatment, when the temperature rises to 80 degrees, add solid coal tar, activator, surfactant, continue stirring, and wait for the rubber powder to dissolve. The temperature was raised to 150 degrees, talc was added, quenched to room temperature, and sealed for later use. (2) Then add PP raw material, POE, naphthenic oil, antioxidant

Embodiment 2

[0059] The material formula consists of: PP (F401), plasticized rubber powder, naphthenic oil, POE, 1250 mesh talc, antioxidant 1010, PE wax, butyl methacrylate, DCP, anti-ultraviolet additive UV-9; Wherein, the plasticized rubber powder is obtained from waste EPDM rubber powder (with a rubber content greater than 40%) through pretreatment, and the pretreatment formula is composed of the following components in parts by weight: 80 mesh waste EPDM rubber powder, Solid coal tar, rubber activator 450, surfactant silane coupling agent 602, 1250 mesh talc. See Table 1 for specific parts by weight.

[0060] Preparation process: (1) First, put the waste EPDM rubber powder into the high mixer for 1400 rpm treatment, when the temperature rises to 80 degrees, add solid coal tar, activator, surfactant, continue stirring, and wait for the rubber powder to dissolve. The temperature was raised to 150 degrees, talc was added, quenched to room temperature, and sealed for later use. (2) Then ad

Embodiment 3

[0067] The material formula is composed of: recycled PP, plasticized rubber powder, naphthenic oil, POE, 1250 mesh talc, antioxidant 1010, PE wax, butyl methacrylate, DCP, sericite; among which, the plasticized rubber powder is composed of Waste EPDM rubber powder (containing more than 40% of glue) is obtained through pretreatment, and the pretreatment formula is composed of the following components in parts by weight: 80 mesh waste EPDM rubber powder, solid coal tar, rubber activator 480, surfactant (oleic acid), 1250 mesh talc. See Table 1 for specific parts by weight.

[0068] The preparation process is the same as that of Example 1.

[0069] Table 1 Material components, pretreatment formulations and their physical and mechanical properties used in each example

[0070]

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Abstract

The invention relates to an EPDM (Ethylene-Propylene-Diene Monomer)/polypropylene thermoplastic elastomer and a preparation process thereof. The EPDM/polypropylene thermoplastic elastomer is characterized by comprising the following components in parts by weight: 1065-1250 parts of PP (Poly Propylene ) raw material, 150-550 parts of plasticized rubber powder, 60-80 parts of naphthenic oil, 80-180 parts of POE (Poly Olefin Elastomer), 100-150 parts of 250-mesh talcum powder, 3-7 parts of antioxidant 1010, 10-30 parts of PE (Poly Ethylene) wax, 15-45 parts of butyl methacrylate and 4.5-15 parts of DCP, wherein the plasticized rubber powder is obtained from the waste ethylene -propylene-diene monomer powder through preprocessing, and a formula for the preprocessing includes 1500 parts by weight of 80-mesh waste ethylene -propylene-diene monomer powder, 100-200 parts by weight of solid coal tar, 5-10 parts by weight of activator, 20-40 parts by weight of surfactant and 20-40 parts by weight of 1250-mesh talcum powder. The thermoplastic elastomer is wide in hardness change range, high in strength, and remarkably improved in physical and mechanical properties.

Description

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Claims

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Application Information

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Owner 辽宁瑞德橡塑科技有限公司
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