Auxiliary agent component-containing boehmite and/or pseudo boehmite, and applications thereof

A boehmite, additive-containing technology, applied in alumina/aluminum hydroxide, catalyst carrier, other chemical processes, etc., can solve the problem of alumina specific surface area, pore volume reduction, pseudo-boehmite or thin water The problems such as the increase of bauxite grains can achieve the effect of realizing grain growth, improving relative crystallinity and inhibiting the growth of grains.

Active Publication Date: 2015-08-26
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new modification process improves how well it prevents growing tiny particles called cocrystals that form during production processes such as sintering or burning ceramic materials like porcelain powder at very low temperatures (<400°C). By controllably modifying these modifications, this improvement allows for increased particle size without compromising their overall properties.

Problems solved by technology

This patented technical problem addressed in this patent describes how improving the quality and efficiency of producing highly porous materials like zirconia can be achieved through modifying certain aspects of these materials during manufacturing processes.

Method used

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  • Auxiliary agent component-containing boehmite and/or pseudo boehmite, and applications thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] Alumina hydrate containing auxiliary agent provided by the invention and preparation thereof:

[0069] Weigh 364 grams of CL-A powder and 110 grams of CL-A-600 powder on a dry basis (the mass ratio of CL-A-600 powder to CL-A powder on a dry basis is 0.30), and combine them with Mix 3600 grams of deionized water, add 10.78 grams of ammonium dihydrogen phosphate, and stir to form a slurry; transfer the slurry to a stainless steel autoclave with a stirring volume of 5 liters and a Teflon liner, and heat it to 160 ℃ for 4 hours; after cooling down to room temperature and filtering, the filter cake was dried at 120 ℃ for 8 hours to obtain hydrated alumina Q-S1 containing additives. The crystal phase, crystallinity and grain size were characterized by X-ray diffraction method, and the results are listed in Table 1.

[0070] Formed alumina provided by the invention and its preparation:

[0071] Q-S1 was extruded into a clover-shaped strip with a circumscribed circle diameter of

Embodiment 2

[0073] Alumina hydrate containing auxiliary agent provided by the invention and preparation thereof:

[0074]Weigh 235 grams of CL-A powder and 296 grams of CL-A-600 powder on a dry basis (the mass ratio of CL-A-600 powder to CL-A powder on a dry basis is 1.26), and weigh them Mix with 3600 grams of deionized water, and add 12.08 grams of ammonium dihydrogen phosphate, and stir to form a slurry; transfer the slurry to a stainless steel autoclave with a stirring volume of 5 liters and a Teflon liner, and heat it to Constant temperature at 160°C for 4 hours; after cooling down to room temperature and filtering, the filter cake was dried at 120°C for 8 hours to obtain hydrated alumina Q-S2 containing additives. The crystal phase, crystallinity and grain size were characterized by X-ray diffraction method, and the results are listed in Table 1.

[0075] Formed alumina provided by the invention and its preparation:

[0076] Q-S2 is extruded into a clover-shaped strip with a circumsc

Embodiment 3

[0078] Alumina hydrate containing auxiliary agent provided by the invention and preparation thereof:

[0079] Weigh 126 grams of CL-A powder and 453 grams of CL-A-600 powder on a dry basis (the mass ratio of CL-A-600 powder to CL-A powder on a dry basis is 3.60), and add 13.21 grams of ammonium dihydrogen phosphate, mix them with 3600 grams of deionized water and stir to form a slurry; transfer the slurry to a stainless steel autoclave with a stirring volume of 5 liters and a Teflon liner, heat it to 160 ℃ for 4 hours; after cooling down to room temperature and filtering, the filter cake was dried at 120 ℃ for 8 hours to obtain hydrated alumina Q-S3 containing additives. The crystal phase, crystallinity and grain size were characterized by X-ray diffraction method, and the results are listed in Table 1.

[0080] Formed alumina provided by the invention and its preparation:

[0081] Q-S3 is extruded into a clover-shaped strip with a circumscribed circle diameter of 1.6 millimete

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Abstract

The invention relates to auxiliary agent component-containing boehmite and/or pseudo boehmite, and applications thereof, wherein the mass fraction of the auxiliary agent component is 0.1-10% by adopting the dry basis to calculate and by adopting the auxiliary agent component-containing boehmite and/or pseudo boehmite as the reference, and the auxiliary agent component is one or a plurality of materials selected from group IIIA, group IVA, group VA, group VIIA, group IIA, group IIB, group IIIB, and group IVB. The preparation method comprises: (1) roasting at least an alumina hydrate; (2) mixing the roasted product obtained in the step (1), at least a boehmite and/or pseudo boehmite, an auxiliary agent component-containing compound, and water to obtain a mixture; (3) carrying out a hydrothermal treatment on the mixture obtained in the step (2) in a sealed reactor; and (4) drying the product obtained in the step (3). The auxiliary agent component-containing boehmite and/or pseudo boehmite can be used as the raw material for preparing the formed alumina carrier and the adsorbent.

Description

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Claims

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Application Information

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Owner CHINA PETROLEUM & CHEM CORP
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