Process and apparatus for the polymerisation of olefins

Active Publication Date: 2016-07-19
INEOS SALES (UK) LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The fouling is a result of continuing polymerisation under non-favourable conditions (particles at rest with poor heat exchange), and manifests itself most severely as increases in pressure drop through heat exchangers and other components, and reductions in heat trans

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  • Process and apparatus for the polymerisation of olefins
  • Process and apparatus for the polymerisation of olefins

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[0017]In contrast, the present Applicants have now been able to operate a polymerisation process which is characterised by negligible fouling rates, even though some fine particles are present in the recycle stream. Such processes do not require shut-down to clean heat exchangers, even after several years of operation.

[0018]Thus, in a first aspect the present invention provides a process for the gas phase polymerisation of olefins in a fluidised bed reactor, which process comprises:[0019]a) passing a fluidising gas comprising one or more olefin monomers through a fluidised bed of polymer particles in the presence of a polymerisation catalyst,[0020]b) withdrawing a first gaseous stream comprising solid particles from the top of the reactor,[0021]c) passing the first gaseous stream to a gas / solids separator, separating solid particles therefrom, and forming a second gaseous stream comprising residual solid particles,[0022]d) passing at least a portion of the second gaseous stream to on

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Abstract

Process for gas phase polymerization of olefins in a fluidized bed reactor by (a) passing a fluidizing gas containing at least one olefin monomer through a fluidized bed of polymer particles in the presence of a polymerization catalyst to produce polymer at a polymer production rate of C Tonnes/hour, (b) withdrawing a first gaseous stream containing solid particles from the top of the reactor, (c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream containing residual solid particles, (d) passing a portion of the second gaseous stream to at least one heat exchanger to remove heat of reaction whereby residual solid particles contact the heat exchanger, and (e) recycling a portion of the cooled stream from step (d) as the fluidizing gas in step (a). The heat exchangers have a heat exchange surface area which totals less than 120×C m2.

Description

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Claims

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Application Information

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Owner INEOS SALES (UK) LTD
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