The invention belongs to the polyethylene oxide product production field, and particularly relates to a polymerization device in a production process of polyethylene oxide products; the polymerization device includes a polymerization kettle main body, a stirring device, a catalyst loading device, a shearing machine and a cooling device; the inner wall of the polymerization kettle main body is provided with at least four baffle plates along the circumference in a uniform distribution manner; the stirring device is arranged at a longitudinal central position of the interior of the polymerization kettle main body and adopts a three-layer push type stirring structure, wherein the length of first-layer stirring blades and second-layer stirring blades is 450 mm, and the length of third-layer stirring blades is 550 mm. Through special design of the baffle plates and the stirring device in the polymerization device, and through reasonable installation and use of the shearing machine, a phenomenon of local implosion generated by the reaction is avoided, so that the volume of the polymerization device is successfully amplified to 6000 L, and the production scale of the products is improved.