The invention discloses a preparing method of graphene luminous cutting-prevention flame-retardant firefighting gloves. The gloves are woven through one or more of aramid fiber 1414/graphene chinlon core-spun yarn, stainless steel wire/ aramid fiber 1414 coating yarn, luminous-green dacron DTY yarn, spandex-coated nylon dyed yarn and shirr; the woven gloves are impregnated through high-temperature-resistance and environment-friendly silica gel to obtain a finished product. The preparing technology is simple, the gloves can be produced on a large scale, and are high in cutting resistance, conductivity, flame retardance, static resistance, bacterial resistance, cutting resistance, fire resistance, skid resistance, and wearproof performance, and are comfortable and convenient to wear. The preparing method can be widely applied to special industries like equipment manufacturing and firefighting.