The invention provides a treatment method of chemical copper plating waste liquid. The method comprises the following steps: (1) mixing persimmon tannin and copper plating waste liquid to form a solution, and performing stirring reaction at the room temperature; (2) adding a water solution containing 25% of glutaraldehyde to the solution, adjusting the pH value, and then performing stirring reaction at the room temperature; (3) adjusting the pH value of the solution to make the persimmon tannin settled, filtered and dried, so as to obtain a solid; (4) carbonizing the obtained solid at high temperature, so as to obtain CuO. The treatment method of the chemical copper plating waste liquid has the following advantages that 1, the chemical copper plating waste liquid is treated by using the persimmon tannin, thereby realizing environmental protection and no pollution; 2, the cost is low, the operation is convenient, and the application effect is good; 3, Cu can be effectively recycled to make waste profitable. Therefore, compared with the prior art, the treatment method of the chemical copper plating waste liquid has a better treatment effect, improves the production rate, reduces the cost, and has a wide application prospect in the field of treatment of chemical plating waste liquid.