Macromolecular coated scale inhibitor for oil field and preparation method thereof

A polymer and antiscalant technology, applied in chemical instruments and methods, descaling and water softening, water/sludge/sewage treatment, etc., can solve the problem of low thermal stability of antiscalants, loss of antiscaling effect, To solve problems such as poor scale inhibition effect, achieve good sustained release effect, prolong the protection period, and achieve the effect of less dosage

Inactive Publication Date: 2016-01-13
无棣华信石油技术服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, scale inhibitors have poor scale inhibition effect at high temperature. The main reason is that general scale inhibitors have low thermal stability and are easily decomposed at high temperature and lose their scale inhibition effect.

Method used

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  • Macromolecular coated scale inhibitor for oil field and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0037] Example 1

[0038] A method for preparing a polymer film-coated scale inhibitor for oilfields includes the following steps:

[0039] Step (1), according to parts by weight, weigh out 0.02 parts of Polyporus umbellatus extract, 0.1 part of artemisinin, 13 parts of citric acid, 5 parts of sorbitol, 2 parts of 2-(diethanolamino)ethanesulfonic acid, 0.5 part of sulfosuccinate, 0.1 part of dehydroabietic acid, 10 parts of ethanol, 68 parts of water;

[0040] In step (2), the polyporus umbellatus extract, artemisinin and sulfosuccinate weighed in step (1) are added to ethanol and mixed uniformly to obtain mixed liquid A;

[0041] Step (3), add the citric acid, sorbitol, 2-(diethanolamino)ethanesulfonic acid and dehydroabietic acid weighed in step (1) to the water, and then heat to 40°C, then add step (2) ) The obtained mixture A is stirred at a speed of 50r / min until the mixture is uniform, and the mixture B is obtained;

[0042] Step (4), soak the porous chitosan microspheres in the

Example Embodiment

[0046] Example 2

[0047] A method for preparing a polymer film-coated scale inhibitor for oilfields includes the following steps:

[0048] Step (1), in terms of parts by weight, weigh out 0.04 parts of Polyporus umbellatus extract, 0.2 parts of artemisinin, 18 parts of citric acid, 10 parts of sorbitol, 5 parts of 2-(diethanolamino)ethanesulfonic acid, 0.8 parts of sulfosuccinate, 0.3 parts of dehydroabietic acid, 15 parts of ethanol, 83 parts of water;

[0049] In step (2), the polyporus umbellatus extract, artemisinin and sulfosuccinate weighed in step (1) are added to ethanol and mixed uniformly to obtain mixed liquid A;

[0050] In step (3), the citric acid, sorbitol, 2-(diethanolamino)ethanesulfonic acid and dehydroabietic acid weighed in step (1) are added to water, and then heated to 45°C, then added to step (2) 1) The obtained mixture A is stirred at a speed of 80r / min until the mixture is uniform, and the mixture B is obtained;

[0051] Step (4), soak the porous chitosan micr

Example Embodiment

[0055] Example 3

[0056] A method for preparing a polymer film-coated scale inhibitor for oilfields includes the following steps:

[0057] Step (1), weigh out 0.034 parts of Polyporus umbellatus extract, 0.14 parts of artemisinin, 15 parts of citric acid, 6 parts of sorbitol, 4 parts of 2-(diethanolamino)ethanesulfonic acid, 0.7 parts of sulfosuccinate, 0.22 parts of dehydroabietic acid, 13 parts of ethanol, 77 parts of water;

[0058] In step (2), the polyporus umbellatus extract, artemisinin and sulfosuccinate weighed in step (1) are added to ethanol and mixed uniformly to obtain mixed liquid A;

[0059] Step (3), add the citric acid, sorbitol, 2-(diethanolamino)ethanesulfonic acid and dehydroabietic acid weighed in step (1) to water, and then heat to 42°C, then add step (2) 1) The obtained mixture A is stirred at a speed of 60r / min until the mixture is uniform, and the mixture B is obtained;

[0060] Step (4), soak the porous chitosan microspheres in the mixed solution B, and after

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Abstract

The invention relates to a macromolecular coated scale inhibitor for an oil field and a preparation method thereof, and belongs to the petroleum additive technical field. The macromolecular coated scale inhibitor for the oil field is prepared with a polyporus umbellatus extract, artemisinin, citric acid, sorbitol, N,N-bis(2-hydroxyethyl)taurine, sulfosuccinate, dehydroabietic acid, ethanol and water as raw materials and through a series of steps. The macromolecular coated scale inhibitor has the advantages of good dispersing performance and excellent thermal stability, and also has good scale inhibition performance and corrosion inhibition performance at high temperature of 90 DEG C; through determination, the corrosion inhibition rate is more than or equal to 87% and the scale inhibition rate is more than or equal to 90% at the high temperature of 90 DEG C. The preparation method is simple, the raw materials contain no phosphorus, and the prepared macromolecular coated scale inhibitor for the oil field is friendly to environment, has less dosage during use, has the scale inhibitor adding amount of 15-18 mg/L, has relatively high calcium tolerance, and is prone to popularization and application.

Description

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Claims

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Application Information

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Owner 无棣华信石油技术服务有限公司
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