Stannic oxide-polyacid compound gas sensing material and preparation method thereof

A tin dioxide and composite sensing technology, applied in chemical instruments and methods, tungsten compounds, analytical materials, etc., can solve the problems of weakening of gas sensing detection signal, affecting electron transmission, unfavorable real-time monitoring of measured gas, etc.

Inactive Publication Date: 2016-07-06
NORTHEAST NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. In tin dioxide materials, after the electrons transition to the conduction band, the electrons and holes are easy to recombine, which affects the transmission of electrons, resulting in the weakening of the gas sensor detection signal

Method used

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  • Stannic oxide-polyacid compound gas sensing material and preparation method thereof
  • Stannic oxide-polyacid compound gas sensing material and preparation method thereof
  • Stannic oxide-polyacid compound gas sensing material and preparation method thereof

Examples

Experimental program
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Effect test

specific Embodiment 1

[0039] Put the interdigitated electrode with the composite film into a 500 ml airtight quartz bottle for testing, one of the gold electrodes of the interdigitated electrode is connected to the working electrode of the electrochemical workstation with a wire, the other gold electrode and the counter electrode and the reference connected to the electrodes. A voltage of 1V was applied between the two electrodes, and a stable photocurrent value was obtained under the irradiation of a xenon lamp. When 50ppm, 100ppm, 150ppm and 200ppm formaldehyde gas were injected into the quartz vial, the photocurrent between the two electrodes increased significantly. (see attached Figure 7 )

specific Embodiment 2

[0040] Put the interdigitated electrode with the composite film into a 500 ml airtight quartz bottle for testing, one of the gold electrodes of the interdigitated electrode is connected to the working electrode of the electrochemical workstation with a wire, the other gold electrode and the counter electrode and the reference connected to the electrodes. A voltage of 1V was applied between the two electrodes, and a stable photocurrent value was obtained under the irradiation of a xenon lamp. When 50ppm, 100ppm, 150ppm and 200ppm toluene gas were injected into the quartz vial, the photocurrent between the two electrodes increased significantly.

[0041] (see attached Figure 8 ).

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Abstract

The invention provides a stannic oxide-polyacid compound gas sensing material and a preparation method thereof. The prepared new polyacid-modified stannic oxide nano-rod material can be applied to a photoelectric gas sensor. The material is the stannic oxide-polyacid compound material which is formed by taking stannic oxide (SnO2) nano-rod as a main body and modifying with a cyanogen metal complex modified Dawson type phosphowolframate ((C4H10ON)23[HN(CH2CH2OH)3]10H2[FeIII(CN)6(alpha2-P2W17O61CoII)4].27H2O). Under room temperature environment and irradiation of a xenon lamp, the sensor has obvious sensing detecting property for toxic formaldehyde and methylbenzene gas. The preparation method for the stannic oxide-polyacid compound gas sensing material provided by the invention is simple and is fit for the development and production of a novel high-performance gas sensor.

Description

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Claims

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Application Information

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Owner NORTHEAST NORMAL UNIVERSITY
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