Porous solid ionic gel electrode and preparation method and application thereof

[0027] Example 1

[0028] (1) Weigh 9.1 g of double trifluoromethanesulfonyl amide and 7 ml of tetraned diol dimethyl ether in a glass bottle, and the sealing is stirred for 12 h to give a slightly viscous solvation ionic fluid.

[0029] (2) 3 ml of acrylate, 1 ml of ethoxyethoxyethyl escetyl ester, 2 ml of the above prepared solvate ionic fluid and 10 μl of polyethylene glycol diacrylate and 0.04 g of 1-hydroxycyclohexylphenyl group The ketone is added to the small glass bottle to stir, so that it is mixed uniform to obtain an ion gel precursor solution.

[0030] (3) Weighing 0.1 g of ammonium bicarbonate added to 2 mL of the above prepared ion gel precursor solution, stirred for 1 h, making it mixed uniform. Under the transparent mold of a pipette to a tracery film, then place the molded mold on the heater that has been preheated to 100 ° C, adjust the ultraviolet lamp to irradiate power, and select a gradient power irradiation mode. 10W was irradiated for 30 seconds, 5 W for 1 min

[0031] Example 2

[0032] (1) Weigh 5.2 g of double trifluoromethane sulfonylimide and 4 ml of tetranedethydrol dimethyl ether in a glass bottle, and the sealing is stirred for 12 h to give a slightly viscous solvate ionic fluid.

[0033] (2) 2.66 mL of propyl acrylate, 1.33 mL of ethoxyethoxyethyl escetyl escetyl ester, 2 ml of the prepared solvated ionic liquid and 10 μL of polyethylene glycol triacrylate and 1.25 g 1 - Hydroxy cyclohexylphenyl ketone is added to the small glass bottle to stir, so that it is mixed uniform to give an ion gel precursor solution.

[0034] (3) Weighing 0.1 g of ammonium bicarbonate added to 2 mL of the above prepared ion gel precursor solution, stirred for 1 h, making it mixed uniform. In the transparent mold of 1 ml to a tracery film with a pipette, the power of the ultraviolet lamp was 10 W under room temperature, and the solution was allowed to obtain a porous ion gel electrode after 2 minutes.

[0035] Example 3

[0036] (1) Weigh 6.5 g of double trifluoromethanesulfonazide dissolved in 5 ml of tetraned diol dimethyl ether, and the two chelate reactions, and release heat. After stirring at room temperature for 24 h, a solvated ionic liquid having a certain viscosity was obtained.

[0037] (2) 5 ml of hydroxyethyl acrylate, 5 ml of ethoxyethoxyethyl acrylate, 5 ml of the prepared solvated ionic liquid and 50 μl of polyethylene glycol diacrylate and 0.1 g 1-hydroxy cyclohexylphenyl group Methodophenone is added to a 20 ml small glass bottle in the sealing of the sealing, so that it is mixed to mix and give the ion gel precursor solution.

[0038] (3) Weighing 0.3 g of ammonium bicarbonate to 3 mL of the above prepared ion gel precursor solution, stirred for 1 h, so that it is mixed. Upper 1ml of 1ml into the transparent mold of the release film with a pipette, and then placed on a heating station with a solution to 100 ° C, adjusting the power of the ultraviolet lamp to 10W, a