Ternary metal catalyst with excellent chlorine resistance and efficient catalytic oxidation of mixed VOCs

[0015] Weigh 5.1120mg platinum acetylacetonate, add 2.5mL octadecene, 2.5mL oleylamine, 0.5mL oleic acid, stir and dissolve at room temperature for 20min, then add 49.3164mg ascorbic acid, continue stirring for 5-10min, then weigh 49.2660mg hexacarbonyl Add tungsten and 21.3110 mg triruthenium dodecacarbonyl into the mixed solution to finally form a mixed precursor solution, continue stirring at room temperature for 10-20 minutes, then put it into a reaction kettle, and react in an oven at 200 ° C for 8 hours. After cooling to room temperature, pour the reacted solution into a centrifuge tube, and centrifugally wash with a mixed solution of cyclohexane and ethanol for 3-4 times to obtain PtWRu ternary alloy nanoparticles. The prepared PtWRu ternary alloy nanoparticles were uniformly dispersed in about 10 mL of cyclohexane for storage. Using the adsorption method, a certain amount of r-TiO 2 The carrier was added to the cyclohexane solution containing nanocrystals, stirred for 6-

[0018] Weigh 5.1120mg platinum acetylacetonate, add 2.5mL octadecene, 2.5mL oleylamine, 0.5mL oleic acid, stir and dissolve at room temperature for 20min, then add 49.3164mg ascorbic acid, continue stirring for 5-10min, then weigh 49.2660mg hexacarbonyl Tungsten and 22.0060 mg of chromium hexacarbonyl were added to the mixed solution to finally form a mixed precursor solution. Stirring was continued at room temperature for 10-20 minutes, then loaded into a reaction kettle, and reacted in an oven at 200°C for 8 hours. After cooling to room temperature, pour the reacted solution into a centrifuge tube, and centrifugally wash with a mixed solution of cyclohexane and ethanol for 3-4 times to obtain PtWCr ternary alloy nanoparticles. The prepared PtWCr ternary alloy nanoparticles were uniformly dispersed in about 10 mL of cyclohexane for storage. Using the adsorption method, a certain amount of r-TiO 2 The carrier was added to the cyclohexane solution containing nanocrystals, stirred

[0021] Weigh 5.1120mg platinum acetylacetonate, add 2.5mL octadecene, 2.5mL oleylamine, 0.5mL oleic acid, stir and dissolve at room temperature for 20min, then add 49.3164mg ascorbic acid, continue stirring for 5-10min, then weigh 49.2660mg hexacarbonyl Add tungsten and 19.49885 mg of manganese decacarbonyl into the mixed solution to finally form a mixed precursor solution, continue stirring at room temperature for 10-20 minutes, then put it into a reaction kettle, and react in an oven at 200 ° C for 8 hours. After cooling to room temperature, pour the reacted solution into a centrifuge tube, and centrifugally wash with a mixed solution of cyclohexane and ethanol for 3-4 times to obtain PtWMn ternary alloy nanoparticles. The prepared PtWMn ternary alloy nanoparticles were uniformly dispersed in about 10 mL of cyclohexane for storage. Using the adsorption method, a certain amount of r-TiO 2 The carrier was added to the cyclohexane solution containing nanocrystals, stirred for 6-1