Method of making phosphor containing glass plate, method of making light emitting device

Active Publication Date: 2009-07-23
TOYODA GOSEI CO LTD +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

[0019]It is an object of the invention to provide a method for making a light emitting device that is excellent in heat resistance, light resistance and gas impermeability while preventing the deterioration of phosphor with low moisture resistance.

Problems solved by technology

However, since the conventional white LED lamps use the transparent resin as the sealing material, the transparent resin near the LED chip may be yellowed due to light or heat etc. from the LED chip, so that the light extraction efficiency will deteriorate with time.
In particular, the yellowing of the transparent resin is notably caused when a short-wavelength LED chip for emitting blue light etc. with high energy.
Further, since the transparent resin has permeability to gases, the phosphor powder contained in the transparent resin may be reacted with gas (especially moisture) in the air, so that the phosphor characteristics can often deteriorate with time.
Because of this, it is difficult to keep the characteristics of these phosphors although they can be used as high excitation efficiency green or red phosphor.
As described, sealing by the transparent resin is insufficient to meet the heat resistance, the light resistance and the impermeability to gases which are demanded for LED lamps.
However, since glass has a high viscosity even at a temperature (i.e., yielding point (At)) where it starts to be softened, it is exactly very difficult to uniformly disperse the phosphor therein.
However, in this method, the glass characteristic such as strength and transparency may deteriorate due to the remainder of the resin binder.
Therefore, phosphors with low moisture resistance will be subject to deterioration in fluorescence characteristic.
However, since the sol-gel glass is porous and therefore has gas permeability, phosphors with low moisture resistance will be subject to deterioration in fluorescence characteristic.
Further, since the sol-gel glass is large in volume change before and after the vitrification, it may cause cracks when it is formed into a thick film.
Therefore, it is difficult to use it as a sealing material which is needed to be formed relatively thick.

Method used

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  • Method of making phosphor containing glass plate, method of making light emitting device
  • Method of making phosphor containing glass plate, method of making light emitting device
  • Method of making phosphor containing glass plate, method of making light emitting device

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[0049]FIG. 1A to 7 show the preferred embodiment of the invention. FIGS. 1A to 1C are cross sectional views showing an LED lamp in the embodiment. FIG. 2 is a cross sectional view showing an LED chip used in the embodiment.

[0050]As shown in FIG. 1A, the LED lamp (=light emitting device) 1 is composed of a flip-chip type LED chip (=light emitting element) 2, a wiring substrate 3 for mounting the LED chip 2 thereon, a wiring 4 formed on or in the wiring substrate 3, and a glass sealing portion 6 sealing the LED chip 2, adhered to the wiring substrate 3 and containing a phosphor 7 therein.

[0051]As shown in FIG. 2, the LED chip 2 is composed of, grown sequentially on the surface of a crystal growth substrate 20, a buffer layer 21, an n-type layer 22, a light emitting layer 23 and a p-type layer 24 which are of gallium nitride-based semiconductor (Al1-X-YInXGaYN, 0≦X≦1, 0≦Y≦1, 0≦X+Y≦1), and formed by MOVPE (metalorganic vapor phase epitaxy). The LED chip 2 is epitaxially grown at 700° C. or

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Abstract

A method of making a light emitting device includes mixing a glass powder with a phosphor powder including at least one of a sulfide phosphor, an aluminate phosphor and a silicate phosphor to produce a mixed powder in which the phosphor powder is dispersed in the glass powder, heating and softening the mixed powder to provide an integrated material, and subsequently solidifying the integrated material to provide a phosphor-dispersed glass, and fusion-bonding the phosphor-dispersed glass onto a mounting portion on which a light emitting element is mounted by hot pressing, and simultaneously sealing the light emitting element with the phosphor-dispersed glass on the mounting portion.

Description

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Claims

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Application Information

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Owner TOYODA GOSEI CO LTD
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