Conductive composition for electrophotographic apparatuses and conductive roll for electrophotographic apparatuses using same

An electrophotography and conductive roller technology, applied in the field of conductive rollers, can solve the problems of easy roughness, slow moving speed, and high viscosity, etc., and achieve the effects of reducing the amount of addition, reducing resistance, and improving cationicity

Active Publication Date: 2015-07-08
TOKAI RUBBER IND LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, kneading of carbon black can achieve low resistance, but there are problems such as high viscosity, low productivity, and roughness
In addition, ion-conducting agents move slower due to their larger ionic radii than electrons

Method used

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  • Conductive composition for electrophotographic apparatuses and conductive roll for electrophotographic apparatuses using same
  • Conductive composition for electrophotographic apparatuses and conductive roll for electrophotographic apparatuses using same
  • Conductive composition for electrophotographic apparatuses and conductive roll for electrophotographic apparatuses using same

Examples

Experimental program
Comparison scheme
Effect test

Example

[0101] [Examples 1-1 to 1-14, Comparative Examples 1-1 to 1-4 (toner supply roller)]

[0102] Each component was mix|blended so that it might become the compounding ratio (unit: mass part) shown in Table 4 - Table 6, and it mixed with a stirrer, and the composition of the urethane foam of an Example and a comparative example was prepared. Details of the materials shown in Tables 4 to 6 are as follows.

[0103] [Raw materials of urethane foam]

[0104] (Polyether polyol)

[0105] · Sanyo Chemical Co., Ltd., trade name "Sonnickus FA703", EO content: 10%, OHv: 33 mgKOH / g

[0106] · Asahi Glass Co., Ltd., trade name "EXCENOL3021", EO content: 0%, OHv: 34 mgKOH / g

[0107] (Silicone Foam Stabilizer)

[0108] ・Product name: "SRX274DL" manufactured by Torayo Co., Ltd.

[0109] (foaming agent)

[0110] Distilled water: OHv: 6233mgKOH / g

[0111] (Ion Conductive Agent): Refer to Table 1 to Table 3

[0112] (catalyst)

[0113] ・Product name "TEDA L33" manufactured by Toso Ichi

Example

[0137] [Examples 2-1 to 2-2, Comparative Example 2-1 (charging roller)]

[0138] Each component was mixed so that it might become the mixing ratio (unit: mass part) shown in Table 7, and it mixed with a stirrer, and the composition of the base mix and the coating film mix of an Example and a comparative example was prepared. Details of the materials shown in Table 7 are as follows.

[0139] [Basic deployment of grassroots]

[0140] · ECO: ダイソ One company, trade name "エビタロマ CG102"

[0141] ・Carbon black: manufactured by Tokai Kaybon Co., Ltd., trade name "シースト116"

[0142] Peroxide: 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane: manufactured by NOF Corporation, trade name "Panabol 25B40"

[0143] ·Ion conductive agent: refer to Table 1 and Table 3

[0144] [Coating film preparation of surface layer]

[0145] ·N-methoxymethylated nylon

[0146] ·Citric acid

[0147] ·Methanol

[0148] ·Ion conductive agent: refer to Table 1 and Table 3

[0149]

[0150] (formation of base

Example

[0166] [Examples 3-1 to 3-2, Comparative Example 3-1 (developing roller)]

[0167] Each component was prepared so that it might become a compounding ratio (unit: mass part) shown in Table 8, and it mixed with a mixer, and the composition of the base compounding of an Example and a comparative example, and a coating film preparation was prepared. Details of the materials shown in Table 8 are as follows.

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Abstract

Provided are: a conductive composition for electrophotographic apparatuses, which is capable of reducing the resistance even in cases where an ion conductive agent is used; and a conductive roll for electrophotographic apparatuses. A conductive roll (1) is configured using a conductive composition, which contains a polar polymer and a quaternary ammonium salt represented by formula (1) and serving as a conductivity-imparting agent, in at least one of a base layer (3), a surface layer (4) and an intermediate layer (5), said layers being formed around a shaft body (2). In formula (1), each of R1-R3 represents a C1-C14 alkyl group; R4 represents a methacrylate group or an acrylate group; X- represents an anion, which is bistrifluoromethane sulfonimide, triflate or fluorosulfonyl imide; and A represents an alkylene group.

Description

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Claims

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Application Information

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Owner TOKAI RUBBER IND LTD
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