Preparation method of magnetic carbon material

A magnetic carbon, mass ratio technology, applied in chemical instruments and methods, alkali metal oxides/hydroxides, inorganic chemistry, etc., can solve the problems of waste water preparation process, expensive and complicated equipment, and achieve simple process route and environmental protection. The effect of low pollution and excellent lithium storage performance

Active Publication Date: 2018-07-24
SHANXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new type of magentic carbon material made from iron oxide particles was developed through an improved manufacturing technique called magnetron sputtering (MS). It had many advantages over existing materials such as long cycle life, stable operation at room temperature, no harmful chemicals used during its synthesis, etc., making them ideal for use in batteries.

Problems solved by technology

This patents discuss different ways for making magnecarbon particles smaller without losing their effectiveness when used alone due to issues like aggregation phenomena that can lead to fast decreases in charging ability over time. Additionally, it highlighted how the size distribution (the ratio between two main types) affects the overall behavior of magnetocaloric substances.

Method used

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  • Preparation method of magnetic carbon material
  • Preparation method of magnetic carbon material

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Embodiment 1

[0018] Ferrocene and red phosphorus are used as raw materials, and the two are uniformly mixed according to the mass ratio of 1.5:1, and then placed in a closed reactor with an oxygen content of 21% for heat treatment. The heating mechanism is as follows: firstly, the temperature is raised to 450°C at a rate of 3°C / min, and then the temperature is kept at a constant temperature for 4 hours, and then naturally cooled to room temperature. Open the kettle to take out the reaction product, heat it at a temperature of 50°C to initiate combustion, and the collected black fluffy combustion product is a magnetic carbon material. The material is used as the negative electrode material of the lithium ion battery, and the reversible capacity of 554 mAh / g can be maintained after 500 charge-discharge cycles at a current density of 100 mA / g.

Embodiment 2

[0020] Ferrocene and red phosphorus are used as raw materials, and the two are uniformly mixed according to the mass ratio of 0.5:1, and then placed in a closed reactor with an oxygen content of 5% for heat treatment. The heating mechanism is as follows: first, the temperature was raised to 400°C at a rate of 5°C / min, and then the temperature was kept at a constant temperature for 1 hour, and then naturally cooled to room temperature. Open the kettle to take out the reaction product, heat it at 40°C to initiate combustion, and the collected black fluffy combustion product is a magnetic carbon material. The material is used as the negative electrode material of the lithium ion battery, and the reversible capacity of 502 mAh / g can be maintained after 500 charge-discharge cycles at a current density of 100 mA / g.

Embodiment 3

[0022] Ferrocene and red phosphorus are used as raw materials, and the two are uniformly mixed according to the mass ratio of 2:1, and then placed in a closed reaction kettle with an oxygen content of 15% for heat treatment. The heating mechanism is as follows: first, the temperature is raised to 500°C at a rate of 2°C / min, and then the temperature is kept at a constant temperature for 4 hours, and then naturally cooled to room temperature. Open the kettle to take out the reaction product, heat it at 80°C to initiate combustion, and the collected black fluffy combustion product is a magnetic carbon material. The material is used as the negative electrode material of the lithium ion battery, and the reversible capacity of 529 mAh / g can be maintained after 500 charge-discharge cycles at a current density of 100 mA / g.

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Abstract

The invention discloses a preparation method of a magnetic carbon material and belongs to the technical field of carbon materials. The problems that wastewater is produced in a conventional process ofpreparing the magnetic carbon material by taking ferroferric oxide as a magnetic component, the preparation process is complicated and equipment is expensive can be solved. The preparation method specifically comprises the following steps: taking ferrocene and red phosphorus as raw materials, uniformly mixing the two materials according to a feed mass ratio of (0.5-3):1, and heating in a closed reactor with oxygen content of 5-25%, wherein the temperature rise mechanism comprises the following steps: raising the temperature to 400-500 DEG C at a rate of 1-5 DEG C per minute, maintaining the constant temperature for 1-5 hours, and naturally cooling to a room temperature; opening the reactor to take out the reaction product, heating under the temperature condition of 40-80 DEG C, initiatingcombustion, and collecting the obtained black fluffy combustion product, namely the magnetic carbon material. The preparation method of the magnetic carbon material disclosed by the invention has theadvantages of being simple and reliable in process route, capable of realizing large-scale preparation and the like.

Description

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Claims

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Application Information

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Owner SHANXI UNIV
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