Metal ion guiding carboxylic acid ligand functionalized polyacid compound, preparation method thereof and application of catalytic degradation chemical warfare agent simulant

[0040] Example 1 Preparation of metal ion-guided carboxylic acid ligand functionalized polyacid hybrid compound catalyst, the specific steps are as follows:

[0041] Dissolve 0.145g sodium molybdate, 0.0197g arsenic dioxide, 0.0224g potassium chloride, 0.0089g alanine and 0.0274g p-hydroxybenzoic acid in 20mL water and stir, adjust the PH=3.5 with HCl, and then stir at room temperature 1 After hours, add 0.0714g of cobalt chloride, finally reflux at 80°C for one hour, and cool to obtain the desired compound.

[0042] The 0.0714g cobalt chloride is replaced by 0.0678g nickel chloride, 0.0861g zinc chloride or 0.0486g manganese chloride.

[0043] Example 2 Preparation of metal ion-guided carboxylic acid ligand functionalized polyacid hybrid compound catalyst, the specific steps are as follows:

[0044] Dissolve 0.145g sodium molybdate, 0.0197g arsenic dioxide, 0.0224g potassium chloride, 0.0089g alanine and 0.0274g p-hydroxybenzoic acid in 20mL water and stir, adjust the PH=3.5 with HCl, and then stir at room temperature 1 Then add 0.0873g nickel nitrate, and finally reflux at 80°C for one hour, and cool to obtain the desired compound.

[0045] Example 3 Preparation of metal ion-guided carboxylic acid ligand functionalized polyacid hybrid compound catalyst, the specific steps are as follows:

[0046] Dissolve 0.145g sodium molybdate, 0.0197g arsenic dioxide, 0.0224g potassium chloride, 0.0089g alanine and 0.0274g p-hydroxybenzoic acid in 20mL water and stir, adjust the PH=3.5 with HCl, and then stir at room temperature 1 Then add 0.0893g zinc nitrate, and finally reflux at 80°C for one hour. Cooling is the preparation of metal ion-guided carboxylic acid ligand functionalized polyacid hybrid compound catalyst in Example 4. The specific steps are as follows:

[0047] Dissolve 0.145g sodium molybdate, 0.0197g arsenic dioxide, 0.0149g potassium chloride, 0.0089g alanine and 0.0274g p-hydroxybenzoic acid in 20mL water and stir, adjust the PH=3.5 with HCl, and then stir at room temperature. Then add 0.0843g cobalt sulfate, finally reflux at 80°C for one hour, and cool to obtain the desired compound.