Compound of general formula and application thereof

A compound of general formula and selected technology, applied in the field of organic electroluminescence devices, can solve the problems of unbalanced horizontal and vertical mobility, poor pixel crosstalk, etc.

Pending Publication Date: 2019-09-10
BEIJING ETERNAL MATERIAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, when this material is applied in the production line, due to its uneven horizontal and vertica

Method used

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  • Compound of general formula and application thereof
  • Compound of general formula and application thereof
  • Compound of general formula and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Synthesis of compound 1

[0061]

[0062] Synthesis of Intermediate 1-1;

[0063] Under nitrogen protection, in a four-necked flask equipped with mechanical stirring, add raw materials carbazole (30g, 180mmol, 1eq), 1-(4-bromophenyl)-4-chlorobiphenyl (61.4g, 180mmol, 1eq), three (dibenzylideneacetone) dipalladium (5.0g, 5.4mmol, 3%eq), tri-tert-butylphosphine tetrafluoroborate (3.1g, 10.8mmol, 6 %eq), sodium tert-butoxide (26g, 270mmol, 1.5eq), and 300mL toluene were reacted at 80°C for 24h. After cooling down to room temperature, 250 mL of aqueous solution was added directly, the aqueous phase was extracted three times with 200 mL of dichloromethane, and the combined organic phases were concentrated to obtain a crude product. The crude product was boiled and washed in petroleum ether, and filtered to obtain 27g of white powder.

[0064] Synthesis of compound 1;

[0065] Under nitrogen protection, in a four-necked flask equipped with mechanical stirring, 1-1 (27g, 6

Embodiment approach

[0071] The organic light emitting diode includes a first electrode and a second electrode on the substrate, and an organic material between the electrodes, and a hole transport layer, a light emitting layer, and an electron transport layer are included between the first electrode and the second electrode.

[0072] The substrate is a substrate used in organic light emitting displays, such as glass, polymer materials, glass and polymer materials with TFT components, and the like.

[0073] The anode material can be transparent conductive materials such as indium tin oxide (ITO), indium zinc oxide (IZO), tin dioxide (SnO2), zinc oxide (ZnO), or metal materials such as silver and its alloys, aluminum and its alloys , can also be an organic conductive material such as PEDOT, and a multilayer structure of the above materials.

[0074] The cathode is magnesium-silver mixture, LiF / Al, ITO and other metals, metal mixtures, oxides

[0075] The device may also include hole injection layer

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PUM

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Abstract

The invention discloses a general formula compound with the following structure, wherein R1 is selected from C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl; R2 and R3 are independently selected from hydrogen, C1-C12 alkyl, C1-C8 alkoxy, C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl; M and n are each independently selected fromintegers of 1 to 4; L is selected from single bonds, or C1-C12 alkyl, C1-C8 alkoxy, C5-C30 arylene, C3-C30 heterocyclic arylene; Ar1 and Ar2 are independently selected from C6-C30 aryl or fused ring aryl respectively; Ar3 and Ar4 are independently selected from C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl respectively. The invention also protects the organic electroluminescent device adopting the general formula compound. When the compound is used as a hole transport material in an OLED light emitting layer, the compound exhibits excellent device performance and stability.

Description

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Claims

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Application Information

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Owner BEIJING ETERNAL MATERIAL TECH
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