Organic light-emitting device and preparation method thereof

An electroluminescent device and electroluminescent technology, which are applied in the fields of electro-solid devices, semiconductor/solid-state device manufacturing, electrical components, etc., can solve the problems of low exciton recombination probability, low luminous efficiency of devices, etc., and are conducive to the transmission of electrons. , the chain segments are arranged in an orderly manner, and the effect of improving the luminous efficiency

Inactive Publication Date: 2015-06-24
OCEANS KING LIGHTING SCI&TECH CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In traditional organic electroluminescent devices, the electron transport rate is two or three orders of magnitude lower than the hole transport rate. Therefore, it is very easy to

Method used

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  • Organic light-emitting device and preparation method thereof
  • Organic light-emitting device and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] A method for preparing an organic electroluminescent device, comprising the following steps:

[0042] (1) Sonicate commercially available ordinary glass with detergent, deionized water, acetone, ethanol, and isopropanol for 15 minutes each to remove organic pollutants on the glass surface, clean it and air dry it; then use it on the glass substrate ITO with a thickness of 120nm was prepared by magnetron sputtering. The acceleration voltage of magnetron sputtering was 700V, the magnetic field was 120G, and the power density was 25W / cm 2 ; Then adopt the method of thermal resistance evaporation on the anode to prepare hole injection layer, hole transport layer, light-emitting layer and electron transport layer successively; Wherein,

[0043] The hole injection layer is made of MoO 3 , the pressure used in evaporation is 8×10 -4 Pa, the evaporation rate is 2nm / s, and the evaporation thickness is 25nm;

[0044] The material of the hole transport layer is NPB, and the pr

Embodiment 2

[0052] A method for preparing an organic electroluminescent device, comprising the following steps:

[0053] (1) Firstly, use detergent, deionized water, acetone, ethanol, and isopropanol to sonicate commercially available ordinary glass for 15 minutes each to remove organic pollutants on the glass surface, clean it and air dry it; then use it on the glass substrate AZO with a thickness of 300nm was prepared by magnetron sputtering. The acceleration voltage of magnetron sputtering was 300V, the magnetic field was 50G, and the power density was 40W / cm 2 ; Then adopt the method of thermal resistance evaporation on the anode to prepare hole injection layer, hole transport layer, light-emitting layer and electron transport layer successively; Wherein,

[0054] The material of the hole injection layer is WO 3 , the pressure used in evaporation is 2×10 -3 Pa, the evaporation rate is 10nm / s, and the evaporation thickness is 20nm;

[0055] The material of the hole transport layer

Embodiment 3

[0063] A method for preparing an organic electroluminescent device, comprising the following steps:

[0064] (1) Firstly, use detergent, deionized water, acetone, ethanol, and isopropanol to sonicate commercially available ordinary glass for 15 minutes each to remove organic pollutants on the glass surface, clean it and air dry it; then use it on the glass substrate AZO with a thickness of 150nm was prepared by magnetron sputtering. The acceleration voltage of magnetron sputtering was 800V, the magnetic field was 200G, and the power density was 1W / cm 2 ; Then adopt the method of thermal resistance evaporation on the anode to prepare hole injection layer, hole transport layer, light-emitting layer and electron transport layer successively; Wherein,

[0065] The material of the hole injection layer is WO 3 , the pressure used in evaporation is 5×10 -5 Pa, the evaporation rate is 1nm / s, and the evaporation thickness is 55nm;

[0066] The material of the hole transport layer i

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Abstract

The invention discloses an organic light-emitting device and a preparation method thereof. The organic light-emitting device comprises a glass substrate, a conductive anode, a hole injection layer, a hole transport layer, a light-emitting layer, an electron transport layer, electron injection layers and a cathode which are sequentially overlapped. The electron injection layers are each made of a mixture composed of thiophene compounds, phthalocyanine compounds and passive materials according to the mass ratio between 2 to 20 to 1 and 10 to 40 to 1. The thiophene compounds are 3-hexylthipphene or 3-methylthiophene or 3-octylthiophene or 3-dodecylthiophene. The phthalocyanine compounds are copper phthalocyanine or zinc phthalocyanine or magnesium phthalocyanine or vanadium phthalocyanine. The passive materials are silicon dioxide or silicon monoxide or aluminum oxide. By means of the electron injection layers, the light-emitting efficiency of the device can be effectively improved.

Description

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Claims

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Application Information

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Owner OCEANS KING LIGHTING SCI&TECH CO LTD
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