Battery positive electrode composite pole piece, preparation method thereof and solid-state battery comprising battery positive electrode composite pole piece

A battery positive electrode, solid electrolyte technology, applied in battery electrodes, positive electrodes, secondary batteries and other directions, can solve problems such as being unsuitable for large-scale industrialization and application, complex operation procedures, etc., and achieve mass production, simple process, and low cost. Effect

Pending Publication Date: 2021-11-16
EVE ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology describes making batteries with improved performance compared to traditional methods such as pasted layers on current collectors. By applying an insulating material onto one side of each plate's surface during manufacturing, it prevents short circuits between different parts while still allowing good contact between them. Additionally, this technique simplifies the way that cathode materials are made into cells without adding extra steps like sintering powders together. Overall these technical improvements make batteries better at delivering high amounts of energy over longer periods of time than previously possible.

Problems solved by technology

The technical problem addressed in this patent text is the need for a battery positive composite electrode sheet that can be easily prepared, has a low cost, and exhibits excellent electrochemical performance in solid-state batteries.

Method used

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  • Battery positive electrode composite pole piece, preparation method thereof and solid-state battery comprising battery positive electrode composite pole piece
  • Battery positive electrode composite pole piece, preparation method thereof and solid-state battery comprising battery positive electrode composite pole piece

Examples

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Embodiment 1

[0094] This embodiment provides a battery positive composite pole piece, the battery positive composite pole piece includes an aluminum layer, and a composite active material layer, a solid electrolyte layer and a polymer lithium salt that are sequentially stacked from opposite sides of the aluminum layer Floor. The thickness of the composite active material layer is 100 μm, including polyvinylidene fluoride, lithium hexafluoroarsenate, lithium cobaltate, polyacrylonitrile and carbon fiber; the lithium hexafluoroarsenate and lithium cobaltate in the composite active material layer The mass ratio is 5:85; the mass proportion of carbon fiber in the composite active material layer is 3%; the mass proportion of polyvinylidene fluoride in the composite active material layer is 5%; the polyvinylidene fluoride in the composite active material layer The mass proportion of acrylonitrile is 2%; the thickness of the solid electrolyte layer is 40 μm, including polyvinylidene fluoride, lithiu

Embodiment 2

[0105] This embodiment provides a battery positive composite pole piece, the battery positive composite pole piece includes an aluminum layer, and a composite active material layer, a solid electrolyte layer and a polymer lithium salt that are sequentially stacked from opposite sides of the aluminum layer Floor. The thickness of the composite active material layer is 50 μm, including polyethylene oxide, lithium bisfluorosulfonimide, lithium nickel manganese oxide, polyacrylonitrile and graphene; the lithium bisfluorosulfonimide in the composite active material layer The mass ratio of lithium nickel manganese oxide is 8.4:80; the mass proportion of graphene in the composite active material layer is 1%; the mass proportion of polyethylene oxide in the composite active material layer is 5.6%; the The mass proportion of polyacrylonitrile in the composite active material layer is 5%; the thickness of the solid electrolyte layer is 20 μm, including polyethylene oxide, lithium bisfluoro

Embodiment 3

[0114] This embodiment provides a battery positive composite pole piece, the battery positive composite pole piece includes an aluminum layer, and a composite active material layer, a solid electrolyte layer and a polymer lithium salt that are sequentially stacked from opposite sides of the aluminum layer Floor. The thickness of the composite active material layer is 200 μm, including polyacrylonitrile, lithium tetrafluoroborate, lithium iron phosphate, polyvinylidene fluoride and carbon nanotubes; in the composite active material layer, lithium tetrafluoroborate and lithium iron phosphate The mass ratio is 1.1:81; the mass proportion of carbon nanotubes in the composite active material layer is 5%; the mass proportion of polyacrylonitrile in the composite active material layer is 9.9%; The mass proportion of polyvinylidene fluoride is 3%; the thickness of the solid electrolyte layer is 60 μm, including polyacrylonitrile, lithium tetrafluoroborate and aluminum oxide; the mass rat

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Abstract

The invention provides a battery positive electrode composite pole piece, a preparation method thereof and a solid-state battery comprising the battery positive electrode composite pole piece. The battery positive electrode composite pole piece comprises an aluminum layer, and a composite active substance layer, a solid-state electrolyte layer and a polymer lithium salt layer which are sequentially laminated from two opposite surfaces of the aluminum layer. The preparation method comprises the following steps: coating two sides of an aluminum layer with composite active substance slurry, then continuously coating the surface of the composite active substance layer with solid electrolyte slurry, and coating the surface of the solid electrolyte layer with polymer lithium salt slurry to obtain the battery positive electrode composite pole piece. According to the battery positive electrode composite pole piece disclosed by the invention, the polymer lithium salt layer is in close contact with the negative electrode pole piece, and the high ionic conductivity brought by the solid electrolyte layer is utilized, so the interface impedance can be effectively reduced, and the solid-state battery performance is improved.

Description

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Claims

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Application Information

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Owner EVE ENERGY CO LTD
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