Hollow articles comprising fiber-filled polyester compositions, methods of manufacture, and uses thereof

a technology of polyester composition and fiber-filled polyester, which is applied in the direction of furniture parts, process and machine control, mechanical control devices, etc., can solve the problems of surface roughness and achieve excellent surface gloss

Inactive Publication Date: 2012-10-04
SABIC GLOBAL TECH BV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention relates to methods used during production of plastic products that have good appearance without any visible defects such as bumps or cracks on their surfaces when they are made from materials like polypropylene (PP) due to poor quality material properties caused by imperfections in the process itself. This results in an improved product's overall look and performance compared with other types of plastings.

Problems solved by technology

This patented technical solution involves improving the quality (quality) of glass-fibre fillings in polyester resin composites while maintaining desired physical properties such heat conductivity, rigidity, tensile stress hardening behavior, and moisture absorption capabilities over time.

Method used

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  • Hollow articles comprising fiber-filled polyester compositions, methods of manufacture, and uses thereof

Examples

Experimental program
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examples

Materials

[0062]The following materials are used in Examples 1 to 2 and Comparative Examples A to F. Table 1 shows the nomenclature used as well as a description.

TABLE 1Raw MaterialsDescriptionPBT 195Poly(1,4-butylene terephthalate), intrinsic viscosity(IV) = 0.66 dl / g, Mw weight-average molecularweight = 53400 g / mol, Tm 215° C.PBT 315Poly(1,4-butylene terephthalate), intrinsic viscosity(IV) = 1.10 dl / g, Mw weight-average molecularweight = 110000 g / mol, Tm 217° C.Low IV PET0.535 dl / g IV PET, 0.8% DEG, Tm 257° C.Hi IV PET0.83 dl / g IV PET, 0.8% DEG, Tm 242° C.Glass FiberOwens Corning 183F 13 micron diameter E glassMold ReleasePenta erythritol tetra stearate (PETS)Antioxidant 1PEPQ phosphonite from ClariantAntioxidant 2Diphenyl isodecyl phosphiteCarbon black25 wt % 17 nm particle size carbon black in PBT 195SilicaPrecipitated amorphous silica process aid

General Testing Techniques and Procedures:

[0063]Gloss was measured per ASTM D523 at six different locations in a glossy region

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Abstract

A hollow molded article is obtained by molding a thermoplastic polyester composition comprising a blend of reinforcing fiber glass, polybutylene terephthalate with a melting point of 210 to 230° C. and polyethylene terephthalate with a melting point of 240 to 260° C., wherein at least 10% of the outer surface of the article has a continuous glossy region with a gloss of at least 75 gloss units, as measured at 60 degrees in accordance with ASTM D523 and wherein the gloss varies from the average less than 10 gloss units in the glossy region. A gas-assisted injection molding process is also disclosed for making such hollow molded articles, which articles can have various uses, including handles for appliances or the like.

Description

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Claims

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Application Information

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Owner SABIC GLOBAL TECH BV
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