Water paint solidified by ultraviolet light, preparation method and application

A water-based coating and ultraviolet light technology, applied in polyurea/polyurethane coatings, coatings, latex paints, etc., can solve the difficult problem of taking into account the hardness and flexibility of the coating film, environmental and human health hazards, volatilization and drying time, etc. problems, to achieve a wide range of applications and application prospects, improve production efficiency, and easy-to-control performance

Inactive Publication Date: 2007-10-10
GUANGZHOU SHILI SPORTS EQUIP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, at present, more than 99% of ultraviolet light-curable coatings are oil-based paints, and most of them use reactive oligomers and low-molecular reactive diluents such as benzene, esters, and ketones as solvents, and the most used mixed solvents are toluene and ethyl acetate. , Butanone, the amount of solvent accounts for about 70% of the weight of the coating, and the solvent volatilizes disorderly during the drying process, causing great harm to the environment and human health, and causing a waste of petroleum resources, which does not meet the requirements of e

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0034] Example 1

[0035] Recipe 1:

[0036] Diphenylmethane diisocyanate 6%

[0037] Dimethylolpropionic acid 5%

[0038] Polypropylene glycol 200 18%

[0039] Hydroxyethyl acrylate 6%

[0040] Triethanolamine 8%

[0041] Benzophenone 2%

[0042] Water 55%

[0043] Coating production method:

[0044] 1. Preparation of high molecular polymer:

[0045] (1) Under normal pressure, add the measured amount of diphenylmethane diisocyanate, dimethylolpropionic acid, polypropylene glycol 200, and hydroxyethyl acrylate into a three-necked reaction flask according to the above formula. After stirring, the temperature is raised to 70°C. , React for 3 hours.

[0046] (2) Add triethanolamine to (1) and stir for 0.5 hour.

[0047] 2. Add water and benzophenone, stir evenly to obtain the coating.

[0048] Coating product appearance: semi-transparent and uniform liquid

[0049] Wettability: good wetting on the wood surface

[0050] Storage period: ≤30℃, one year

[0051] Curing time: ≤10 seconds

Example Embodiment

[0052] Example 2

[0053] Formulation 2:

[0054] Diphenylmethane diisocyanate 5%

[0055] Dimethylolpropionic acid 5%

[0056] Polypropylene glycol 400 15%

[0057] Hydroxyethyl acrylate 5%

[0058] Triethanolamine 8%

[0059] Benzophenone 2%

[0060] Water 60%

[0061] Coating production method:

[0062] 1. Preparation of high molecular polymer:

[0063] (1) Under normal pressure, add the metered amount of diphenylmethane diisocyanate, dimethylolpropionic acid, polypropylene glycol 400, and hydroxyethyl acrylate into a three-necked reaction flask according to the above formula. After stirring, the temperature is raised to 75 ℃, react for 3 hours.

[0064] (2) Add triethanolamine and stir for 0.5 hour.

[0065] 2. Add water and benzophenone, stir evenly to obtain the coating.

[0066] Coating product appearance: semi-transparent and uniform liquid

[0067] Wettability: good wetting on the wood surface

[0068] Storage period: ≤30℃, one year

[0069] Curing time: ≤10 seconds

Example Embodiment

[0070] Example 3

[0071] Recipe 3:

[0072] Toluene diisocyanate 8%

[0073] Dimethylolpropionic acid 5%

[0074] Polypropylene glycol 200 21%

[0075] Hydroxyethyl acrylate 4%

[0076] Triethanolamine 7%

[0077] Benzophenone 3%

[0078] Water 52%

[0079] Coating production method:

[0080] 1. Preparation of high molecular polymer:

[0081] (1) Under normal pressure, add the metered toluene diisocyanate, dimethylolpropionic acid, polypropylene glycol 200, and hydroxyethyl acrylate into a three-necked reaction flask according to the above formula. After stirring, the temperature is raised to 75°C, and the reaction is 3 hour.

[0082] (2) Add triethanolamine and stir for 0.5 hour.

[0083] 2. Add water and benzophenone and stir to obtain the coating.

[0084] Coating product appearance: semi-transparent and uniform liquid

[0085] Wettability: good wetting on the wood surface

[0086] Storage period: ≤30℃, one year

[0087] Curing time: ≤10 seconds.

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PUM

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Abstract

This invention discloses an UV-curing waterborne paint, which is composed of: polymer 9-60 wt. %, photoinitiator 1-10 wt. %, and water 30-90 wt. %. The product has such advantages as high hardness and flexibility of coating film, no pollution, no toxicity, and wide applications.

Description

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Claims

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Application Information

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Owner GUANGZHOU SHILI SPORTS EQUIP
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