Semi-conductor photoelectrocatalysis combination electrode for simultaneously degrading ethylene and sterilizing and preparation and applications
A composite electrode and photoelectric catalysis technology, which is applied in application, preservation of fruits/vegetables through radiation/electrical treatment, food preservation, etc., can solve the problem of high probability of electron-hole recombination, limitation of industrialization and industrial application, and photocatalytic reaction rate Unsatisfactory and other problems, to achieve the effect of fast reaction speed, improved catalytic activity, and simple reaction system structure
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Embodiment 1
[0037] The present invention will be described in further detail below in conjunction with the accompanying drawings and specific embodiments. Example 1 Silver-loaded nano-TiO 2 / ACF(nano TiO 2 -Ag / ACF) system and nano-TiO 2 / ACF(nano TiO 2 / ACF) system preparation
[0038] The specific expression is as follows:
[0039] (1) Nano-TiO 2 - Preparation of Ag / ACF system
[0040] 1.1 The nanoscale TiO loaded with silver 2 Immobilized on activated carbon fibers to prepare two pieces of nano-TiO 2 -Ag / ACF composite material.
[0041] The preparation process is attached figure 1 shown.
[0042] Nanoscale Titanium Dioxide TiO Prepared by Gas Phase Method 2 , its specific surface area: 50±15m 2 / g; primary particle size: 23nm, such as the P25 product of Degussa Company in Germany. Activated carbon fiber, the specific surface area is 1150~1250m 2 / g; the diameter of the single filament is 15-20um, such as the model-STF1300 product of Nantong Sutong Carbon Fiber
Embodiment 2
[0058] Example 2 Semiconductor photoelectric simultaneous degradation of ethylene penicillium reaction unit and operation experiment
[0059] Nano TiO 2 -Ag / ACF system cathode and anode photoelectrodes, nano-TiO 2 The cathode and anode photoelectrodes of the / ACF system are connected in parallel to form the cathode and anode ports of the compound electrode, and the distance between the two systems is 7-8mm. as attached figure 2 As shown, the light source is three 2W cold cathode lamps that can emit a wavelength of 254nm, and the light wave is irradiated on the nano-TiO 2 -Ag / ACF system cathode and anode photoelectrodes and nano-TiO 2 On the cathode and anode photoelectrodes of the / ACF system, the distance between the lamp tube and the system is 2.5-3mm. DC stabilized power supply, output 0~150v; DC voltage and 0~2A DC current, such as WYK-K1002 of China Huatai Company. DC fan, size 50mm×50mm×10mm, wind pressure 250~270Pa, air volume: 0.28mm 3 / min.
[0060] Con
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