Synthetic method of N-ethyl ethylenediamine

A technique for the synthesis of ethylethylenediamine, which is applied in the direction of condensation/addition reaction to prepare amino compounds, organic chemistry, etc., can solve the problems of expensive catalyst, harsh reaction conditions, and difficulty in purification, and achieve low production cost and easy Effect of purification and less by-products

Active Publication Date: 2013-09-11
NANTONG SYNASIA NEW MATERIAL CO LTD
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new technology reduces harmful chemical substances from fossil fuel sources while producing products that can be easily separated for further use or sale without causing any health hazards during manufacturing processes.

Problems solved by technology

Technologies described involve methods for producing n-ethenyltriaminopropionitrile from formaldehydes or alcohols with different starting substances like nitrobenzene or cyclohexadienes. These techniques have advantages over existing processes but also come challenging due to their high cost and environmental concerns associated with these chemical reactions.

Method used

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  • Synthetic method of N-ethyl ethylenediamine

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Embodiment Construction

[0029] The present invention will be described in detail below in combination with specific embodiments.

[0030] The whole reaction was carried out in a closed autoclave. 150 g of ethylamine aqueous solution (the content of ethylamine was calculated as 105 g), 100.3 g of cycloethylamine and 5 g of molybdenum oxide were added into the autoclave together, the temperature was raised to 50 ° C, and the reaction was stirred for 5 h. After the reaction is completed, molecular sieves are added to the reaction liquid to seal and dry the liquid. The next day, the molecular sieves were filtered off, and the filtrate was distilled under reduced pressure by a water pump. The fraction at 38-41°C was collected and weighed to obtain 196g, with a purity of 99% and a yield of 95.6%.

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Abstract

The invention discloses a synthetic method of N-ethyl ethylenediamine. The method comprises the steps of reacting an ethylamine water solution and cyclohexylamine under the effect of a catalyst in a sealed high-pressure reaction kettle, wherein the reaction temperature is 30-100 DEG C; the reaction time is 2-12 hours; the reaction pressure is 5-30 kg; filtering a reaction liquid, and distilling at reduced pressure, so as to obtain the N-ethyl ethylenediamine. By adopting the method, the problems of environmental pollution, difficult purification of the product, high cost and the like in the traditional bromoethane method are avoided; and the byproduct obtained by reaction is fewer, easy to purify, high in yield and low in production cost.

Description

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Claims

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Application Information

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Owner NANTONG SYNASIA NEW MATERIAL CO LTD
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