Sized phase change material and preparation method thereof

A technology of phase change materials and raw materials, applied in heat exchange materials, chemical instruments and methods, etc., can solve the problems of low thermal stability, easy to produce plastic crystals, poor thermal conductivity, etc., and achieve good thermal stability and high thermal conductivity. , the effect of excellent performance

Inactive Publication Date: 2016-07-06
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology improves upon existing methods by modifying and making new types of materials that work better than previously possible with certain rare earth elements like zirconium dioxide. These modifications help make these materials more stable against changes caused during repeated cycling between crystalline states without losing its effectiveness over time. Foaming silica ceramics or cuprous metals results in pores inside them while maintaining strong bondings among themselves. By adding this type of modification, it becomes easier to create different forms such as cylinders or tubular structures. Additionally, they provide superior insulation compared to traditional ways of doing things like perlite.

Problems solved by technology

This patents describes different ways to make phase changes material systems faster and easier compared to existing methods like solvent exchange method. These improvements include reducing particle size, increasing specific surface area, enhancing thermal conduction, prevention from deformation caused by external forces, and enhancement of thermal stability over time. Additionally, these modifications aim towards better compatibility between multiple phases while maintaining good physical characteristics.

Method used

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  • Sized phase change material and preparation method thereof
  • Sized phase change material and preparation method thereof

Examples

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Embodiment 1

[0027] A preparation method for a shaped phase change material, comprising the steps of:

[0028] 1) Preparation of rare earth oxide modified solid-solid phase change materials (or modified solid-solid phase change materials):

[0029] ①After drying the analytically pure trimethylolethane, grind it into a uniform powder, pass through a 200-mesh sieve, put it in a drying dish for 24 hours and take it out (the purpose is to fully dry the raw material and discharge the internal gas to ensure its No air bubbles are generated during use), ready for use;

[0030] 2. again according to the mass percentage of each raw material: trimethylolethane 95%, neodymium oxide 5%, select trimethylolethane and neodymium oxide;

[0031] ③ Mechanically blend trimethylolethane and neodymium oxide powder for 12 hours, and after mixing evenly, obtain a solid-solid phase change material modified by rare earth oxides;

[0032]2) According to the mass percentage of each raw material: rare earth oxide modi

Embodiment 2

[0038] A preparation method for a shaped phase change material, comprising the steps of:

[0039] 1) Preparation of solid-solid phase change materials modified by rare earth oxides:

[0040] ①After drying the analytically pure trimethylolethane, grind it into a uniform powder, pass through a 200-mesh sieve, put it in a drying dish for 24 hours and take it out (the purpose is to fully dry the raw material and discharge the internal gas to ensure its use No air bubbles will be generated during the time), stand-by;

[0041] ②According to the mass percentages of each raw material: trimethylolethane 90%, neodymium oxide 10%, select trimethylolethane and neodymium oxide;

[0042] ③ Mechanically blend trimethylolethane and neodymium oxide powder for 12 hours, and after mixing evenly, obtain a solid-solid phase change material modified by rare earth oxides;

[0043] 2) According to the mass percentage of each raw material: rare earth oxide modified solid-solid phase change material 80%

Embodiment 3

[0048] A preparation method for a shaped phase change material, comprising the steps of:

[0049] 1) Preparation of solid-solid phase change materials modified by rare earth oxides:

[0050] ① First dry the analytically pure trimethylolethane and grind them into uniform powder, pass through a 200-mesh sieve, put it in a drying dish for 24 hours and take it out (the purpose is to fully dry the raw materials and discharge the internal gas to ensure its use No air bubbles will be generated during the time), stand-by;

[0051] ②According to the mass percentages of each raw material: trimethylolethane 92%, yttrium oxide 3%, neodymium oxide 5%, select trimethylolethane, yttrium oxide and neodymium oxide;

[0052] ③Then mechanically blend trimethylolethane, yttrium oxide and neodymium oxide powder for 12 hours, and after mixing evenly, a solid-solid phase change material modified by rare earth oxide is obtained;

[0053] 2) According to the mass percentage of each raw material: rare e

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Abstract

The invention relates to a sized phase change heat storage material applied in the medium and low temperature field.The prepared sized phase change material is characterized by being prepared by compositing, by mass, 80%-85% of a rare earth oxide-modified solid-solid phase change material and 15%-20% of a heat conduction reinforcing phase; the rare earth oxide-modified solid-solid phase change material is heated in a closable container to be in a molten state, the heat conduction reinforcing phase is put into the container, adsorption is performed in a vacuum environment under the pressure smaller than 10<2> Pa to enable the liquid to be fully immersed into the heat conduction reinforcing phase, the container is cooled to room temperature, a sample in the container is taken out, and then the sized phase change material is obtained; the rare earth oxide-modified solid-solid phase change material is prepared from, by mass, 90%-95% of a solid-solid phase change material and 5%-10% of rare earth oxide.The prepared sized phase change material is good in heat stability, high in heat conductivity and simple in preparation method.

Description

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Claims

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Application Information

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Owner WUHAN UNIV OF TECH
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