Metallocene titanium compound and its preparing process

[0031] Calculation, C: 37.10% H: 4.68% [Example 2]

[0032] (Preparation of compound B): Under the protection of argon, the alkoxy alcohol (R 1 =CH(CH 3 )CH 2 , R 2 = Methyl) and the ether solution of lower fatty amine (triethylamine), slowly added to CpTiCl with a molar ratio of 1:1.5 to alcohol 3 In the ether solution, at 25° C., the reaction was stirred for 8 hours, filtered, and the clear liquid was drained. The obtained oil was recrystallized with toluene and n-hexane to obtain a clear yellow oil. The analysis and test results are as follows:

[0033] Molecular formula: C 9 H 14 Cl 2 O 2 Ti; mass spectrum shows molecular ion peak 272 (4, M + ).

[0034] Infrared spectrum data (cm -1 ): 3107m, 2932m, 2890m, 1441m, 1373w, 1147m, 1110s, 1093s, 1014s, 822s, 790s.

[0035] NMR data ( 1H NMR, ppm): 6.94 to 6.72 (m, 5H), 4.99 (m, 1H), 3.49 to 3.45 (m, 2H), 3.45 (s, 3H), 1.35 (d, 3H, J=6.6 Hz).

[0036] Elemental analysis data: actual measurement, C: 38.41% H: 4.64%

[0037] Calculation, C: 39.59% H: 5.18% [Example 3]

[0038] (Preparation of compound C): Under the protection of argon, the aryloxy alcohol ( R 2 = Methyl) and the benzene solution of the lower aliphatic amine (triethylamine), slowly added to CpTiCl with a molar ratio of 1:1.2 to the alcohol 3 In the benzene solution, stirred and reacted at 10°C for 24 hours, filtered, and the clear liquid was drained. The obtained oil was recrystallized with toluene and n-hexane to obtain a clear black-red oil. The analysis and test results are as follows:

[0039] Molecular formula: C 12 H 12 Cl 2 O 2 Ti; mass spectrum shows molecular ion peak 306 (7, M + ).

[0040] Infrared spectrum data (cm -1 ): 3108m, 1612w, 1596m, 1501s, 1484m, 1361w, 1263s, 1225s, 1100s, 1022m, 824s, 794s, 750s.

[0041] NMR data ( 1 H NMR, ppm): 6.93-6.85 (m, 4H), 6.62-6.45 (m, 5H), 3.88 (s, 3H).

[0042] Elemental analysis data: actual measurement, C: 47.08% H: 4.07%

[0043] Calculation, C: 46.94% H: 3.95% [Example 4]

[0044] (Preparation of compound D): Under the protection of argon, the alkoxy alcohol (tetrahydrofurfuryl alcohol) and the lower aliphatic amine (triethylamine) in an ether solution with a molar ratio of 1:1.2 are slowly added To CpTiCl equimolar with alcohol 3 In the ether solution, at 25° C., the reaction was stirred for 8 hours, filtered, and the clear liquid was drained. The obtained oil was recrystallized with toluene and n-hexane to obtain a clear yellow oil. The analysis and test results are as follows:

[0045] Molecular formula: C 10 H 14 Cl 2 O 2 Ti; mass spectrum shows molecular ion peak 284 (0.2, M + ).

[0046] Infrared spectrum data (cm -1 ): 3107w, 2950m, 2870m, 1440m, 1367w, 1118s, 1077s, 1025m, 826s, 793m.

[0047] NMR data ( 1 H NMR, ppm): 6.82 ~ 6.59 (m, 5H), 4.73 ~ 4.52 (m, 2H), 4.03 ~ 3.98 (m, 1H,), 3.88 ~ 3.84 (t, 1H, J = 6.8H), 3.83 ~ 3.78 (t, 1H, J=6.8H), 2.01 to 1.72 (m, 4H).

[0048] Elemental