Electrode inhibitor and application thereof, and production method of battery pole piece

A battery pole piece and inhibitor technology, applied in battery electrodes, circuits, electrical components, etc., can solve problems such as pole piece cracking, and achieve the effects of improving adhesion, smooth appearance, and inhibiting pole piece cracking problems.

Pending Publication Date: 2022-01-14
SHENZHEN TOPBAND NEW ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology applies an agent called pHENYL EVERSIDE onto batteries that are used for their purpose. It prevents damage caused by excessively high temperatures during charging or discharges from happening when they use them. By adding this chemicals into the coatings made up of plates containing PolyVinyl FluoroEthanum Acids (PTFEA)) with specific properties, we have improved battery characteristics such as increased energy density and reduced impedance over time. Additionally, these agents help prevent cracks forming at certain points along its edges due to insulation between layers inside the battery's structure.

Problems solved by technology

This patents discusses how improvements made by adding certain chemicals or substances into lithiated carbonate (LCO) cathode material improves its properties like high power output, long cycle life, low cost manufacturing process, longer lifetimes over time without losing their effectiveness due to cracks caused from repeated use cycles.

Method used

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  • Electrode inhibitor and application thereof, and production method of battery pole piece
  • Electrode inhibitor and application thereof, and production method of battery pole piece
  • Electrode inhibitor and application thereof, and production method of battery pole piece

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preparation example Construction

[0027] When the battery inhibitor of the present invention is used for the positive pole piece of the battery, the preparation method of the battery pole piece may further comprise the steps:

[0028] S1. Dissolve PVDF (polyvinylidene fluoride) in a solvent to form a first glue solution, then add electrode inhibitors to the first glue solution, and mix evenly to form a second glue solution.

[0029] According to the choice of PVDF, the solvent uses N-methylpyrrolidone (NMP).

[0030] S2. After adding a conductive agent and an active material to the second glue solution, disperse at a high speed to form a uniform and stable slurry.

[0031] The speed of high-speed dispersion can be selected from 1500r / min-4000r / min.

[0032] The corresponding pole piece is a positive pole piece, and the active material can be nickel-cobalt lithium manganese oxide, lithium manganese oxide, lithium cobalt oxide, lithium iron phosphate, etc., which can be realized by the existing technology.

Embodiment 1

[0048] Take active material (LFP): SP (conductive carbon black): PVDF: electrode inhibitor = 92.52:4:3:0.48 as an example:

[0049] First use NMP to prepare 30g of PVDF glue with a solid content of 5%, add 0.82g of electrode inhibitor and stir to form a uniform glue; successively weigh 2.01g of SP and 46.5g of LFP, add 27.6g of NMP, and disperse at a high speed (2000r / min) 15 minutes to mix evenly to obtain a slurry with a solid content of 47.0%; use the coating equipment to coat the slurry on the surface of the aluminum foil, and dry the solvent at 105°C to obtain the pole piece; Get a lithium-ion battery.

Embodiment 2

[0051] Take LCO (lithium cobaltate):SP:PVDF:electrode inhibitor=97.46:1:1.3:0.24 as an example:

[0052] First prepare 13g of PVDF glue with a solid content of 5% with NMP, add 0.4g of electrode inhibitor and stir to form a uniform solution; weigh 0.5g of SP and 48.85g of LCO successively, add 11.0g of NMP, and disperse at a high speed (2000r / min) Mix evenly for 15 minutes to obtain a slurry with a solid content of 68.0%. The slurry is coated on the surface of aluminum foil with coating equipment, and the solvent is dried at 105°C to obtain a pole piece; a lithium-ion battery is obtained through sheet production, assembly, chemical formation, and capacity separation.

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Abstract

The invention discloses an electrode inhibitor and an application thereof, and a production method of a battery pole piece. The electrode inhibitor comprises the following components in percentage by mass: 10-30% of hydroxyethyl cellulose and 70-90% of N-methyl pyrrolidone. The electrode inhibitor is applied to the battery pole piece and is mainly added into a coating slurry of the pole piece, hydroxyethyl cellulose in the electrode inhibitor can react during heating, the crystal form of a polyvinylidene fluoride (PVDF)-(C2H2F2) n-series binder on the pole piece is rearranged (including the crystal is changed into a disordered state from an ordered state), the appearance of a coating film is smooth, and the problem of pole piece cracking caused by the semi-crystallinity of polyvinylidene fluoride during rapid thick film coating is inhibited so that the capacity, the rate capability and the like of the lithium ion battery are improved.

Description

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Claims

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Application Information

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Owner SHENZHEN TOPBAND NEW ENERGY CO LTD
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