Elastic member

Inactive Publication Date: 2017-10-05
BRIDGESTONE CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0022]The elastic member of the invention has, formed on the surface thereof, a coating layer in which the content of low-friction powder and the 100% modulus have been optimized and which is endowed with both good film formability and low friction properties. By using this elastic member as, for example, a sealing member in a toner container, good sealing properties can be reliably exhibited over an extended period of time and the reliability of the printing performance with a printer or copier can be increased.
[0023]FIG. 1 is a schematic cross-sectional diagram showing an example of a sealing member which, at an opening in a toner container, seals between the lid and the toner container.
[0024]FIG. 2 is a schematic cross-sectional diagram showing the same sealing member in a state where the opening in the toner container is open and toner is being discharged.
[0025]FIG. 3 is a schematic cr

Problems solved by technology

However, because the toner t constantly flows with rotation of the bottle body 2, leakage of the toner t between the lid 1 and the opening 4 tends to arise.
However, in the coating composition that forms the coating layer, the balance between film formability and coefficient of friction fluctuates greatly

Method used

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Examples

Experimental program
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examples

[0052]The invention is illustrated more fully below by way of Working Examples and Comparative Examples, although the invention is not limited by these Examples.

working examples 1 to 4

, Comparative Examples 1 to 5

[0053]The polyurethane composition formulated as shown below was stirred in an Cakes mixer while feeding 113 cc / min of air per 100 cc / min of polyol. The reaction mixture was then sheeted onto a film with a bar coater and dried at 150° C. for 15 minutes, giving a 2 mm×500 mm×500 mm polyurethane foam sheet. This was used as the base.

[Polyurethane Composition]

[0054]

Polyol 1100parts by weight(Sannix GS-3000, from Sanyo ChemicalIndustries, Ltd.)Polyol 25parts by weight(1,4-butanediol, from BASF)Isocyanate (isocyanate index, 105)30parts by weight(Sumidur 44V20, from Sumika Bayer UrethaneKK)Tin catalyst0.02part by weightSilicone foam stabilizer4parts by weight(NIAX SILICONE L626, from MomentivePerformance Materials Japan)

[0055]In a separate procedure, water-based coatings formulated as shown in Table 1 were prepared. Each of the resulting water-based coatings was applied by spraying onto one surface of the sheet-like base made of polyurethane foam and dried to

working examples 5 to 7

, Comparative Examples 6 to 8

[0062]Water-based coatings in which the content of the low-friction powder (Tospearl 145) was changed as shown in Table 2 from the formulation in Working Example 1 were prepared, and elastic members having a resin coating layer on the surface were produced in the same way as in Working Example 1. The 100% modulus, film formability and coefficient of dynamic friction for the resulting resin coating layers and elastic members were measured or evaluated in the same way as in Working Example 1. The results are shown in Table 2, which also presents the results for Working Example 1.

TABLE 2Comp.ComparativeEx.Working ExampleExample6561778FormulationWater-based80808080808080(pbw)coating A(resin content,35 wt %)Water-based20202020202020coating B(resin content,35 wt %)Low-viscosity00.62615.717.535powder*(1.71)(5.71)(17.14)(44.86)(50)(100)Co-solvent6666666(butyl cellosolve)Diluent (water)88888888888888Film100% modulus (MPa)27.627.627.627.627.627.610propertiesProductFi

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Abstract

Provided is an elastic member which is obtained by forming a resin coating layer on at least a part of the surface of a base that is formed of an elastic material, and which is characterized in that the resin coating layer is a coating film that contains 1.5-45 parts by mass of a low-friction powder per 100 parts by mass of a base resin and has a 100% modulus of 22-30 MPa. This elastic member has a resin coating layer that has a good balance between film formability and low friction, and is suitable as a sealing member for an opening part of a toner container that is provided on a toner cartridge of a printer, a copy machine or the like.

Description

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Claims

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Application Information

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Owner BRIDGESTONE CORP
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