The invention relates to a preparation method of a
hydrodesulfurization catalyst taking a
mesoporous carbon material as a carrier, and the preparation method of the catalyst comprises the following steps: uniformly mixing
molybdenum salt,
cobalt salt, a template agent, a
carbon source and a vulcanizing agent according to certain parts by weight to form a precursor solution of the catalyst, and then carrying out freezing and
vacuum sublimation drying; and finally,
roasting, washing and
drying the product to obtain the mesoporous structure carbon material loaded high-activity
hydrodesulfurization catalyst with uniformly distributed
active components. According to the invention, in-situ growth of a high-activity II-type CoMoS
active phase and synchronous synthesis and effective riveting of a
mesoporous carbon structure are realized, and the catalyst is rich in active sites, developed in pore structure, small in
mass transfer resistance and relatively high in
hydrodesulfurization reaction activity.