Ion additive for carbon dioxide absorbent of organic amines

A carbon dioxide and organic amine technology, applied in the direction of inorganic chemistry, through absorption, reagents, etc., can solve the problems of absorbent oxidation, chemical corrosion, fly ash pollution, etc., and achieve the effect of reducing electrochemical corrosion and oxidation rate

Active Publication Date: 2011-09-07
CPI YUANDA ENVIRONMENTAL PROTECTION ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This new type of chemical can reduce its effectiveness when combined with other substances due to their ability to absorb gases from air or water vapor that may be harmful for some people's health if released into our environment during manufacturing processes such as thermal processing steps like heating up materials at high temperatures.

Problems solved by technology

This patented describes different methods or techniques that aim at removing carbon dioxide (CO2) produced during combustion processes. These include traditional wet scrubbing with water followed by dry cleaners such as activated charcoal powder, molecular sieves, ion exchange resins, metal plates/oxides, zeolite materials, and other technologies like catalyst systems. However, these existing solutions have drawbacks including high costs associated with their maintenance due to degraded components over time, potential environmental concerns related to disposable resources needed after treatment has been completed, and poor selectivity towards specific compounds found within exhaust streams.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Example 1 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives

[0014] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives

[0015] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 0.01% by mass Rb[UO 2 SeO 4 (OH) H 2 O], the mass percentage is 0.01%Cu 2 (CO 3 )(OH) 2 And the mass percentage is 0.01%Na 2 CO 3 composition.

[0016] 2. Performance testing

[0017] 2.1 Test of oxidation rate

[0018] The oxidation rate test in this example is calculated as the time at which the amine (MEA) is reduced to 95% concentration.

[0019] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stir

Embodiment 2

[0024] Example 2 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives

[0025] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives

[0026] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 5% by mass Rb[UO 2 SeO 4 (OH) H 2 O] and mass percentage of 5%Cu 2 (CO 3 )(OH) 2 composition.

[0027] 2. Performance testing

[0028] 2.1 Test of oxidation rate

[0029] In this example, the time when the oxidation rate of an amine is reduced to 95% is calculated.

[0030] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stirrer is adjusted to the absorption temperature of 105 ° C and the magnetic stirri

Embodiment 3

[0035] Example 3 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives

[0036] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives

[0037] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 0.2% by mass Rb[UO 2 SeO 4 (OH) H 2 O], the mass percentage is 0.2%Cu 2 (CO 3 )(OH) 2 And the mass percentage is 0.1%Na 2 CO 3 composition.

[0038] 2. Performance testing

[0039] 2.1 Test of oxidation rate

[0040] In this example, the time when the oxidation rate of an amine is reduced to 95% is calculated.

[0041] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stirrer is adjusted to the absorptio

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Abstract

The invention relates to a carbon dioxide separation technique, which is particular applied to an ion additive for carbon dioxide absorbent of organic amines, wherein, the ionic additive contains 0.01%-5% of Rb[UO2SeO4(OH).H2O] and 0.01%-5% Cu2(CO3)OH2. Compared with organic amines without the ion additive, the oxidation speed of the organic amines with the ionic additive can be reduced by around 50% and the electrochemical corrosion can be decreased by 40%.

Description

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Claims

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Application Information

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Owner CPI YUANDA ENVIRONMENTAL PROTECTION ENG
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