Ion additive for carbon dioxide absorbent of organic amines
A carbon dioxide and organic amine technology, applied in the direction of inorganic chemistry, through absorption, reagents, etc., can solve the problems of absorbent oxidation, chemical corrosion, fly ash pollution, etc., and achieve the effect of reducing electrochemical corrosion and oxidation rate
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Embodiment 1
[0013] Example 1 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives
[0014] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives
[0015] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 0.01% by mass Rb[UO 2 SeO 4 (OH) H 2 O], the mass percentage is 0.01%Cu 2 (CO 3 )(OH) 2 And the mass percentage is 0.01%Na 2 CO 3 composition.
[0016] 2. Performance testing
[0017] 2.1 Test of oxidation rate
[0018] The oxidation rate test in this example is calculated as the time at which the amine (MEA) is reduced to 95% concentration.
[0019] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stir
Embodiment 2
[0024] Example 2 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives
[0025] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives
[0026] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 5% by mass Rb[UO 2 SeO 4 (OH) H 2 O] and mass percentage of 5%Cu 2 (CO 3 )(OH) 2 composition.
[0027] 2. Performance testing
[0028] 2.1 Test of oxidation rate
[0029] In this example, the time when the oxidation rate of an amine is reduced to 95% is calculated.
[0030] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stirrer is adjusted to the absorption temperature of 105 ° C and the magnetic stirri
Embodiment 3
[0035] Example 3 Organic Amine Carbon Dioxide Absorber Containing Ionic Additives
[0036] 1. Preparation of organic amine carbon dioxide absorbent containing ionic additives
[0037] The organic amine carbon dioxide absorber containing ionic additives consists of 18% by mass MEA, 0.2% by mass Rb[UO 2 SeO 4 (OH) H 2 O], the mass percentage is 0.2%Cu 2 (CO 3 )(OH) 2 And the mass percentage is 0.1%Na 2 CO 3 composition.
[0038] 2. Performance testing
[0039] 2.1 Test of oxidation rate
[0040] In this example, the time when the oxidation rate of an amine is reduced to 95% is calculated.
[0041] To increase the reaction rate, 100% oxygen was used. In a stirred reactor at atmospheric pressure, the determination of various amine solutions at 100% O 2 The main experimental process of the oxidation rate in the presence of the test preparation stage is as follows: in the test preparation stage, the constant temperature oil bath magnetic stirrer is adjusted to the absorptio
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