Method for removing sulfide in methyl tert butyl ether by catalytic distillation

[0020] Example 1

[0021] Catalytic distillation desulfurization tower reactor with a diameter of 30 mm, a height of 500 mm, and a number of plates of 25, equipped with Raschig ring ceramic packing, filled with a height of 100 mm, 25% hydrogen peroxide, methyl tert-butyl The base ether is fed from the bottom of the tower through a metering pump in the gas phase at a rate of 80g / h, and the formic acid is fed from the top of the tower through a metering pump through a metering pump in countercurrent contact with methyl tert-butyl ether and oxidized by hydrogen peroxide. Function: Oxidize organic sulfide in methyl tertiary butyl ether to water-soluble sulfate. The bottom temperature of the tower is 90℃, the temperature of the oxidation reaction section is 80℃, the top temperature is 60℃, and the top reflux ratio is 1; after oxidation Water-soluble sulfates are formed and dissolved in the water reduced with hydrogen peroxide, and left at the bottom of the tower; the methyl tert-but

[0022] Example 2

[0023] Catalytic distillation desulfurization tower reactor with a diameter of 30 mm, a height of 500 mm, and a number of plates of 25, equipped with ceramic Raschig ring packing, filled with 25% hydrogen peroxide and methyl tert-butyl with a height of 125 mm The base ether is fed from the bottom of the tower through a metering pump in the gas phase at a speed of 60g / h, and the formic acid is fed from the top of the tower through a metering pump at a rate of 2.0g / h. The liquid phase feed is in countercurrent contact with methyl tert-butyl ether and is oxidized by hydrogen peroxide. Function: Oxidize organic sulfide in methyl tertiary butyl ether to water-soluble sulfate. The bottom temperature of the tower is 80℃, the temperature of the oxidation reaction section is 75℃, the top temperature is 60℃, and the top reflux ratio is 2; after oxidation Water-soluble sulfates are formed and dissolved in the water reduced with hydrogen peroxide, and left at the botto

[0024] Example 3

[0025] Catalytic distillation desulfurization tower reactor with a diameter of 30 mm, a height of 500 mm, and a number of trays of 15 pieces, equipped with ceramic Raschig ring packing, filled with 5% hydrogen peroxide and methyl tert-butyl with a height of 150 mm Base ether is fed from the bottom of the tower through a metering pump in the gas phase at a speed of 20g / h, and formic acid is fed from the top of the tower through a metering pump at a rate of 2.0g / h. The liquid phase feed is in countercurrent contact with methyl tert-butyl ether and oxidized by hydrogen peroxide. Function: Oxidize the organic sulfide in methyl tert-butyl ether to water-soluble sulfate. The temperature at the bottom of the tower is 80°C, the temperature of the oxidation reaction section is 75°C, the temperature at the top of the tower is 65°C, and the reflux ratio at the top of the tower is 1; after oxidation Water-soluble sulfates are formed and dissolved in the water reduced wi