Method for preparing high-temperature resistant microporous membrane

A microporous membrane, high temperature resistant technology, applied in the direction of electrical components, circuits, battery pack components, etc., can solve the problems of battery safety hazards, easy to block the diaphragm, and inability to obtain consistency, etc., to solve compatibility problems, Solve the effect of mechanical property degradation

Active Publication Date: 2014-05-21
SUZHOU GREEN POWER NEW ENERGY MATERIALS CO LTD
View PDF3 Cites 13 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This technology improves upon traditional materials used for making batteries separator membranes due to its ability to maintain their shape when heated up or cooled down repeatedly over time without losing strength at room temperatures. By adding certain types of polymers that have specific functions such as good chemical stability during processing steps like extrusion into films made from these compositions can improve their performance even after repeated exposures to extreme conditions (temperature).

Problems solved by technology

This technical issue addressed by this patented solution relates to improving the thermal stability (meltdown) behavior of micro porous films that can protect Li ion batteries from damage caused by overheat or accidental explosion during use.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A method for preparing a high-temperature-resistant microporous membrane, the method for preparing comprises the following steps in sequence:

[0025] A, 40kg resin mixture and 160kg paraffin oil will be added to the twin-screw extruder through a feeding port and mixed uniformly. The resin mixture is made up of 0.8kg polyester, 2kg polypropylene and 37.2kg polyethylene, polyester Melting point greater than 170 ° C, polyethylene contains 3.72kg molecular weight greater than 10 6 Polyethylene, the average molecular weight of polyethylene is 2.5×10 5 ~1.5×10 6 , the average molecular weight of polypropylene is 2×10 4 ~10 6 And the melting point is greater than 145°C;

[0026] B. The raw materials mixed in step A are melted and extruded through the die of the extruder at 170 ° C, and naturally cooled to form a sheet;

[0027] C. The sheet in step B is first stretched vertically five times and then stretched horizontally by the roller. The total s

Embodiment 2

[0032] A method for preparing a high-temperature-resistant microporous membrane, the method for preparing comprises the following steps in sequence:

[0033] A. Mix 40kg of resin mixture and 126.4kg of paraffin oil raw materials. The resin mixture is composed of 2.4kg of polyamide, 4kg of polypropylene and 33.6kg of polyethylene. The melting point of polyamide is greater than 170°C, and polyethylene contains 7.44kg of molecular weight 10 6 Polyethylene, the average molecular weight of polyethylene is 2.5×10 5 ~1.5×10 6 , the average molecular weight of polypropylene is 2×10 4 ~10 6 And the melting point is greater than 145°C. The mixing process is as follows: ① Mix 2.4kg polyamide, 4kg polypropylene and 16.8kg polyethylene in a high-speed dispersion to form a material, ② Mix the remaining 16.8kg polyethylene with 63.2kg paraffin oil Mix it into material b, ③, add material a into material b and mix it into material c, ④, add material c and the remaining 6

Embodiment 3

[0040] A method for preparing a high-temperature-resistant microporous membrane, the method for preparing comprises the following steps in sequence:

[0041] A. Mix 40kg of resin mixture and 32.8kg of paraffin oil in a kneader and add them to the extruder. The resin mixture is composed of 4kg of polymethylpentene, 6kg of polypropylene and 30kg of polyethylene. Polymethylpentene The melting point of alkene is greater than 170°C, and polyethylene contains 27.9kg of molecular weight greater than 10 6 Polyethylene, the average molecular weight of polyethylene is 2.5×10 5 ~1.5×10 6 , the average molecular weight of polypropylene is 2×10 4 ~10 6 And the melting point is greater than 145°C;

[0042] B. Melt and extrude the raw materials mixed in step A through the die head of the extruder at 250°C, and cool with a roller at a cooling rate of 80°C / s to form a sheet, and the cooling medium is water;

[0043] C, the sheet material of step B is stretched hor

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Melting pointaaaaaaaaaa
Melting pointaaaaaaaaaa
Login to view more

Abstract

The invention relates to a method for preparing a high-temperature resistant microporous membrane. The method sequentially comprises the following steps: (A) mixing raw materials consisting of 20-55% (by weight) of resin mixture and 45-80% (by weight) of membrane forming solvent; (B) carrying out melt extrusion on the mixed raw materials, and cooling to form a sheet; (C) longitudinally and transversely stretching the sheet, so as to form a membrane; (D) extracting the membrane forming solvent from the membrane through an extraction solvent, so as to form a microporous membrane; (E) carrying out heat-setting on the microporous membrane formed in the step (D), wherein the resin mixture consists of the ingredients in percentage by weight: 2-10% of high-temperature resistant resin, 5-15% of polypropylene and 75-93% of polyethylene, the melting point of the high-temperature resistant resin is higher than 170 DEG C, and polyethylene with the molecular weight greater than 106 accounts for 10-30% the total weight of the polyethylene. The method for preparing the high-temperature resistant microporous membrane, disclosed by the invention, aims to provide the high-temperature resistant microporous membrane which is good in temperature resistance and relatively high in melting rupture temperature and better meets the use requirements of lithium battery diaphragms.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Owner SUZHOU GREEN POWER NEW ENERGY MATERIALS CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products