Positive plate capable of improving lithium nickel manganese oxide battery capacity and lithium nickel manganese oxide battery applying positive electrode plate

A technology of lithium nickel manganese oxide and battery capacity, applied in the field of lithium nickel manganese oxide battery, can solve the problems of multi-active lithium ions, blockage of lithium ion channels, collapse of crystal structure, etc., and achieve the effect of improving battery capacity

Pending Publication Date: 2016-07-27
SUZHOU YOULION BATTERY INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Thermodynamically, there are two main reasons for the reduction of battery capacity: one is the loss of activity of the positive and negative electrode materials, such as the collapse of the crystal structure, the blockage of lithium ion channels, and poor contact between the active material and the conductive agent; the other is the consumption of active lithium ions. , such as used to form SEI film and lithium ions that cannot be completely removed from the positive and negative electrodes
[0005] For example, a high-voltage lithium nickel

Method used

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  • Positive plate capable of improving lithium nickel manganese oxide battery capacity and lithium nickel manganese oxide battery applying positive electrode plate

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] This embodiment provides a lithium nickel manganese oxide battery, including a battery main body, a negative electrode arranged on the battery main body and made of graphite, a positive electrode sheet arranged on the battery main body and corresponding to the negative electrode, and a battery filled in the battery main body. electrolyte in the

[0025] In terms of mass percentage, the positive electrode sheet contains the following components: 3wt% compound, 5wt% conductive agent, 3wt% binder, and a positive electrode active material composed of lithium nickel manganese oxide that occupies the remaining proportion;

[0026] The compound is lithium iron phosphate;

[0027] Correspondingly, lithium titanate, lithium vanadate or lithium peroxide are all the same as lithium iron phosphate, which can realize the extraction of lithium ions at a lower voltage; they can be substituted for each other when needed;

[0028] The conductive agent is carbon black;

[0029] The binder

Embodiment 2

[0033] Example 2 is basically the same as Example 1, the only difference is that the content of the compound is 5wt%.

Embodiment 3

[0035] Embodiment 3 is basically the same as Embodiment 2, the only difference is: the compound content is 8wt%.

[0036] refer to figure 1 , and in conjunction with embodiment 1, embodiment 2, and embodiment 3 and simultaneously add the lithium nickel manganese oxide battery used at the present stage to run at a voltage interval of 3.5 with a charge and discharge rate of C / 3; and obtain the battery used at the present stage, Embodiment 1, embodiment 2, and the specific capacity of its corresponding lithium nickel manganese oxide of embodiment 3;

[0037] At this time, lithium iron phosphate is completely oxidized to iron phosphate and does not participate in the electrochemical reaction, so the battery capacity comes entirely from lithium nickel manganese oxide. At the same time, as the amount of lithium iron phosphate in the positive electrode increases, the specific capacity of lithium nickel manganese oxide It will increase accordingly; lithium nickel manganese oxide is th

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Abstract

The invention discloses a positive plate capable of improving lithium nickel manganese oxide battery capacity. The positive plate comprises the following components based on mass percentage: 0.1-10% of compound, 1-20% of conductive agent, 2-10% of binder, and the balance beinga positive electrode active material consisting of lithium nickel manganese oxide, wherein the compound is lithium titanate, lithium iron phosphate, lithium vanadate or lithium peroxide. The positive plate capable of improving the lithium nickel manganese oxide battery capacity and the lithium nickel manganese oxide battery applying the positive electrode plate have the beneficial effects as follows: the compound consisting of lithium titanate, lithium iron phosphate, lithium vanadate or lithium peroxide is added to the positive plate; the lithium titanate, lithium iron phosphate, lithium vanadate or lithium peroxide are materials capable of realizing lithium ion intercalation under a relatively low voltage; therefore, active lithium ions are released in the initial charging process within charging-discharging voltage sections of the high-voltage lithium nickel manganese oxide battery; the lithium ion absorption is not continued in the subsequent discharging process of the lithium nickel manganese oxide battery; and therefore, the capacity of the lithium nickel manganese oxide battery is improved.

Description

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Claims

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Application Information

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Owner SUZHOU YOULION BATTERY INC
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